Organometallic cluster complexes with face-capping arene ligands. 8. Nucleophilic reactivity of cluster complexes with face-capping arene ligands: Metal vs ligand protonation

Organometallics

Volumn 15, Issue 26, 1996, Pages 5622-5634

  Wadepohl, Hubert ^a   Calhorda, Maria José ^b,c   Herrmann, Michael ^a   Jost, Christof ^a   Lopes, Pedro E M ^b   Pritzkow, Hans ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

^b INSTITUTO DE TECNOLOGIA QUÍMICA E BIOLÓGICA   (Portugal)

^c INSTITUTO SUPERIOR TÉCNICO   (Portugal)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0006224970     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9605692     Document Type: Article

References (58)

1. (a) Pauson, P. L. in Methoden der organischen Chemie (Houben-Weyl); Falbe, J., Ed., Thieme: Stuttgart, Germany, 1986; Vol. E18, Chapter II.
2. (b) Watts, W. E. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: Oxford, U.K., 1982; Vol. 8, Chapter 59.
3. (c) Davies, S. G. Organotransition Metal Chemistry: Application to Organic Synthesis; Pergamon: Oxford, U.K., 1982; Chapter 4.1.6, 4.2.4.
4. (d) Kane-Maguire, L. A. P.; Honig, E. D.; Sweigart, D. A. Chem. Rev. 1984, 84, 525.
5. Wadepohl, H. Angew. Chem. 1992, 104, 253; Angew. Chem., Int. Ed. Engl. 1992, 31, 247 and references cited therein.
6. Wadepohl, H. Angew. Chem. 1992, 104, 253; Angew. Chem., Int. Ed. Engl. 1992, 31, 247 and references cited therein.
7. Braga, D.; Dyson, P. J.; Grepioni, F.; Johnson, B. F. G. Chem. Rev. 1994, 94, 1585 and references cited therein.
8. (a) Borchert, T.; Lewis, J.; Pritzkow, H.; Raithby, P. R.; Wadepohl, H. J. Chem. Soc., Dalton Trans. 1995, 1061.
9. (b) Borchert, T.; Lewis, J.; Pritzkow, H.; Raithby, P. R.; Shields, G. P.; Wadepohl, H. Manuscript in preparation.
10. (a) Gallop, M. A.; Johnson, B. F. G.; Lewis, J.; Wright, A. H. J. Chem. Soc., Dalton Trans. 1989, 481;
11. (b) Edwards, A. J.; Gallop, M. A.; Johnson, B. F. G.; Köhler, J. U.; Lewis, J.; Raithby, J. R. Angew. Chem. 1994, 106, 1166; Angew. Chem., Int. Ed. Engl. 1994, 33, 1093.
12. (b) Edwards, A. J.; Gallop, M. A.; Johnson, B. F. G.; Köhler, J. U.; Lewis, J.; Raithby, J. R. Angew. Chem. 1994, 106, 1166; Angew. Chem., Int. Ed. Engl. 1994, 33, 1093.
13. (a) Wadepohl, H.; Büchner, K.; Pritzkow, H. Angew. Chem. 1987, 99, 1294; Angew. Chem., Int. Ed. Engl. 1987, 26, 1259.
14. (a) Wadepohl, H.; Büchner, K.; Pritzkow, H. Angew. Chem. 1987, 99, 1294; Angew. Chem., Int. Ed. Engl. 1987, 26, 1259.
15. (b) Wadepohl, H.; Büchner, K.; Herrmann, M.; Pritzkow, H. Organometallics 1991, 10, 861.
16. (c) Wadepohl, H.; Borchert, T.; Büchner, K.; Herrmann, M.; Paffen, F.-J.; Pritzkow, H. Organometallics 1995, 14, 3817.
17. Wadepohl, H.; Borchert, T.; Pritzkow, H. J. Organomet. Chem. 1996, 516, 187.
18. Wadepohl, H.; Pritzkow, H. J. Organomet. Chem. 1993, 450, 9.
19. (a) Wadepohl, H.; Borchert, T.; Büchner, K.; Pritzkow, H. Chem. Ber. 1993, 126, 1615.
20. (b) Wadepohl, H.; Borchert, T.; Pritzkow, H. J. Chem. Soc., Chem. Commun. 1995, 1447.
21. (c) Wadepohl, H.; Borchert, T.; Pritzkow, H. Chem. Ber., in press.
22. Wadepohl, H. In The Synergy Between Dynamics and Reactivity at Clusters and Surfaces; Farrugia, L. J., Ed.; Nato ASI Series C: Mathematical and Physical Sciences, Vol. 465; Kluwer, Dordrecht, 1995; p 175.
23. Wadepohl, H.; Gebert, S. Coord. Chem. Rev. 1995, 143, 535.
24. Wadepohl, H.; Herrmann, M.; Jost, C.; Müller, S. Manuscript in preparation.
25. Jost, C. Zulassungsarbeit; Universität Heidelberg, 1995.
26. Using ΔG° = -RT ln(K) (van't Hoff reaction isotherm). ΔG° is the standard enthalpy of reaction for the conversion of the two isomers.
27. Vogel, P. Carbocation Chemistry; Elsevier: Amsterdam, 1985; Chapter 4.
28. (a) Seyferth, D. Adv. Organomet. Chem. 1976, 14, 97.
29. (b) Seyferth, D.; Williams, G. H.; Nivert, C. L. Inorg. Chem. 1977, 16, 758.
30. (c) Schilling, B. E. R.; Hoffmann, R. J. Am. Chem. Soc. 1978, 100, 6274; 1979, 101, 3456.
31. (c) Schilling, B. E. R.; Hoffmann, R. J. Am. Chem. Soc. 1978, 100, 6274; 1979, 101, 3456.
32. (d) Edidin, R. T.; Norton, J. R.; Mislow, K. Organometallics 1982, 1, 561.
33. McGlinchey, M. J.; Girard, L.; Ruffolo, R. Coord. Chem. Rev. 1995, 143, 331.
34. Acampora, M.; Ceccon, A.; Dal Farra, M.; Giacometti, G.; Rigatti, G. J. Chem. Soc., Perkin Trans. 2 1977, 483.
35. Olah, G. A.; Yu, S. H. J. Org. Chem. 1976, 41, 1694.
36. Wadepohl, H.; Zhu, L. J. Organomet. Chem. 1989, 376, 115.
37. (a) Gallop, M. A.; Gomez-Sal, M. P.; Housecraft, C. E.; Johnson, B. F. G.; Lewis, J.; Owen, S. M.; Raithby, P. R.; Wright, A. H. J. Am. Chem. Soc. 1992, 114, 2502.
38. (b) Riehl, J.-F.; Koga, N.; Morokuma K. Organometallics 1993, 12, 4788.
39. Downton, P. A.; Sayer, B. G.; McGlinchey, M. J. Organometallics 1992, 11, 3281.
40. Wadepohl, H.; Gebert, S.; Pritzkow, H.; Braga, D. Chem. Eur. J., submitted for publication.
41. Pellecchia, C.; Immirzi, A.; Pappalardo, D.; Peluso, A. Organometallics 1994, 13, 3773.
42. (a) Friend, C. M.; Muetterties, E. L. J. Am. Chem. Soc. 1981, 103, 773.
43. (b) Tsai, Min-Chi; Muetterties, E. L. J. Phys. Chem. 1982, 86, 5067.
44. (c) Avery, N. R. J. Chem. Soc., Chem. Commun. 1988, 153.
45. Wadepohl, H.; Büchner, K.; Pritzkow, H. Organometallics 1989, 8, 2745.
46. 13
47. Herrmann, M. Dissertation, Heidelberg, 1991.
48. (a) SHELXS-86, Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467. SHELXL-93: Sheldrick, G. M. Universität Göttingen, 1993.
49. (a) SHELXS-86, Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467. SHELXL-93: Sheldrick, G. M. Universität Göttingen, 1993.
50. Johnson, C. K. ORTEP-II; Report ORNL-5138; Oak Ridge National Laboratory: Oak Ridge, TN.
51. (a) Hoffmann, R. J. Chem. Phys. 1963, 39, 1397.
52. (b) Hoffmann, R.; Lipscomb, W. N. J. Chem. Phys. 1962, 36, 2179, 3489.
53. Ammeter, J. H.; Bürgi, H.-B.; Thibeault, J. C.; Hoffmann, R. J. Am. Chem. Soc. 1978, 100, 3686.
54. Mealli, C.; Proserpio, D. M. J. Chem. Educ. 1990, 67, 39.
55. (a) Baerends, E. J.; Ellis, D. E.; Ros, P. Chem. Phys. 1973, 2, 42.
56. (b) Baerends, E. J.; Ros, P. Int. J. Quantum Chem. 1978, S12, 169.
57. Vosko, S. H.; Wilk, L.; Nusair, M. Can. J. Phys. 1980, 58, 1200.
58. Perdew, J. P.; Wang, Y. Phys. Rev. B 1986, 33, 8800.