Mechanism of 1,5-Hydrogen Migration in Diene Iron Carbonyl Complexes

Journal of the American Chemical Society

Volumn 95, Issue 17, 1973, Pages 5811-5813

  Whitesides, Thomas H ^a   Neilan, James P ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0007770781     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00798a089     Document Type: Letter

References (10)

1. C. F. Woods, N. C. Bolgiano, and D. E. Duggan, J. Amer. Chem. Soc., 77. 1802(1955).
2. T. H. Whitesides and R. W. Arhart, J. Amer. Chem. Soc., 93, 5296 (1971).
3. W. R. Roth and J. König, Justus Liebigs Ann. Chem., 699, 24 (1966);
4. H. Kloosterziel and A. P. ter Borg, Reel. Trav. Chim. Pays-Bas?, 84, 1305 (1965), have found values of /ch/&d of 5-7 for concerted 1,5 shifts.
5. R. Victor, R. Ben-Shoshan, and S. Sarel, J. Org. Chem., 37. 1930 (1972).
6. R. Victor, R. Ben-Shoshan, and S. Sarel, Tetrahedron Lett., 4257 (1970).
7. H. W. Whitlock and R. L. Markezich, J. Amer. Chem. Soc., 93, 5290, 5291 (1971);
8. H. W. Whitlock, C. Reich, and W. P. Woessner, J. Amer. Chem. Soc., 93, 2483 (1971);
9. H. W. Whitlock and Y. N. Chuah, J. Amer. Chem. Soc., 87, 3605 (1965).
10. C. P. Casey and C. R. Cyr, J. Amer. Chem. Soc., 95, 2248 (1973). We thank Professor Casey for a preprint of his manuscript.