Nickel(0)-catalyzed efficient 2:2 double-cycloaddition of monoynes with n-substituted maleimides to form bicyclo[2.2.2]oct-7-enes and its development into nickel(0)-catalyzed double-cycloaddition copolymerization of diynes with N-substituted maleimides to poly(bicyclo[2.2.2]oct-7-ene)s

Organometallics

Volumn 16, Issue 5, 1997, Pages 932-941

  Tsuda, Tetsuo ^a   Mizuno, Haruna ^a   Takeda, Atsushi ^a   Tobisawa, Akihiko ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0006684572     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9609877     Document Type: Article

References (13)

1. Coates, G. W.; Waymouth, R. M. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Hegedus, L. S., Eds.; Pergamon: Oxford, 1995; Vol. 12, p 1193.
2. (b) Moore, J. S. Ibid. p 1209.
3. (a) Tsuda, T. Gazz. Chim. Ital. 1995, 125, 101.
4. (b) Tsuda, T. In The Polymeric Materials Encyclopedia; Salamone, J. C., Ed.; CRC: Boca Raton, FL, 1996; Vol. 3, p 1905 and Vol. 5 p 3525.
5. The expression of a repeat unit of the cycloaddition copolymer in Scheme 1 is based on the nonregiospecific formation of carbo- and heterocycles.
6. (a) Tsuda, T.; Maruta, K.; Kitaike, Y. J. Am. Chem. Soc. 1992, 114, 1498.
7. (b) Tsuda, T.; Maruta, K. Macromolecules 1992, 25, 6102.
8. (c) Tsuda, T.; Ooi, O.; Maruta, K. Macromolecules 1993, 26, 4840.
9. (d) Tsuda, T.; Kitaike, Y.; Ooi, O. Macromolecules 1993, 26, 4956.
10. (e) Tsuda, T.; Hokazono, H. Macromolecules 1994, 27, 1289.
11. (f) Tsuda, T.; Yasukawa, H.; Hokazono, H.; Kitaike, Y. Macromolecules 1995, 28, 1312.
12. (g) Tsuda, T.; Yasukawa, H.; Komori, K. Macromolecules 1995, 28, 1356.
13. 2 copolymerization to a poly(4-pyrone), see: h) Tsuda, T.; Hokazono, H.; Toyota, K. J. Chem. Soc., Chem. Commun. 1995, 2417.