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Volumn 103, Issue 26, 1999, Pages 5049-5054

A Hidden Hydrogen Transfer in the Unimolecular Reaction of 1,2-Dimethoxyethane •+

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0007819659     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp990654y     Document Type: Article
Times cited : (7)

References (34)
  • 11
    • 0041739784 scopus 로고    scopus 로고
    • note
    • The mechanisms involving 1,2- or 1,3-H transfers to a radical site, which involve very high energy barriers, were not selected. In any case, such mechanisms are in contradiction with the data summarized in Table 1.
  • 17
    • 0000397250 scopus 로고    scopus 로고
    • Structure and Reactivity of Selected Distonic Radical Cations
    • Baer, T., Ng, C-Y., Powis, I., Eds.; John Wiley & Sons: Chichester, U.K.
    • Smith, R. L.; Chou, P. K.; Kenttämaa, H. I. Structure and Reactivity of Selected Distonic Radical Cations. In The Structure, Energetics and Dynamics of Organic Ions; Baer, T., Ng, C-Y., Powis, I., Eds.; John Wiley & Sons: Chichester, U.K., 1996; pp 197.
    • (1996) The Structure, Energetics and Dynamics of Organic Ions , pp. 197
    • Smith, R.L.1    Chou, P.K.2    Kenttämaa, H.I.3
  • 20
    • 85088001842 scopus 로고    scopus 로고
    • note
    • 2 loss and methanol loss, was evaluated in this work from its CID spectrum and from its peak shape in the MIKE spectrum of 1f; (iv) interpretation was revisited.
  • 21
    • 0041739782 scopus 로고    scopus 로고
    • note
    • It may be also possible that the nature (H or D) of the first transfer changes the energy content of the intermediate 3. In contrast, it will be shown further below, that the simple cleavage giving m/z 45, dominant in the ion source, occurs without isotope effect and has, therefore, no influence on the internal energy distribution in the ion source.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.