First structurally characterised lithium hexafluorophosphate complexes with acyclic Lewis bases: Ion-separated [Li2(hmpa)5] 2+·2(PF6-) and ion-contacted [(pmdeta)LiPF6]2 [hmpa = (Me2N)3PO; pmdeta = MeN(CH2CH2NMe2)2]

Chemical Communications

Volumn , Issue 9, 1998, Pages 1011-1012

  Armstrong, David R ^a   Khandelwal, Amit H ^b   Kerr, Lesley C ^c   Peasey, Sonja ^c   Raithby, Paul R ^c   Shields, Gregory P ^c   Snaith, Ronald ^c   Wright, Dominic S ^c  

^a UNIVERSITY OF STRATHCLYDE   (United Kingdom)

^b DEFENCE SCIENCE AND TECHNOLOGY LABORATORY   (United Kingdom)

^c UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0006011443     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a801280f     Document Type: Article

References (19)

1. G. Pistoia, Lithium batteries: new materials, developments and perspectives, Industrial Chemistry Library, Elsevier, Amsterdam, 1994, vol. 5;
2. A. G. Ritchie, Philos. Trans. R. Soc. London A, 1996, 354, 1643.
3. 6 complexes are known, all containing cyclic ligands and all being ion-separated: R. Schwesinger, K. Piontek, W. Littke and H. Prinzbach, Tetrahedron Lett., 1985, 26, 1201;
4. E. C. Constable, L.-Y. Chung, J. Lewis and P. R. Raithby, J. Chem. Soc., Chem. Commun., 1986, 1719;
5. E. C. Constable, M. J. Doyle, J. Healy and P. R. Raithby, ibid., 1988, 1262;
6. C. G. Choo, S. D. Rychnovsky and M. C. Etter, Chem. Mater., 1994, 6, 1200.
7. R. Snaith and D. S. Wright, in Lithium Chemistry: A Theoretical and Experimental Overview, eds. A.-M. Sapse and P. v. R. Schleyer, Wiley, New York, 1995, ch. 8.
8. P. S. Gentile, J. G. White and D. D. Cavalluzzo, Inorg. Chim. Acta, 1976, 20, 37.
9. D. Barr, M. J. Doyle, R. E. Mulvey, P. R. Raithby, D. Reed, R. Snaith and D. S. Wright, J. Chem. Soc., Chem. Commun., 1989, 318.
10. D. Stalke and D. S. Wright, unpublished work.
11. (a) R. V. Honeychuck and W. W. Hersh, Inorg. Chem., 1989, 28, 2869
12. (b) J. M. Maud, J. F. Stoddart, H. M. Colquhoun and D. J. Williams, Polyhedron, 1984, 3, 675
13. (c) P. D. Beer, H. Sikanyika, C. Blackburn, J. F. McAleer and M. G. B. Drew, J. Chem. Soc., Dalton Trans., 1990, 3295.
14. W. J. Hehre, R. Ditchfield and J. A. Pople, J. Chem. Phys., 1972, 56, 2257;
15. P. C. Hariharan and J. A. Pople, Theor. Chim. Acta, 1973, 28, 213;
16. J. D. Dill and J. A. Pople, J. Chem. Phys., 1975, 62, 2921.
17. M. Dupuis, D. Spangler and J. J. Wendoloski, GAMESS NRCC Software Catalogue, Program No. 2 GOI, vol. 1, 1980;
18. M. F. Guest, J. Kendrick and S. A. Pope, GAMESS Documentation, Daresbury Laboratory, Warrington, UK, 1983;
19. M. F. Guest, P. Fantucci, R. J. Harrison, J. Kendrick, J. H. van Lenthe, K. Schoeffel and P. Sherwood, GAMESS-UK Daresbury (CFS Ltd., 1993).