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The mechanisms involving 1,2- or 1,3-H transfers to a radical site, which involve very high energy barriers, were not selected. In any case, such mechanisms are in contradiction with the data summarized in Table 1.
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2 loss and methanol loss, was evaluated in this work from its CID spectrum and from its peak shape in the MIKE spectrum of 1f; (iv) interpretation was revisited.
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21
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0041739782
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It may be also possible that the nature (H or D) of the first transfer changes the energy content of the intermediate 3. In contrast, it will be shown further below, that the simple cleavage giving m/z 45, dominant in the ion source, occurs without isotope effect and has, therefore, no influence on the internal energy distribution in the ion source.
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