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53249115670
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2 (88% of crude product).
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16
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53249119739
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(a) Use of commercially available 2-bromo-2-butene (Aldrich Chem. Co., Milwaukee, WI) which consists of 80-90% of 2-bromo-trans-2-butene ultimately gives Cp‡H in lower yield (44%) and purity (62%).
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17
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53249136418
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note
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2 complex was obtained in 67% yield from the 62% purity Cp‡H above with the use of a 2.5-fold excess of the Cp‡H product.
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