Cu2S mediated cross-coupling of α-stannylepoxides

Synlett

Volumn , Issue SPEC. ISS., 1997, Pages 481-482

  Falck, J R ^a   Bhatt, Rama K ^a   Reddy, Komamdla Malla ^a   Ye, Jianhua ^a  

^a UNIVERSITY OF TEXAS SOUTHWESTERN MEDICAL CENTER   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0006632897     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1997-6123     Document Type: Article

References (18)

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15. Except as noted, all α-epoxystannanes were prepared by epoxidation of the corresponding alkenyltins: Nishida, A.; Shibasaki, M.; Ikegami, S. Tetrahedron Lett. 1981, 22, 4819.
16. α-Epoxystannanes may constitute a unique subclass of α-stannylethers, since acyclic α-alkyloxystannanes are refractory under the same reaction conditions: Ye, J.; Bhatt, R. K.; Falck, J. R. J. Am. Chem. Soc. 1994, 116, 1.
17. In contrast, cross-couplings of α-epoxystannanes with thiol chloroformates, e.g., ethyl chlorothiolformate, were sluggish and good yields of adduct required co-catalysis by Pd salts.
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