Nuclear magnetic relaxation measurements on liquid acetonitrile and acetonitrile water mixtures

Zeitschrift fur Physikalische Chemie

Volumn 214, Issue 12, 2000, Pages 1633-1657

  Hardy, E H ^a,b   Zygar, A ^a   Zeidler, M D ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

^b ETH ZURICH   (Switzerland)

Author keywords

Binary critical mixtures; Deuterium quadrupole coupling constants; Isotope effects; Liquid acetonitrile and acetonitrile water; NMR

Indexed keywords

ACTIVATION ENERGY; AMMONIA; ANISOTROPY; BINARY MIXTURES; DEUTERIUM; LIQUIDS; MOLECULES; NUCLEAR MAGNETIC RESONANCE; PROTONATION; THERMODYNAMICS;

ACETONITRILE-WATER MIXTURE; BINARY CRITICAL MIXTURES; ISOTOPE EFFECT; LIQUID ACETONITRILE; NUCLEAR MAGNETIC RELAXATION; NUCLEAR OVERHAUSER ENHANCEMENT; QUADRUPOLE COUPLING CONSTANTS; RELAXATION MEASUREMENTS;

ACETONITRILE;

EID: 0005537990     PISSN: 09429352     EISSN: None     Source Type: Journal    
DOI: 10.1524/zpch.2000.214.12.1633     Document Type: Article

References (5)

1. H. G. Hertz and M. D. Zeidler, Kernmagnetische Relaxationszeitmessungen zur Frage der Hydratation unpolarer Gruppen in wäßriger Lösung. Ber. Bunsenges. Phys. Chem. 68 (1954) 821-837.
2. E. v. Goldammer and H. G. Hertz, Molecular motion and structure of aqueous mixtures with nonelectrolytes as studied by nuclear magnetic relaxation methods, J. Phys. Chem. 74 (1970) 3734-3755.
3. H. G. Hertz and H. Leiter, Hydrophobic interactions in aqueous mixtures of methanol, ethanol, acetonitrile, and dimethylformamide, Z. Phys. Chem. NF 133 (1982) 45-67.
4. H. Leiter, K. J. Patil and H. G. Hertz, Search for hydrophobic association between small aprotic solutes from an application of the nuclear magnetic relaxation method, J. Solution Chem. 12 (1983) 503-517.
5. H. Leiter, C. Albayrak and H. G. Hertz, Direct detection of enhanced water-water association in mixtures with small "hydrophobic" solute molecules, J. Mol. Liq. 27 (1984) 211-225.