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Volumn 28, Issue 4, 1989, Pages 773-780

Synthesis, Structure, and Electronic Properties of Tris(propane-l,3-dithiolato) and Tris(ethylene-l,2-dithiolato) Complexes of Niobium(V) and Tantalum(V)

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EID: 0007147646     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic00303a032     Document Type: Article
Times cited : (26)

References (26)
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    • Elegant studies of tris(benzeneL,2-dithiolato) and tris(toluene-3,4-di-thiolato) complexes of Nb and Ta and those of other early transition metals are available: (b) Martin, J. L.; Takats, J. Inorg. Chem. 1975, 14, 73–78, 1358–1364. (c) Cowie, M.; Bennett, M. J. Inorg. Chem. 1976, 15, 1584–1589, 1589–1595, 1595–1603
    • Elegant studies of tris(benzeneL,2-dithiolato) and tris(toluene-3,4-di-thiolato) complexes of Nb and Ta and those of other early transition metals are available: (a) Bennett, M. J.; Cowie, M.; Martin, J. L.; Takats, J. J. Am. Chem. Soc. 1973, 95, 7504–7505. (b) Martin, J. L.; Takats, J. Inorg. Chem. 1975, 14, 73–78, 1358–1364. (c) Cowie, M.; Bennett, M. J. Inorg. Chem. 1976, 15, 1584–1589, 1589–1595, 1595–1603.
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    • Bennett, M.J.1    Cowie, M.2    Martin, J.L.3    Takats, J.4
  • 8
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    • Examples of ethane-1,2-dithiolate complexes are as follows: Dorfman, J. R.; Rao, Ch. P.; Holm, R. H. Inorg. Chem. 1985, 24, 453–454. Rao, Ch. P.; Dorfman, J. R.; Holm, R. H. Inorg. Chem. 1986, 25, 428–439. (b) Snow, M. R.; Ibers, J. A. Inorg. Chem. 1973, 12, 249–254. (c) Herskovitz, T.; DePamphilis, B. V.; Gillum, W. O.; Holm, R. H. Inorg. Chem. 1975, 14, 1426–1428. (d) Money, J. K.; Huffman, J. C.; Christou, G. J. Am. Chem. Soc. 1987, 109, 2210-2211; Inorg. Chem. 1985, 24, 3297-3302; 1988, 27, 507–514. Nicholson, J. R.; Huffman, J. C.; Ho, D.; Christou, G. Inorg. Chem. 1986, 25, 4072–4074. (e) Szeymies, D.; Krebs, B.; Henkel, G. Angew. Chem. 1984, 96, 797-798; Angew. Chem., Int. Ed. Engl. 1984, 23, 804–805. Tremel W.; Krebs, B.; Henkel, G. J. Chem. Soc., Chem. Commun. 1986, 1527–1529. (f) Blower, P. J.; Dilworth, J. R.; Hutchinson, J. P.; Zubieta, J. A. Inorg. Chim. Acta 1982, 65, L225-L226. Dahlstrom, P. L.; Kumar, S.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1981, 411–412. (g) Rakowski DuBois, M.; Haltiwanger, R. C.; Miller, D. J.; Glatzmaier, G. J. Am. Chem. Soc. 1979, 101, 5245–5252. (h) Pan, W. H.; Chandler, T.; Enemark, J. H.; Stiefel, E. J. Inorg. Chem. 1984, 23, 4265–4269. Halbert, T. R.; McGauley, K.; Pan, W. H.; Czer-nuszewicz, R. S.; Stiefel, E. I. J. Am. Chem. Soc. 1984,106, 1849–1851
    • Examples of ethane-1,2-dithiolate complexes are as follows: (a) Dorfman, J. R.; Holm, R. H. Inorg. Chem. 1983, 22, 3179–3181. Dorfman, J. R.; Rao, Ch. P.; Holm, R. H. Inorg. Chem. 1985, 24, 453–454. Rao, Ch. P.; Dorfman, J. R.; Holm, R. H. Inorg. Chem. 1986, 25, 428–439. (b) Snow, M. R.; Ibers, J. A. Inorg. Chem. 1973, 12, 249–254. (c) Herskovitz, T.; DePamphilis, B. V.; Gillum, W. O.; Holm, R. H. Inorg. Chem. 1975, 14, 1426–1428. (d) Money, J. K.; Huffman, J. C.; Christou, G. J. Am. Chem. Soc. 1987, 109, 2210-2211; Inorg. Chem. 1985, 24, 3297-3302; 1988, 27, 507–514. Nicholson, J. R.; Huffman, J. C.; Ho, D.; Christou, G. Inorg. Chem. 1986, 25, 4072–4074. (e) Szeymies, D.; Krebs, B.; Henkel, G. Angew. Chem. 1984, 96, 797-798; Angew. Chem., Int. Ed. Engl. 1984, 23, 804–805. Tremel W.; Krebs, B.; Henkel, G. J. Chem. Soc., Chem. Commun. 1986, 1527–1529. (f) Blower, P. J.; Dilworth, J. R.; Hutchinson, J. P.; Zubieta, J. A. Inorg. Chim. Acta 1982, 65, L225-L226. Dahlstrom, P. L.; Kumar, S.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1981, 411–412. (g) Rakowski DuBois, M.; Haltiwanger, R. C.; Miller, D. J.; Glatzmaier, G. J. Am. Chem. Soc. 1979, 101, 5245–5252. (h) Pan, W. H.; Chandler, T.; Enemark, J. H.; Stiefel, E. J. Inorg. Chem. 1984, 23, 4265–4269. Halbert, T. R.; McGauley, K.; Pan, W. H.; Czer-nuszewicz, R. S.; Stiefel, E. I. J. Am. Chem. Soc. 1984,106, 1849–1851.
    • (1983) Inorg. Chem. , vol.22 , pp. 3179-3181
    • Dorfman, J.R.1    Holm, R.H.2
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    • The atomic scattering factors and anomalous dispersion corrections for Nb were taken from: Cromer, D. T.; Liberman, D. J. Chem. Phys. 1970, 53, 1891–1898
    • The atomic scattering factors and anomalous dispersion corrections for Nb were taken from: Cromer, D. T.; Mann, J. B. Acta Crystallogr. 1968, A24, 321–324. Cromer, D. T.; Liberman, D. J. Chem. Phys. 1970, 53, 1891–1898.
    • (1968) Acta Crystallogr. , vol.A24 , pp. 321-324
    • Cromer, D.T.1    Mann, J.B.2
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    • The NbS distances in the diethyldithiocarbamate complex [Nb-(S2CNEt2)4]Br are ca. 0,1 A longer than those of la and 5b
    • The NbS distances in the diethyldithiocarbamate complex [Nb-(S2CNEt2)4]Br are ca. 0,1 A longer than those of la and 5b: Drew, M. G. B.; Rice, D. A.; Williams, D. M. J. Chem. Soc., Dalton Trans, 1985, 1821–1828.
    • (1985) J. Chem. Soc., Dalton Trans , pp. 1821-1828
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    • The related tris(2-aminobenzenethiolato) complexes of Mo(VI) assume a trigo-nal-prismatic structure
    • The related tris(2-aminobenzenethiolato) complexes of Mo(VI) assume a trigo-nal-prismatic structure: Gardner, J. K.; Pariyadath, N.; Corbin, J. L.; Stiefel, E. I. Inorg, Chem. 1978, 17, 897–904
    • (1978) Inorg, Chem. , vol.17 , pp. 897-904
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    • There is a group of d1, d2 complexes with three bidentate ligands, geometries of which range from trigonal prism to octahedron: (a) Brown, G.; Stiefel, E. I. Inorg. Chem. 1973, 12, 2140–2147. (b) Dra-ganjac, M.; Coucouvanis, D. J. Am. Chem. Soc. 1983, 105, 139–140. (c) Boyde, S.; Garner, C. D. J. Chem. Soc., Dalton Trans. 1987, 2267–2271. (d) Colmanet, S. F.; Williams, G. A. J. Chem, Soc., Dalton Trans. 1987, 2305–2310. (e) Stiefel, E. 1.; Dori, Z.; Gray, H. B. J. Am. Chem Soc. 1967, 89, 3353–3354.
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    • and references therein (b) Kirchner, R. M.; Mealli, C.; Bailey, M.; Howe, N.; Torre, L. P.; Wilson, L. J.; Andrews, L. C.; Rose, N. J.: Lingafelter. E. C. Coord. Chem. Rev, 1987. 77. 89–163
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    • Nakamoto K. “Infrared Spectra of Inorganic and Coordination Compounds” Wiley: New York, 1970
    • Nakamoto K. “Infrared Spectra of Inorganic and Coordination Compounds” Wiley: New York, 1970. (b) Murrell, J. N. J. Chem. Soc. A 1969, 297–301.
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