Hexaeoordinated group-14 elements with phosphorus syntheses and structures of (E = Si, Ge, Sn)

Chemische Berichte

Volumn 129, Issue 6, 1996, Pages 671-676

  Karsch, Hans H ^a,b   Deubelly, Brigitte ^a   Keller, Ursula ^a   Steigelmann, Oliver ^a   Laehmann, Joachim ^a   Müller, Gerhard ^a  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

^b UNIVERSITY OF KONSTANZ   (Germany)

Author keywords

Germanium; Hexacoordination; Phosphinomethanide ligands; Silicon; Tin

Indexed keywords

EID: 0008833396     PISSN: 00092940     EISSN: None     Source Type: Journal    
DOI: 10.1002/cber.19961290613     Document Type: Article

References (30)

1. [1a] C. Chuit, R. J. P. Corriu, C. Rcye, J. C. Young, Chem. Rev. 1993, 93, 1371.
2. [1b] V. E. Shklover, Yn. T. Struchkov, M. G. Voronkov, Russ. Chem. Rev. 1989, 53, 3.
3. [2a] D. Kummer, S. G. Chaudry, W. Depmaier, G. Mattern, Chem. Ber. 1990, 123, 2241 and cited literature.
4. [2b] R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1 and cited literature.
5. See e.e.: [3a] C. Silvestru, I. Haiduc, J. Organomet. Chem. 1989, 365, 83 and cited literature; [3b] J R. K. Chadha, J. E. Drake, A. B. Sakar, Inorg. Chim. Acta 1988, 143, 31 and cited literature.
6. 4: G. Müller, M. Waldkircher, unpublished results.
7. [5a] H. H. Karsch, A. Appell, G. Müller, Organometallics 1986, 5, 1664.
8. [5b] H. H. Karsch, B. Deubelly, G. Hanika, J. Riede, G. Müller, J. Organomet. Chem. 1988, 344, 153.
9. [5c] H. H. Karsch, U. Keller, S. Gamper, G. Müller, Angew. Chem. 1990, 102, 297; Angew. Chem. Int. Ed. Engl. 1990, 29, 295.
10. 3: H. H. Karsch. A. Appell, l Riede, G. Müller, Organometallics 1987, 6, 316.
11. 3: H. H. Karsch, M. Kawecki, A. Schier, not yet published.
12. 4]: H. H. Karsch, G.
13. Ferazin, H. Koijman, O. Steigelmann, A. Schier, P. Bissinger, W. Hiller, J. Organomet. Chem. 1994, 482, 151.
14. [9a] B. Deubelly, Dissertation TU München 1988.
15. [9b] U. Keller, Dissertation TU München 1992.
16. H. H. Karsch, B. Deubelly, J. Riede, G. Müller, Angew. Chem. 1987, 99, 703; Angew. Chem. Int. Ed. Engl. 1987, 26, 673.
17. H. H. Karsch, RUSS. Chem. Bull. 1993, 42, 1937.
18. See for example: H. H. Karsch, R. Richter, B. Deubeliy, A. Schier, M. Paul, M. Heckel, K. Angermaier, W. Hiller, Z. Naturforsch. B: Chem. Sci. 1994, 49, 1798.
19. H. H. Karsch, K. Zellner, G. Müller, Organometallics 1991, 10, 2884.
20. W. S. Sheldrick, The Chemistry of Organic Silicon Compounds (Eds.: S. Paiai, Z. Rappoport) John Wiley & Sons, 1989, Chapter 3, p. 260.
21. H. H. Karsch, U. Keller, B. Deubelly, F. Bienlein, G. Baumgartner, G. Müller, P. Bissinger, M. Heckel, Chem. Ber., submitted.
22. An excess of lithium diphosphinomethanide in the solution lowers the conversion rate considerably - this is the reason for the stoichiometry in Eq. (2), but the effect is not yet understood.
23. H. H. Karsch, A. Appell, B. Deubelly, K. Zellner, J. Riede, G. Müller, Z. Naturforsch. B: Chem. Sci. 1988, 43, 1416.
24. H. H. Karsch, G. Grauvogl, P. Mikulcik, P. Bissinger, G. Müller, J. Organomet. Chem. 1994, 465, 65.
25. H. Zimmermann, H. Burzlaff, Z. Kristallogr. 1985, 170, 241.
26. Y. LePage, J. Appl. Crystallogr. 1982, 75, 255.
27. G. M. Sheldrick in Crystallographic Computing 3, (Eds.: G. M. Sheldrick, C. Krüger, R. Goddard), Oxford University Press 1985, p. 175.
28. G. M. Sheldrick, SHELX-76, Program for Crystal Structure Determination. University of Cambridge, Cambridge, England, 1976.
29. C. K. Johnson, ORTEP-II, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976.
30. Further crystal structure data, including complete tables of atomic parameters and observed and calculated structure factors may be obtained from the Fachinformationszentrum Karlsruhe GmbH, D-76344 Eggenstein-Leopoldshafen (Germany), by quoting the depository number CSD-59243, the names of the authors, and the journal citation.