Synthesis and dynamic behavior of the dimeric, monocyclic barium bis[bispropyldimethylphosphanide] - Molecular structurtes of P(SiMe2Ph)3, of momomieric (thf)4Ba[P(SiMe2iPr)2]2 and of the dimer {thf2Ba[P(SiMe2iPr)2]2}2

Chemische Berichte

Volumn 129, Issue 9, 1996, Pages 1035-1040

  Westerhausen, Matthias ^a   Lang, Gerhard ^a   Schwarz, Wolfgang ^a  

^a UNIVERSITY OF STUTTGART   (Germany)

Author keywords

Barium bis(phosphanide); Bis(silyl)phosphanes; Phosphanes; Phosphanides; Tris(silyl)phosphanes

Indexed keywords

EID: 0005883745     PISSN: 00092940     EISSN: None     Source Type: Journal    
DOI: 10.1002/cber.19961290910     Document Type: Article

References (35)

1. M. Westerhausen, W. Schwarz, Z. Anorg. Aug. Chem. 1992, 609, 39;
2. M. Westerhausen, W. Schwarz, ibid. 1991, 604, 127;
3. M. Westerhauseri, W. Schwarz, ibid. 1991, 606, 177;
4. B. A. Vaanstra, 1 C. Huffman, W. E. Streib, K. G. Caulton, Inorg. Chem. 1991, 30, 121.
5. M. Westerhausen. Inorg. Chem. 1991, 30, 96.
6. M. Westerhauscn, J. Organomet. Chem. 1994, 479, 141.
7. G. W. Rabe, J. Riede, A. Schier, Organometallics 1996, 15, 439.
8. Review: E Pauer, P. P. Power in Lithium Chemistry: a Theoretical and Experimental Overview (Eds.: A.-M. Sapse, P. v. R. Schleyer), Wiley-Interscience, New York, 1995, chapter 9;
9. see also: E. Hey-Hawkins, E. Sattler, J. Chem. Soc., Chem. Commun. 1992, 775:
10. G. Becker, H. M. Hartmann, W. Schwarz, Z. Anorg. Aug. Chem. 1989, 577, 9;
11. E. Hey, P. B. Hitchcock, M. F. Lappert, A. K. Rai, J. Organomet. Chem. 1987, 325, 1.
12. S. C. Goei. M. Y. Chiang. W. E. Buhro, J. Am. Chem. Soc. 1990, 112, 5636;
13. S. C. Goel, M. Y. Chiang, D. J. Rauscher, W. E. Buhro, ibid. 1993, 115, 160;
14. B. Rademacher, W. Schwarz, M. Westerhausen, Z. Anorg. Alig. Chem. 1995, 621, 287.
15. M. Westerhausen, M. Hartmann, W. Schwarz, Inorg. Chem. 1996,55,2421.
16. M. Westerhausen, R. Löw, Universität Stuttgart, unpublished results;
17. for the magnesium and calcium bis(phosphanides) see also: M. Westerhausen, R. Low, W. Schwarz, / Organomet. Chem. 1996, 513, 213.
18. H. Bürger, U. Goetze, J. Organomet. Chem. 1968, 12. 451;
19. E. Fluck, H. Bürger, U. Goetze, Z. Natur forsch., Par! B, 1967, 22, 912;
20. W. Uhlig, A. Tzschach, Z. Anorg. All g. Chem. 1989, 576, 281.
21. G. Becker, H. Schmidt, G. UM, W. UM, Inorg. Svnth. 1990, 27, 243.
22. H. Schäfer, G. Friîz, W. Hölderich, Z. Anorg. AHg. Chem. 1977, 428, 222;
23. M. Baudler, K. Glinka, Inorg. Synih. 1990, 27, 228.
24. K. Hassler, Monatsh. Chem. 1988, 119, 851; 119, 863.
25. G. A. Forsyth, D. W. H. Rankin, H. E. Robertson, J. Mol Struct. 1990, 239, 209.
26. M. Westerhausen, A. Pfitzner, J. Organomet. Chem. 1995, 487, 187.
27. M. Westerhausen, W. Schwarz, J. Organomet. Chem. 1993, 463, 51.
28. M. Westerhausen, H.-D. Hausen, W. Schwarz, Z. Anorg. Aug. Chem. 1995, 621, 877.
29. M. Schütze, Angew. Chem. 1958, 70, 697.
30. Further details of the crystal structure investigations are available on request from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoidshafen, on quoting the depository numbers CSD-405066, -405067, and -405065 for 2c, 3A, and 3B, respectively.
31. Hahn (Ed.), International Tables for Crystallography, vol. A, Space Group Symmetry, 2nd Ed., D. Reidel, Dordrecht, 1984.
32. SHELXLTL Plus, Siemens Analytical X-Ray Instruments, Inc., 1980.
33. G. M. Sheldrick, SHELXL-93, Universität Göttingen, 1993.
34. D. T. Comer, J. B. Mann, Ada Crvstallogr., Sect. A, 1968, 24,
35. R. F. Stewart, E. R. Davidson, W. T. Simpson, J. Chem. Phvs. 1965, 42, 3175.