Kinetics and Mechanism of the Reactions of Sulfito Complexes in Aqueous Solution. 5. Formation, Isomerization, and Sulfite Addition Reactions of the Oxygen-Bonded (Sulfito)pentaammineplatinum(IV) Ion and the Subsequent Intramolecular Redox Reactions of the Sulfur-Bonded Intermediate, the cis -Bis(sulfito)tetraammineplatinum(IV) Ion

Inorganic Chemistry

Volumn 22, Issue 20, 1983, Pages 2947-2953

  Koshy, K C ^a   Harris, G M ^a  

^a UNIVERSITY AT BUFFALO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0008710305     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic00162a036     Document Type: Article

References (19)

1. Preliminary reports based on this work were presented at the 182nd Meeting of the American Chemical Society, New York, Aug 1981, and at the Third International Conference on Mechanisms of Reactions in Solution, Canterbury, England, July 1982.
2. Preceding paper in this series: El Awady, A. A.; Harris, G. M. Inorg. Chem. 1981, 20, 4251.
3. van Eldik, R.; Harris, G. M. Inorg. Chem. 1980, 19, 880.
4. van Eldik, R. Inorg. Chim. Acta 1980, 42, 49.
5. El-Awady, A. A.; Harris, G. M. Inorg. Chem. 1981, 20, 1660.
6. Dash, A. C.; El-Awady, A. A.; Harris, G. M. Inorg. Chem. 1981, 20, 3160.
7. van Eldik, R.; von Jouanne, J.; Kelm, H. Inorg. Chem. 1982, 21, 2818.
8. “Gmelin Handbuch der Anorganischen Chemie” Springer-Verlag: West Berlin, 1957; Vol. 68D, pp 476–484.
9. Jorgensen, C. K. Acta Chem. Scand. 1956, 10, 518.
10. Typically, Co(III) S-bonded sulfito complexes exhibit strong trans effects in subsequent substitutions. See: Spitzer, U.; van Eldik, R. Inorg. Chem. 1982, 21, 4008 and references quoted therein.
11. “Gmelin Handbuch der Anorganischen Chemie” Springer-Verlag: West Berlin, 1957; Vol. 68D, pp 476–486.
12. Bjerrum, J.; Schwarzenbach, G.; Sillen, L. G. “Stability Constants” The Chemical Society: London, 1957.
13. Sillen, L. B.; Martell, A. E. “Stability Constants” The Chemical Society: London, 1964.
14. Elving, P. J.; Markowitz, J. M.; Rosenthal, L. Anal. Chem. 1956, 28, 1179.
15. Fowless, A. D.; Stranks, D. R. Inorg. Chem.-. (a) 1977, 16, 1276; (b) 1977, 16, 1282; (c) 1977, 16, 1276.
16. Chaffee, E.; Dasgupta, T. P.; Harris, G. M. J. Am. Chem. Soc. 1973, 95, 4169.
17. van Eldik, R.; Palmer, D. A.; Kelm, H.; Harris, G. M. Inorg. Chem. 1980, 19, 3679.
18. Deduced from the data of: Thacker, M. A.; et al. J. Chem. Soc., Dalton Trans. 1974, 647. These data were recently confirmed by: van Eldik, R., personal communication.
19. Gurnee, E. F.; Magee, J. L. J. Chem. Phys. 1957, 26, 1237. Ann. Phys. (Leipzig) 1939, [5] 34, 341.