Hydantoin Derivatives as Spacers for Crystal Engineering in the Chemistry of Heavy Alkali Metal Ions: Synthesis and Crystal Structure of Layered (CsLOH)∞ (L = 5,5-Dimethyl-4-oxoimidazolidine-2-thione)

Inorganic Chemistry

Volumn 37, Issue 17, 1998, Pages 4164-4165

  Arca, Massimiliano ^a   Demartin, Francesco ^b   Devillanova, Francesco A ^a   Garau, Alessandra ^a   Isaia, Francesco ^a   Lippolis, Vito ^a   Verani, Gaetano ^a  

^a UNIVERSITY OF CAGLIARI   (Italy)

^b UNIVERSITY OF MILAN   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0005857461     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980368l     Document Type: Article

References (21)

1. 2S were obtained.
2. w = 0.041.
3. Ab initio SCF calculations with geometry optimization and frequency calculation were performed in the 6-311G** basis set [(a) Pople, J. A. J. Chem. Phys. 1980, 72, 650. (b) Curtis, L. A.; McGrath, M. P.; Blandeau, J.-P.; Davis, N. E.; Binning, R. C., Jr.; Radom, L. J. Chem. Phys. 1995, 103, 6104] with Gaussian 94W.
4. Ab initio SCF calculations with geometry optimization and frequency calculation were performed in the 6-311G** basis set [(a) Pople, J. A. J. Chem. Phys. 1980, 72, 650. (b) Curtis, L. A.; McGrath, M. P.; Blandeau, J.-P.; Davis, N. E.; Binning, R. C., Jr.; Radom, L. J. Chem. Phys. 1995, 103, 6104] with Gaussian 94W.
5. (c) Gaussian 94, Revision D.1; Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Gill, P. M. W.; Johnson, B. G.; Robb, M. A.; Cheeseman, J. R.; Keith, T. A.; Petersson, G. A.; Montgomery, J. A.; Raghavachari, K.; Al-Laham, M. A.; Zakrzewski, V. G.; Ortiz, J. V.; Foresman, J. B.; Peng, C. Y.; Ayala, P. Y.; Wong, M. W.; Andres, J. L.; Replogle, E. S.; Gomperts, R.; Martin, R. L.; Fox, D. J.; Binkley, J. S.; Defrees, D. J.; Baker, J.; Stewart, J. P.; Head-Gordon, M.; Gonzales, C.; Pople, J. A., Gaussian, Inc., Pittsburgh, PA, 1995. Full geometry optimization was performed with conventional Gaussian default convergence criteria from a starting geometry obtained at AM1 level.
6. (d) Dewar, M.; Thiel, W. J. Am. Chem. Soc. 1977, 99, 4499.
7. (e) Davis, L. P.; Guidry, R. M.; Williams, J. R.; Dewar, M. J.; Rzepa, H. S. J. Comput. Chem. 1981, 2, 433.
8. Cristiani, F.; Demartin, F.; Devillanova, F. A.; Isaia, F.; Saba, G.; Verani, G. J. Chem. Soc., Dalton Trans. 1992, 3553.
9. Cristiani, F.; Devillanova, F. A.; Isaia, F.; Verani, G.; Battaglia, L.; Bonamartini Corradi, A. J. Chem. Res. (S) 1989, 32.
10. ∞ are the following (in parentheses the corresponding values of pure L): 198.3 (182) for C=O, 194.4 (181) for C=S, 64.2 (64.8) for C(5), and 25.9 and 23.1 (25.3) for the methyl groups bonded to C(5).
11. Ellaboudy, A.; Dye, J. L. J. Am. Chem. Soc. 1983. 105, 6490.
12. Jacobs, V. H.; Harbrecht, B.; Müller, P.; Bronger, W. Z. Anorg. Allg. Chew. 1982, 491, 154.
13. Mootz, D.; Rütter, H. Z. Anorg. Allg. Chem. 1992, 608, 123.
14. (a) Greenwood, N. N.; Earnshow, A. Chemistry of the elements; Oxford: Pergamon; 1984.
15. (b) Kasuga, N.; Nakahama, S.; Yamaguchi, K., Ohashi, Y.; Hori, K. Bull. Chem. Soc. Jpn. 1991, 64, 3548.
16. Assmus, R.; Böhmer, V.; Harrowfield, J. M.; Ogden, M. I.; Richmond, W. R.; Skelton, B. W.; White, A. H. J. Chem. Soc., Dalton Trans. 1993. 2427.
17. (d) Thuéry, P.; Nierlich, M.; Bryan, J. C.; Lamare, V.; Dozol, J.-F.; Asfari, Z.; Vicens, J. J. Chem. Soc., Dalton Trans. 1997, 4191.
18. (e) Domasevitch, K. V.; Onomareva, V. V.; Rusanov, E. B. J. Chem. Soc., Dalton Trans. 1997, 1177 and references therein.
19. Fredericks, J. R.; Hamilton, A. D. in Comprehensive Supramolecular Chemistry; Atwood, J. L., Eric, J., Davies, D., MacNicol, D. D., Vögtle, F., Eds.; Pergamon: Oxford, 1996; Vol. 9.
20. (a) Subramanian, S.; Zaworotko, M. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 2127.
21. (b) Withersby, M. A.; Blake, J. B.; Champness, N. R.; Hubberstey, P.; Li, W.-S.; Schröder, M. Angew. Chem., Int. Ed. Engl. 1997, 36, 2027 and references therein.