Influence of the Donor Atom in Metallocyclic Rings on the Insertion of Tert-butyl Isocyanide and Carbon Monoxide into Their Pd-C Bonds.1X-ray Molecular structure of _ [Pd(η-(C,N)-η-C(C6H4Ch2SMe)=N-t-Bu)Br]2

Organometallics

Volumn 6, Issue 4, 1987, Pages 899-901

  Dupont, Jalrton ^a   Pfeffer, Michel ^a   Daran, Jean Claude ^b   Jeannin, Yves ^b  

^a UNIVERSITÉ DE STRASBOURG   (France)

^b SORBONNE UNIVERSITÉ   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0008095522     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om00147a041     Document Type: Article

References (9)

1. Reactivity of Cyclopalladated Compounds. 17. Part 16: see ref 3i.
2. Laboratoire de Chimie de Coordination. Laboratoire de Chimie des Metaux de Transition.
3. For a recent review see: Ryabov, A. D. Synthesis 1985, 233. Ossor, H.; Pfeffer, M. J. Chem. Soc., Chem. Commun. 1985, 1540. O'sullivan, R. D.; Perkins, A. W. J. Chem. Soc., Chem. Commun. 1984, 1165. Massarani, F.; Pfeffer, M.; Le Borgne, G. J. Chem. Soc., Chem. Commun. 1986, 488. Albinati, A.; Pregosin, P. S.; Ruedi, R. Helv. Chim. Acta 1985, 68, 2046. Barr, N.; Bartley, J. P.; Clark, P. W.; Dunston, P.; Dyke, S. F. J. Organomet. Chem. 1986, 302, 117. Wu, G.; Rheingold, A. L.; Heck, R. F. Organometallics 1986, 5, 1922. Dupont, J.; Pfeffer, M. J. Organomet. Chem. 1987, 321, C13. Masassarani, F.; Pfeffer, M.; Le Borgne, G. Organometallics, in press.
4. Carruthers, B.; Watkin, D. J. Crystals, an Advanced Crystallographic Computer Program; Chemical Crystallography Laboratory: University of Oxford, Oxford, England, 1985.
5. See for instance: Churchill, M. R.; Wasserman, H. J.; Glenda, J. Y. Inorg. Chem. 1980, 19, 762. Selbin, J.; Abboud, K.; Watkins, S. F.; Gutierrez, M. A.; Fronczek, F. R. J. Organomet. Chem. 1983, 241, 259.
6. Isobe, K.; Nanjo, K.; Nakamura, Y.; Kawaguchi, S. Bul. Chem. Soc. Jpn. 1986, 59, 2141.
7. Uson, R.; Fomies, J.; Espinet, P.; Pueyo, L. J. Organomet. Chem. 1986, 299, 251. (16) Yamamoto, Y.; Yamazaki, H. Inorg. Chim. Acta 1980, 41, 229.
8. Hiraki, K.; Fuchita, Y.; Takechi, K. Inorg. Chem. 1981, 20, 4316.
9. We found that compound 2a resisted all attempts to insert any type of alkyne into its PdC bond.