Actinide Complexation Kinetics: Rate and Mechanism of Dioxoneptunium(V) Reaction with Chlorophosphonazo III

Radiochimica Acta

Volumn 73, Issue 2, 1996, Pages 67-72

  Fugate, Glenn ^a   Feil Jenkins, Janine F ^a   Sullivan, James C ^a   Nash, Kenneth L ^a  

^a ARGONNE NATIONAL LABORATORY   (United States)

Author keywords

Activation; Chelation; Chlorophosphonazo III; Neptunium; Parameters; Rate and mechanism

Indexed keywords

EID: 0006130071     PISSN: 00338230     EISSN: None     Source Type: Journal    
DOI: 10.1524/ract.1996.73.2.67     Document Type: Article

References (22)

1. Nash, K. L., Sullivan, J. C.: Kinetics of complexation and redox reactions of the lanthanides in aqueous solution, in Handbook of the Physics and Chemistry of Rare Earths, Vol. 15 (K. A. Gschneidner, Jr. and L. Eyring. eds.) Elsevier Science Publishers, B. V., pp. 347-391 (1991).
2. Nash, K. L., Sullivan, J. C.: Kinetics and mechanisms of actinide redox and complexation reactions, in Advances in Inorganic and Bioinorganic Reaction Mechanisms (A. G. Sykes, ed.), Academic Press, London, pp. 205-213 (1986).
3. Feil-Jenkins, J. F., Nash, K., Sullivan, J. C.: Kinetics of the Complexation Reactions between Th(IV), Zr(IV) and Chlorophosphonazo III. Radiochim. Acta 68, 215 (1995).
4. Feil-Jenkins, J. F., Sullivan, J. C., Nash, K. L.: Kinetics of the Complexation of Dioxouranium(VI) with Chlorophoshonazo III. Radiochim. Acta 68, 209 (1995).
5. Hines, M. A., Sullivan, J. C., Nash, K. L.: Inorg. Chem. 32, 1820 (1993).
6. Nash, K. L., Horwitz, E. P.: Inorg. Chim. Acta 169, 245 (1990).
7. Nash, K. L.: Radiochim. Acta 61, 147 (1993).
8. Nash, K. L.: Radiochim. Acta 54, 171 (1991).
9. Nash, K. L., Rao, L. F., Choppin, G. R.: A calorimetric and laser induced fluorescence investigation of the complexation geometry of selected europium-(gem)diphosphonate complexes in acidic solutions. Inorg. Chem. 34, 2753 (1995).
10. Sjoblom, R., Hindman, J. C.: J. Am. Chem. Soc. 73, 1744 (1951).
11. Chudinov, E. G., Yakovlev, G. N.: Sov. Radiochem. 4(5), 526 (1962). Translated from Radiokhimiya 4(6), 601 (1962).
12. Chudinov, E. G., Yakovlev, G. N.: Sov. Radiochem. 4(5), 526 (1962). Translated from Radiokhimiya 4(6), 601 (1962).
13. Ferguson, J. W., Richard, J. J., O'Laughlin, J. W., Banks, G. V.: Anal. Chem. 36, 796 (1964).
14. Men'kov, A. A., Nepomnyashchaya, N. A.: Russian J. Inorg. Chem. 22(8), 1155 (1977). Translated from Zh. Neorg. Khim. 22, 2135 (1977).
15. Men'kov, A. A., Nepomnyashchaya, N. A.: Russian J. Inorg. Chem. 22(8), 1155 (1977). Translated from Zh. Neorg. Khim. 22, 2135 (1977).
16. Budesinsky, B.: Monoarylazo and bis(arylazo) derivatives of chromotropic acid as photometric reagents, in Chelates in Analytical Chemistry, Vol. 2 (H. A. Flaschka and A. J. Barnard, Jr. eds.) Marcel Dekker, New York, pp. 1-91 (1969).
17. Nyssen, G. A., Margerum, D. W.: Inorg. Chem. 9, 1814 (1970).
18. Cossy, C., Helm, L., Merbach. A. E.: Inorg. Chem. 28, 2699 (1989).
19. Micskei, M., Heum, L., Brücher, E., Merbach, A. E.: Inorg. Chem. 32, 3844 (1993).
20. Linert, W.: Chem. Soc. Rev. 23, 429 (1994).
21. Shannon, R. D.: Acta Crystallogr. A 32, 751 (1976).
22. Rizkalla, E. N., Choppin, G. R.: Lanthanides and actinides hydration and hydrolysis, in Handbook of the Physics and Chemistry of the Rare Earths, Vol. 18, (K. A. Gschneidner, Jr. and L. Eyring, eds.) Elsevier Science Publishers, Amsterdam (1994), pp. 529-558.