Photochemically reactive polymers: Synthesis and photochemistry of polyamides containing Cp2Mo2(CO)6 molecules along the polymer backbone

Inorganica Chimica Acta

Volumn 242, Issue 1-2, 1996, Pages 303-310

  Nieckarz, Gregory F ^a   Tyler, David R ^a  

^a UNIVERSITY OF OREGON   (United States)

Author keywords

Carbonyl complexes; Cyclopentadienyl complexes; Molybdenum complexes; Photochemistry; Polyamide complexes

Indexed keywords

ABSORPTION SPECTROSCOPY; AMIDES; AMINES; BINARY ALLOYS; CHEMICAL ANALYSIS; CHEMICAL BONDS; CHLORINE COMPOUNDS; DIMERS; METALS; ORGANOMETALLICS; OXYGEN; PHOTOCHEMICAL REACTIONS; PHOTODEGRADATION; PHOTOLYSIS; POLYAMIDES; SYNTHESIS (CHEMICAL);

CARBONYL COMPLEXES; CYCLOPENTADIENYL COMPLEXES; ELECTRONIC ABSORPTION SPECTROSCOPY; MOLYBDENUM COMPLEX; PHOTOCHEMICAL DECOMPOSITIONS; PHOTOCHEMICALLY REACTIVE POLYMERS; PHOTOLYSIS REACTION; SPECTROSCOPIC CHARACTERIZATION;

MOLYBDENUM COMPOUNDS;

EID: 0006366312     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/0020-1693(95)04880-4     Document Type: Article

References (39)

1. (a) N. Grassie and G. Scott, Polymer Degradation and Stabilisation, Cambridge University Press, New York, 1985;
2. (b) J. Guillet, Polymer Photophysics and Photochemistry, Cambridge University Press, Cambridge, 1985.
3. J.F. Rabek, Mechanisms of Photophysical Processes and Photochemical Reactions in Polymers, Wiley, New York, 1987.
4. G. Geuskens, in C.H. Bamford and C.F.H. Tipper (eds.), Comprehensive Chemical Kinetics, Vol. 14, Elsevier, New York, 1975, pp. 333-424.
5. J.E. Guillet, in S.A. Barenberg, J.L. Brash, R. Narayan and A.E. Redpath (eds.), Degradable Materials, CRC Press, Boston, MA, 1990, pp. 55-97.
6. R. West and J. Maxka, in M. Zeldin, K.J. Wynne and H.R. Allcock (eds.), Inorganic and Organometjallic Polymers, ACS Symposium Series 360, American Chemical Society, Washington, DC, 1988, Ch. 2.
7. R. West, L'actualite Chimique (1984) 64.
8. R. West, J. Organomet. Chem., 300 (1986) 327.
9. D.C. Hofer, R.D. Miller, C.G. Willson and A.R. Neureuther, SPIE, Adv. Resist Technol., 469 (1984) 108.
10. M. Ishikawa and K. Nate, in M. Zeldin, K. Wynne and H.R. Allcock (eds.), Inorganic and Organometallic Polymers, ACS Symposium Series 360, American Chemical Society, Washington, DC, 1988, Ch. 16.
11. S. Yajima, J. Hayashi and M. Omori, Chem. Lett. (1975) 931.
12. S. Yajima, Ceram. Bull., 62 (1983) 8, 893.
13. R.M. Laine, Y.D. Blum, D. Tse and R. Glaser, in M. Zeldin, K.J. Wynne and H.R. Allcock (eds.), Inorganic and Organometallic Polymers, ACS Symposium Series 360, American Chemical Society, Washington, DC, 1988, Ch. 10.
14. D. Gilead, in S.A. Barenberg, J.L. Brash, R. Narayan and A.E. Redpath (eds.), Degradable Materials, CRC Press, Boston, 1990, pp. 191-207.
15. J.F. Rabek, Mechanisms of Photophysical Processes and Photochemical Reactions in Polymers, Wiley, New York, 1987., p. 567.
16. G.S. Upton, in S.A. Barenberg, J.L. Brash, R. Narayan and A.E. Redpath, (eds.), Degradable Materials, CRC Press, Boston, MA, 1990, pp. 179-189.
17. J.E. Guillet, in S.A. Barenberg, J.L. Brash, R. Narayan and A.E. Redpath (eds.), Degradable Materials, CRC Press, Boston, MA, 1990, p. 560.
18. S.C. Tenhaeff and D.R. Tyler, Organometallics, 10 (1991) 473-482.
19. S.C. Tenhaeff and D.R. Tyler, Organometallics, 10 (1991) 1116-1123.
20. S.C. Tenhaeff and D.R. Tyler, Organometallics, 11 (1992) 1466-1473.
21. (a) T.J. Meyer and J.V. Caspar, Chem. Rev., 85 (1985) 187;
22. (b) G.L. Geoffroy and M.S. Wrighton, Organometallic Photochemistry, Academic Press, New York, 1979.
23. (a) C.U. Pittman, Jr. and M.D. Rausch, Pure Appl. Chem., 58 (1986) 617;
24. (b) C.M. Casodo, M. Moran, J. Losada, and I. Cuodrado, Inorg. Chem., 34 (1995) 1668-1680.
25. K. Gonsalves, Lin Zhan-ru and M.D. Rausch, J. Am. Chem. Soc., 106 (1984) 3862.
26. K.E. Gonsalves, R.W. Lenz and M.D. Rausch, Appl. Organomet. Chem. (1987) 81.
27. F.W. Knobloch and W.H. Rauscher, J. Polym. Sci., 54 (1961) 651.
28. C.U. Pittman, Jr., J. Polym. Sci., Part A, 6 (1968) 1687.
29. K.E. Gonsalves and M.D. Rausch, J. Polym. Sci., Part A: Polym. Chem., 26 (1988) 2769.
30. W.J. Patterson and S.P. McManus, J. Polym. Sci.: Polym. Chem., 12 (1974) 837.
31. One recent example of a polymer with metal-metal bonds employing this synthetic strategy is found in: M. Moran, M.C. Pascual, I. Cuadrado and J. Losada, Organometallics, 12 (1993) 811-822.
32. A. Avey and D.R. Tyler, Organometallics, 11, (1992) 3856-3863.
33. B.E. Lindfors and D.R. Tyler, J. Photochem., submitted.
34. H.G. Heller and J.R. Langan, J. Chem. Soc., Perkin Trans., 2 (1981) 341-343.
35. R.M. Silverstein, G.C. Bassler and T. C. Morrill, Spectrometric Identification of Organic Compounds, 5th edn., Wiley, New York, 1991, pp. 185-186.
36. F.J. Golemba and J.E. Guillet, Macromolecules, 5 (1972) 212.
37. (a) M. Cousins and M.L.H. Green, J. Chem. Soc. (1964) 1567-1572;
38. (b) M. Cousins, and M. L.H. Green, J. Chem. Soc. (A) (1969) 16-19.;
39. F. Bottomley, E.C. Ferns and P.S. White, Organometallics, 9 (1990) 1166-1171.