Kinetic of copper(III)/(II) tetraglycine reactions with sulfite. Analytical potentialities

Spectroscopy Letters

Volumn 31, Issue 7, 1998, Pages 1495-1512

  Yoshida, Deborah ^a   Moya, Horacio D ^a   Bonifácio, Rodrigo L ^a   Coichev, Nina ^a  

^a UNIVERSITY OF SÃO PAULO   (Brazil)

Author keywords

Cu(II) (III) tetraglycine; Flow injection analysis; Formaldehyde; Sulfite

Indexed keywords

EID: 0008647540     PISSN: 00387010     EISSN: None     Source Type: Journal    
DOI: 10.1080/00387019808001655     Document Type: Article

References (31)

1. Brandt C., van Eldik R. Transition Metal-Catalyzed Oxidation of Sulfur(IV) Oxides. Atmospheric-Relevant Processes and Mechanisms. Chem Rev. 1995; 95: 119, and references therein.
2. Weschler C. J., Mandich M. L., Graedel T. E. Speciation, photosensivity, and reactions of transition metal ions in atmospheric droplets. J. Geophys. Res. 1986; 91: 5189.
3. Graedel T. E., Mandich M. L., Weschler C. J. Kinetic Model Studies of Atmospheric Droplet Chemistry. 2. Homogeneous Transition Metal Chemistry in Raindrops. J. Geophys. Res. 1986; 91; 5205.
4. Hoffmann M. R., Calvert J. G. Chemical Transformation Modules for Eulerian Acid Deposition Models Vol. 2 "The Aqueous-Phase Chemistry" Interagency Agreement DW 930237, 1985.
5. Warneck P. Chemical reactions in clouds. Fresenius Z. Anal. Chem. 1991; 340: 585.
6. Warneck P. Chemistry and Photochemistry in Atmosferic Water Drops. Ber. Busenges. Phys. Chem. 1992; 96: 454.
7. Boyce S. D., Hoffmann M. R., Hong P. A., Moberly L. M. Catalysis of the Autoxidation of Aquated Sulfur Dioxide by Homogeneous Metal-Phtalocyanine Complexes. Environ. Sci. Technol, 17 (1983) 602.
8. Coichev N., Reddy K. B., van Eldik R. The synergistic effect of manganese(II) in the sulfite-induced autoxidation of metal ions and complexes in aqueous solution. Atmos. Environ. 1992; 26A: 2295.
9. III(cyclam)]: Evidence for a Novel Radical Chain Mechanism. Inorg. Chem. 1990; 29: 4356.
10. Dellert-Ritter M., van Eldik R. Kinetics and Mechanism of the Redox Behaviour of the Ethylene diaminetetraacetatoferrate(III)-Sulfite System in Aqueous Solution. J. Chem. Soc., Dalton Trans. 1992; 1037: 1045.
11. Carlyle D.W. Electron Transfer between Sulfur(IV) and Tris (1,10-phenantroline)iron(III) Ion in Aqueous Solution. J. Am. Chem. Soc. 1972; 94: 4525.
12. Coichev N., van Eldik R. Kinetics and Mechanism of Sulfite-induced Autoxidation of Cobalt(II) in Aqueous Azide Medium. Inorg. Chem. 1991; 30: 2375.
13. Coichev N., van Eldik R. A mechanistic study of the sulfite-induced autoxidation of Mn(II) in aqueous azide medium. Inorg. Chim. Acta 1991; 185: 69.
14. Reddy K. B., Coichev N., van Eldik R. Redox Cycling of Iron in Atmospheric Water: the important Role of Sulfite. J. Chem. Soc. Chem. Commun. 1991: 481.
15. Reddy K. B., van Eldik R. Kinetics and Mechanism of the Sulfite-induced Autoxidation of Fe(II) in acidic aqueous solution. Atmos. Environ. 1992; 26A: 661.
16. Kraft J., van Eldik R. Kinetics and Mechanism of the Iron(III)-Catalyzed Autoxidation of S(IV) Oxides in Aqueous Solution. 1. Formation of Transient Iron(III)-Sulfur(IV). Inorg. Chem. 1989; 28: 2297.
17. Coichev N., van Eldik R. A Fascinating Demonstration of Sulfite-induced Redox Cycling of Metal Ions Initiated by Shaking. J. Chem. Ed. 1994; 71: 767.
18. Coichev N., van Eldik R. Metal catalyzed atmospheric oxidation reactions. A challenge to coordination chemists, New. J. Chem. 1994; 18: 123.
19. Gebert J., Neves E. F. A., Klockow D. Evaluation of the sulfar(IV) catalyzed autoxidation of cobalt(III) in an azide containing medium as a means for the determination of sulfite in precipitation. Fresenius Z. Anal. Chem. 1988; 331: 267.
20. Neves E. F. A., Valdes J., Klockow D. Determination of sulfur(IV) dioxide in air on the basis of the catalyzed autoxidation of Co(II) in an azide medium. Fresenius Z. Anal. Chem. 1995; 351: 544.
21. Segundo S. M. A., Neves E. F. A. Klockow D. The Sulfur(IV)-Cobalt(II)-Azide System and Its Application to the Investigation of the Decomposition of Sulfur Hexafluoride under Electrical Discharges. Analyst 1994; 119: 1075.
22. Neves E. F. A., Coichev N. Autoxidation of cobalt(II) in azide containing medium in presence of sulfur(IV): an interpretative study, J. Gebert and D. Klockow. Fresenius Z. Anal. Chem. 1989; 335: 386.
23. Leite H. M. S., Coichev N., Neves E. F. A. The sulfur accelerated autoxidation of cobalt(II) in the presence of tris(hydroxymethil)aminomethane. Analytical Letters 1996; 29 (14): 2587.
24. Anast J. M., Margerum D.W. Trivalent Copper Catalysis of the autoxidation of Sulfite. Kinetics and the mechanism of the Copper (III/II) Tetraglycine Reactions with Sulfite. Inorg. Chem. 1981; 20: 2319.
25. Olson T. M. and Hoffmann M. R. Hydroxyalkylsulfonate formation: its role as a S(IV) reservoir in atmospheric water droplets. Atmos. Environ. 1989; 23: 985.
26. nd ed. Mir Publishers, Moscow; 1978: 253.
27. OLIS KINFIT ROUTINES On-line Instruments Systems Inc., Jefferson, GA, 1989.
28. Brandt C., Fábián I. and van Eldik R. Kinetics and Mechanism of the Iron(III)-Catalyzed Autoxidation of Sulfur(IV) Oxides in Aqueous Solution. Evidence for the redox cycling of Iron in the presence of Oxygen and Modelling of the Overall Reaction Mechanism. Inorg. Chem. 1994; 33: 687.
29. Berglund J., Fronaeus S., Elding L. I. Kinetics and Mechanism for Manganese(II) Catalyzed Autoxidation of Sulfur(IV) Oxides by Oxygen in Aqueous Solution. Inorg. Chem. 1993; 32: 4527.
30. Guekezian M., Coichev N., Suarez-Iha M. E. V. and Neves E. F. A. Stability of sulfur(IV) solutions in the presence of amines and the tendency of sulfite ions to disproportionate in stock solutions, Analytical Letters 1997; 30: 1423.
31. Margerum D. W., Ruckes G. R. Kinetics and mechanisms of metalion and proton-transfer reactions of oligopeptide complexes, in Metal Ions Biological Systems, Vol. 1, Chapter 5, Ed. Helmut Sigel, New York, Marcel Dekker, Inc., 1974, p. 157