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Volumn 62, Issue 21, 1997, Pages 7090-7091

7,14-Dichloro[1.1]metacyclophane: A Highly Strained Aromatic Intermediate

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Indexed keywords


EID: 0005846440     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo971411+     Document Type: Article
Times cited : (6)

References (28)
  • 3
    • 85033147035 scopus 로고    scopus 로고
    • In the case of [5]- and [6]metacyclophanes the thermal stability increases upon chlorine substitution
    • (a) In the case of [5]- and [6]metacyclophanes the thermal stability increases upon chlorine substitution.
  • 7
    • 33748596996 scopus 로고
    • (d) Wijsman, G. W.; Van Es, D. S.; De Wolf, W. H.; Bickelhaupt, F. Angew. Chem. 1993, 105, 739. Angew. Chem., Int. Ed. Engl. 1993, 32, 726.
    • (1993) Angew. Chem., Int. Ed. Engl. , vol.32 , pp. 726
  • 8
    • 85033129754 scopus 로고    scopus 로고
    • 13C NMR and mass spectroscopic methods.
    • 13C NMR and mass spectroscopic methods.
  • 9
    • 85033157871 scopus 로고    scopus 로고
    • note
    • 37Cl 214.0367, Found 214.0369 ± 0.0006.
  • 10
    • 85033154077 scopus 로고    scopus 로고
    • See Supporting Information
    • See Supporting Information.
  • 14
    • 85033155737 scopus 로고    scopus 로고
    • Hydroxide ions are derived from small amounts of water present in the reaction mixture, which in small scale reactions is unavoidable due to the hygroscopic nature of DMSO and t-BuOK
    • Hydroxide ions are derived from small amounts of water present in the reaction mixture, which in small scale reactions is unavoidable due to the hygroscopic nature of DMSO and t-BuOK.
  • 20
    • 84988129057 scopus 로고
    • Stewart, J. J. P. J. Comput. Chem. 1989, 10, 209. The calculations were performed using MOPAC 93 (QCPE No. 445).
    • (1989) J. Comput. Chem. , vol.10 , pp. 209
    • Stewart, J.J.P.1
  • 22
    • 85033138825 scopus 로고    scopus 로고
    • 14b,c
    • 14b,c
  • 27
    • 85033148460 scopus 로고    scopus 로고
    • -) = -73.2 kJ/mol (PM3)
    • -) = -73.2 kJ/mol (PM3).
  • 28
    • 85033127121 scopus 로고    scopus 로고
    • note
    • - to 6.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.