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Volumn 8, Issue , 1996, Pages 1775-1779

Absolute rate constants for abstraction of chlorine from three chlorinating agents by alkyl radicals

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EID: 0006201162     PISSN: 03009580     EISSN: None     Source Type: Journal    
DOI: 10.1039/p29960001775     Document Type: Article
Times cited : (10)

References (41)
  • 2
    • 0042142893 scopus 로고
    • ed. E. S. Huyser, Marcel Dekker, New York
    • For an excellent review, see M. L. Poutsma, in Methods in Free Radical Chemistry, ed. E. S. Huyser, Marcel Dekker, New York, 1969, vol. 1, pp. 79-193.
    • (1969) Methods in Free Radical Chemistry , vol.1 , pp. 79-193
    • Poutsma, M.L.1
  • 3
    • 85088545220 scopus 로고    scopus 로고
    • 6
    • 6
  • 17
    • 0001187021 scopus 로고
    • The vapour phase chlorination of methylcyclopropane was reported earlier by Roberts to yield primarily cyclopropylcarbinyl chloride and 4-chlorobut-1-ene (in comparable yields), and a small amount of ring-chlorinated products (see J. D. Roberts and P. H. Dirstine, J. Am. Chem. Soc., 1945, 67, 1281).
    • (1945) J. Am. Chem. Soc. , vol.67 , pp. 1281
    • Roberts, J.D.1    Dirstine, P.H.2
  • 18
    • 0001658560 scopus 로고
    • H2 vs. hydrogen abstraction) observed in the gas phase vs. solution has been attributed to solvent internal pressure, see J. M. Tanko and N. K. Suleman, J. Am. Chem. Soc., 1994, 116, 5162.
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 5162
    • Tanko, J.M.1    Suleman, N.K.2
  • 19
    • 0000569988 scopus 로고
    • 2 + Cl·). With benzene as a solvent, the cage-walls are highly reactive towards chlorine atom, thereby virtually supressing the in-cage hydrogen abstraction. See P. S. Skell and H. N. Baxter, III, J. Am. Chem. Soc., 1985, 107, 2823;
    • (1985) J. Am. Chem. Soc. , vol.107 , pp. 2823
    • Skell, P.S.1    Baxter III, H.N.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.