Catalytic applications of F8BINOL: Asymmetric oxidation of sulfides to sulfoxides

Journal of Organometallic Chemistry

Volumn 603, Issue 1, 2000, Pages 98-104

  James, L ^a   Martyn, P ^a   Pandiaraju, Subramanian ^a   Yudin, Andrei K ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

BINOL; Catalytic applications; Sulfides; Sulfoxides

Indexed keywords

EID: 0007500078     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0022-328x(00)00172-8     Document Type: Article

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34. For studies related to electronic effects of substituents on chiral ligands in asymmetric catalysis, see: (a) A. Schnyder, L. Hintermann, A. Togni, Angew. Chem. Int. Ed. Engl. 34 (1995) 931. (b) T.V. RajanBabu, A.L. Casalnuovo, J. Am. Chem. Soc. 118 (1996) 6325. (c) M. Palucki, N.S. Finney, P.J. Pospisil, M.L. Güler, T. Ishida, E.N. Jacobsen, J. Am. Chem. Soc. 120 (1998) 948.
35. 8BINOL (2.07 V vs. Ag/AgCl) is 0.6 V more positive than that of BINOL (1.47 V vs. Ag/AgCl).
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