Hydrogen-halogen exchange reactions of (η5:η5-C10H8)W 2(CO)4(PPh2Me)2H2 with CCl4 and CHI3; Characterization of (η5:η5-C10H8)W 2(CO)4(PPh2Me)2X2 (X=Cl, I)

Journal of Organometallic Chemistry

Volumn 584, Issue 2, 1999, Pages 347-355

  Kovacs, Istvan ^a   Pearson, Celine ^a   Shaver, Alan ^a  

^a MCGILL UNIVERSITY   (Canada)

Author keywords

Carbonyl complexes; Crystal structure; Fulvalene complexes; Hydrogen halogen exchange; Isomerization; Metal halides; Metal hydrides; NMR spectroscopy; Phosphine substitution; Tungsten complexes

Indexed keywords

EID: 0005730245     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(99)00174-6     Document Type: Article

References (20)

1. T.L. Brown, in: W.C. Trogler (Ed.), Organometallic Radical Processes, J. Organomet. Chem. Library 22, Elsevier, New York, 1990, p. 67 and references therein.
2. (a) M. Tilset, K.P.C. Vollhardt, R. Boese, Organometallics 13 (1994) 3146.
3. (b) I. Kovacs, M.C. Baird, Organometallics 14 (1995) 4074.
4. (c) I. Kovacs, M.C. Baird, Organometallics 15 (1996) 3588.
5. (d) I. Kovacs, A. Shaver, J. Organomet. Chem. 586 (1999) 31.
6. (a) R. Moulton, T.W. Weidman, K.P.C. Vollhardt, A.J. Bard, Inorg. Chem. 25 (1986) 1846.
7. (b) I. Kovacs, M.C. Baird, Organometallics 14 (1995) 4084.
8. (c) C. Moreno, M.L. Marcos, M.J. Macazaga, R.M. Medina, D.H. Farrar, J. Gonzalez-Velasco, S. Delgado, Organometallics 17 (1998) 4657.
9. (d) M.L. Marcos, C. Moreno, R.M. Medina, M.-J. Macazaga, S. Delgado, J. Gonzalez-Velasco, J. Organomet. Chem. 568 (1998) 185.
10. (e) C. Moreno, M.-J. Macazaga, R.-M. Medina, D.H. Farrar, S. Delgado, Organometallics 17 (1998) 3733.
11. Recent reviews relevant to fulvalene chemistry: (a) P.A. McGovern, K.P.C. Vollhardt, Synlett (1990) 493.
12. (b) N.J. Coville, K.E. duPlooy, W. Pickl, Coord. Chem. Rev. 116 (1992) 1.
13. (c) M.D. Ward, Chem. Soc. Rev. 24 (1995) 121.
14. (d) H. El Amouri, M. Gruselle, Chem. Rev. 96 (1996) 1077.
15. (e) D. Astruc, Acc. Chem. Res. 30 (1997) 383.
16. (f) S. Barlow, D. O'Hare, Chem. Rev. 97 (1997) 637.
17. Meyerhoff D.J., Nunlist R., Tilset M., Vollhardt K.P.C. Magn. Res. Chem. 24:1986;709.
18. (a) T.T. Chin, W.E. Geiger, Organometallics 14 (1995) 1316.
19. (b) D.L. Lichtenberger, N.E. Gruhn, M.E. Rempe, W.E. Geiger, T.T. Chin, Inorg. Chim. Acta 240 (1995) 623.
20. (c) R. Winter, D.T. Pierce, W.E. Geiger, T.J. Lynch, J. Chem. Soc. Chem. Commun. (1994) 1949.