Complexity in the Reductive Reaction of CoCl2 in the Presence of Phosphites. Isolation of Stable, Noninterconvertible Co[P(OCH3)3]4 and Co2[P(OCH3)3]8 Molecules

Journal of the American Chemical Society

Volumn 104, Issue 10, 1982, Pages 2940-2942

  Muetterties, E L ^a   Bleeke, J R ^a   Yang, Z Y ^a   Day, V W ^b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF NEBRASKA LINCOLN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0008192413     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00374a049     Document Type: Article

References (11)

1. Muetterties, E. L.; Watson, P. L. J. Am. Chem. Soc. 1978, 100, 6978.
2. Rakowski, M. C.; Muetterties, E. L. J. Am. Chem. Soc. 1977, 99, 739.
3. Muetterties, E. L.; Hirsekorn, F. J. J. Am. Chem. Soc. 1974, 96, 7920.
4. Lee, B.; Burlitch, J. M.; Hoard, J. L. J. Am. Chem. Soc. 1967, 89, 6362.
5. Sheldrick, G. M.; Simpson, R. N. F. J. Chem. Soc. A 1968, 1005.
6. Meakin, P.; Jesson, J. P. J. Am. Chem. Soc. 1974, 96, 5751.
7. Jesson, J. P.; Meakin, P. J. Am. Chem. Soc. 1974, 96, 5760.
8. This monomer has been reported: Zecchin, S.; Zotti, G.; Pilloni, G. Inorg. Chim. Acta 1973, 33, L117.
9. 4 had been isolated directly from the reduction reaction by F. J. Hirsekorn (Cornell University, 1974, unpublished data).
10. + cation: Coskran, K. J.; Huttemann, T. J.; Verkade, J. G. Adv. Chem. Ser. 1966, 62, 590.
11. Wegman, R. W.; Olsen, R. J.; Gard, D. R.; Faulkner, L. R.; Brown, T. L. J. Am. Chem. Soc. 1981, 103, 6089.