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The vapour phase chlorination of methylcyclopropane was reported earlier by Roberts to yield primarily cyclopropylcarbinyl chloride and 4-chlorobut-1-ene (in comparable yields), and a small amount of ring-chlorinated products (see J. D. Roberts and P. H. Dirstine, J. Am. Chem. Soc., 1945, 67, 1281).
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