Reaction of the dinuclear cobalt complex [Co2{μ-PPh2HCHC(O)CHCHPPh2(CO) 4]with two-electron donor ligands; the stabilisation of cobalt-alkene bonds by incorporation of alkenes into a bridging diphosphine ligand

Inorganica Chimica Acta

Volumn 277, Issue 2, 1998, Pages 186-192

  Mays, Martin J ^a   Raithby, Paul R ^a   Rennie, Moira Ann ^a   Sarveswaran, Vallipuram ^a   Solan, Gregory A ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

Alkene complexes; Cobalt complexes; Crystal structures; Dinuclear complexes; Diphosphine complexes

Indexed keywords

CARBON DIOXIDE; CRYSTAL STRUCTURE; LIGANDS; OLEFINS; SINGLE CRYSTALS;

COBALT COMPLEXES; DINUCLEAR COBALT COMPLEXES; DINUCLEAR COMPLEX; DIPHOSPHINE LIGAND; DIPHOSPHINES; MONOCLINIC SPACE GROUPS; SINGLE CRYSTAL X-RAY DIFFRACTION; THERMAL REACTIONS;

COBALT COMPOUNDS;

EID: 0005361854     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(97)06150-1     Document Type: Article

References (30)

1. See for example: R.B. James, in G. Wilkinson, F.G.A. Stone and E. W. Abel (eds.), Comprehensive Organometallic Chemistry, Vol. 1, Pergamon, New York, 1982, Ch. 51; R.F. Heck and D.S. Breslow, J. Am. Chem. Soc., 83 (1963) 4023; C.A. Tolman, Chem. Soc. Rev., 1 (1972) 317; A.J. Chalk and J.G. Harrod, Adv. Organomet. Chem., 6 (1968) 119; R.B. King, A.D. King Jr., M.Z. Iqbal and C.C. Frazier, J. Am. Chem. Soc., 100 (1978) 1687.
2. See for example: R.B. James, in G. Wilkinson, F.G.A. Stone and E. W. Abel (eds.), Comprehensive Organometallic Chemistry, Vol. 1, Pergamon, New York, 1982, Ch. 51; R.F. Heck and D.S. Breslow, J. Am. Chem. Soc., 83 (1963) 4023; C.A. Tolman, Chem. Soc. Rev., 1 (1972) 317; A.J. Chalk and J.G. Harrod, Adv. Organomet. Chem., 6 (1968) 119; R.B. King, A.D. King Jr., M.Z. Iqbal and C.C. Frazier, J. Am. Chem. Soc., 100 (1978) 1687.
3. See for example: R.B. James, in G. Wilkinson, F.G.A. Stone and E. W. Abel (eds.), Comprehensive Organometallic Chemistry, Vol. 1, Pergamon, New York, 1982, Ch. 51; R.F. Heck and D.S. Breslow, J. Am. Chem. Soc., 83 (1963) 4023; C.A. Tolman, Chem. Soc. Rev., 1 (1972) 317; A.J. Chalk and J.G. Harrod, Adv. Organomet. Chem., 6 (1968) 119; R.B. King, A.D. King Jr., M.Z. Iqbal and C.C. Frazier, J. Am. Chem. Soc., 100 (1978) 1687.
4. See for example: R.B. James, in G. Wilkinson, F.G.A. Stone and E. W. Abel (eds.), Comprehensive Organometallic Chemistry, Vol. 1, Pergamon, New York, 1982, Ch. 51; R.F. Heck and D.S. Breslow, J. Am. Chem. Soc., 83 (1963) 4023; C.A. Tolman, Chem. Soc. Rev., 1 (1972) 317; A.J. Chalk and J.G. Harrod, Adv. Organomet. Chem., 6 (1968) 119; R.B. King, A.D. King Jr., M.Z. Iqbal and C.C. Frazier, J. Am. Chem. Soc., 100 (1978) 1687.
5. See for example: R.B. James, in G. Wilkinson, F.G.A. Stone and E. W. Abel (eds.), Comprehensive Organometallic Chemistry, Vol. 1, Pergamon, New York, 1982, Ch. 51; R.F. Heck and D.S. Breslow, J. Am. Chem. Soc., 83 (1963) 4023; C.A. Tolman, Chem. Soc. Rev., 1 (1972) 317; A.J. Chalk and J.G. Harrod, Adv. Organomet. Chem., 6 (1968) 119; R.B. King, A.D. King Jr., M.Z. Iqbal and C.C. Frazier, J. Am. Chem. Soc., 100 (1978) 1687.
6. K. Jonas, Angew. Chem., Int. Ed. Engl., 24 (1985) 295; K. Jonas, E. Deffense and Dietrich, Angew. Chem., Int. Ed. Engl., 22 (1983) 716; H. Bönnemann, Angew. Chem., Int. Ed. Engl., 24 (1985) 248; S. Gambarotta, S. Stella, C. Floriani, A. Chiesi-Villa and C. Guastini, J. Chem. Soc., Dalton Trans., (1987) 1789; K.I. Goldberg and R.G. Bergmann, J. Am. Chem. Soc., 10 (1988) 4853.
7. K. Jonas, Angew. Chem., Int. Ed. Engl., 24 (1985) 295; K. Jonas, E. Deffense and Dietrich, Angew. Chem., Int. Ed. Engl., 22 (1983) 716; H. Bönnemann, Angew. Chem., Int. Ed. Engl., 24 (1985) 248; S. Gambarotta, S. Stella, C. Floriani, A. Chiesi-Villa and C. Guastini, J. Chem. Soc., Dalton Trans., (1987) 1789; K.I. Goldberg and R.G. Bergmann, J. Am. Chem. Soc., 10 (1988) 4853.
8. K. Jonas, Angew. Chem., Int. Ed. Engl., 24 (1985) 295; K. Jonas, E. Deffense and Dietrich, Angew. Chem., Int. Ed. Engl., 22 (1983) 716; H. Bönnemann, Angew. Chem., Int. Ed. Engl., 24 (1985) 248; S. Gambarotta, S. Stella, C. Floriani, A. Chiesi-Villa and C. Guastini, J. Chem. Soc., Dalton Trans., (1987) 1789; K.I. Goldberg and R.G. Bergmann, J. Am. Chem. Soc., 10 (1988) 4853.
9. K. Jonas, Angew. Chem., Int. Ed. Engl., 24 (1985) 295; K. Jonas, E. Deffense and Dietrich, Angew. Chem., Int. Ed. Engl., 22 (1983) 716; H. Bönnemann, Angew. Chem., Int. Ed. Engl., 24 (1985) 248; S. Gambarotta, S. Stella, C. Floriani, A. Chiesi-Villa and C. Guastini, J. Chem. Soc., Dalton Trans., (1987) 1789; K.I. Goldberg and R.G. Bergmann, J. Am. Chem. Soc., 10 (1988) 4853.
10. K. Jonas, Angew. Chem., Int. Ed. Engl., 24 (1985) 295; K. Jonas, E. Deffense and Dietrich, Angew. Chem., Int. Ed. Engl., 22 (1983) 716; H. Bönnemann, Angew. Chem., Int. Ed. Engl., 24 (1985) 248; S. Gambarotta, S. Stella, C. Floriani, A. Chiesi-Villa and C. Guastini, J. Chem. Soc., Dalton Trans., (1987) 1789; K.I. Goldberg and R.G. Bergmann, J. Am. Chem. Soc., 10 (1988) 4853.
11. A.J.M. Caffyn, M.J. Mays, G.A. Solan, D. Braga, P. Sabatino, G. Conole, M. McPartlin and H.R. Powell, J. Chem. Soc., Dalton Trans., (1991) 3103.
12. A.J. Edwards, A. Martín, M.J. Mays, P. Raithby and G.A. Solan, J. Chem. Soc., Chem Commun., (1992) 1416; G. Conole, M. Kessler, M.J. Mays, G.E. Pateman and G.A. Solan, Polyhedron, (1998) in press.
13. A.J. Edwards, A. Martín, M.J. Mays, P. Raithby and G.A. Solan, J. Chem. Soc., Chem Commun., (1992) 1416; G. Conole, M. Kessler, M.J. Mays, G.E. Pateman and G.A. Solan, Polyhedron, (1998) in press.
14. A.J.M. Caffyn, M.J. Mays, G.A. Solan, G. Conole and A. Tiripicchio, J. Chem. Soc., Dalton Trans., (1993) 2345.
15. 2-coordinated alkene can be displaced see: A. Martín, M.J. Mays, P.R. Raithby and G.A. Solan, J. Chem. Soc., Dalton Trans., (1993) 1789.
16. A.J.M. Caffyn, A. Martín, M.J. Mays, P.R. Raithby and G.A. Solan, J. Chem. Soc., Dalton Trans., (1994) 609.
17. A.J.M. Caffyn, M.J. Mays, G.A. Solan, D. Braga, P. Sabatino, A. Tiripicchio and M.T. Camellini, Organometallics, 12 (1993) 1876.
18. For related Co-Co distances see: K. Yang, J.A. Martin, S.G. Bott and M.G. Richmond, Organometallics, 15 (1996) 2227; K. Yang, S.G. Bott and M.G. Richmond, Organometallics, 14 (1995) 4977; Organometallics, 13 (1995) 3788; A.J.M. Caffyn, M.J. Mays, G. Conole, M. McPartlin and H.R. Powell, J. Organomet. Chem., 436 (1992) 83; A.J. Edwards, S.R. Mack, M.J. Mays, C.-Y. Mo, P.R. Raithby and M.A. Rennie. J. Organomet. Chem., 159 (1996) 243; F.A. Cotton, J.D. Jamerson and B.R. Stults, J. Am. Chem. Soc., 98 (1976) 1774.
19. For related Co-Co distances see: K. Yang, J.A. Martin, S.G. Bott and M.G. Richmond, Organometallics, 15 (1996) 2227; K. Yang, S.G. Bott and M.G. Richmond, Organometallics, 14 (1995) 4977; Organometallics, 13 (1995) 3788; A.J.M. Caffyn, M.J. Mays, G. Conole, M. McPartlin and H.R. Powell, J. Organomet. Chem., 436 (1992) 83; A.J. Edwards, S.R. Mack, M.J. Mays, C.-Y. Mo, P.R. Raithby and M.A. Rennie. J. Organomet. Chem., 159 (1996) 243; F.A. Cotton, J.D. Jamerson and B.R. Stults, J. Am. Chem. Soc., 98 (1976) 1774.
20. For related Co-Co distances see: K. Yang, J.A. Martin, S.G. Bott and M.G. Richmond, Organometallics, 15 (1996) 2227; K. Yang, S.G. Bott and M.G. Richmond, Organometallics, 14 (1995) 4977; Organometallics, 13 (1995) 3788; A.J.M. Caffyn, M.J. Mays, G. Conole, M. McPartlin and H.R. Powell, J. Organomet. Chem., 436 (1992) 83; A.J. Edwards, S.R. Mack, M.J. Mays, C.-Y. Mo, P.R. Raithby and M.A. Rennie. J. Organomet. Chem., 159 (1996) 243; F.A. Cotton, J.D. Jamerson and B.R. Stults, J. Am. Chem. Soc., 98 (1976) 1774.
21. For related Co-Co distances see: K. Yang, J.A. Martin, S.G. Bott and M.G. Richmond, Organometallics, 15 (1996) 2227; K. Yang, S.G. Bott and M.G. Richmond, Organometallics, 14 (1995) 4977; Organometallics, 13 (1995) 3788; A.J.M. Caffyn, M.J. Mays, G. Conole, M. McPartlin and H.R. Powell, J. Organomet. Chem., 436 (1992) 83; A.J. Edwards, S.R. Mack, M.J. Mays, C.-Y. Mo, P.R. Raithby and M.A. Rennie. J. Organomet. Chem., 159 (1996) 243; F.A. Cotton, J.D. Jamerson and B.R. Stults, J. Am. Chem. Soc., 98 (1976) 1774.
22. For related Co-Co distances see: K. Yang, J.A. Martin, S.G. Bott and M.G. Richmond, Organometallics, 15 (1996) 2227; K. Yang, S.G. Bott and M.G. Richmond, Organometallics, 14 (1995) 4977; Organometallics, 13 (1995) 3788; A.J.M. Caffyn, M.J. Mays, G. Conole, M. McPartlin and H.R. Powell, J. Organomet. Chem., 436 (1992) 83; A.J. Edwards, S.R. Mack, M.J. Mays, C.-Y. Mo, P.R. Raithby and M.A. Rennie. J. Organomet. Chem., 159 (1996) 243; F.A. Cotton, J.D. Jamerson and B.R. Stults, J. Am. Chem. Soc., 98 (1976) 1774.
23. For related Co-Co distances see: K. Yang, J.A. Martin, S.G. Bott and M.G. Richmond, Organometallics, 15 (1996) 2227; K. Yang, S.G. Bott and M.G. Richmond, Organometallics, 14 (1995) 4977; Organometallics, 13 (1995) 3788; A.J.M. Caffyn, M.J. Mays, G. Conole, M. McPartlin and H.R. Powell, J. Organomet. Chem., 436 (1992) 83; A.J. Edwards, S.R. Mack, M.J. Mays, C.-Y. Mo, P.R. Raithby and M.A. Rennie. J. Organomet. Chem., 159 (1996) 243; F.A. Cotton, J.D. Jamerson and B.R. Stults, J. Am. Chem. Soc., 98 (1976) 1774.
24. See for example: J.J. Bonnet and R. Mathieu, Inorg. Chem., 17 (1978) 1973; D.H. Bradley, M.A. Khan and K.M. Nicholas, Organometallics, 8 (1989) 554; Organometallics, 11 (1992) 2598; R.H. Cragg, J.C. Jeffery and M.J. Went, J. Chem. Soc., Dalton Trans., (1991) 137.
25. See for example: J.J. Bonnet and R. Mathieu, Inorg. Chem., 17 (1978) 1973; D.H. Bradley, M.A. Khan and K.M. Nicholas, Organometallics, 8 (1989) 554; Organometallics, 11 (1992) 2598; R.H. Cragg, J.C. Jeffery and M.J. Went, J. Chem. Soc., Dalton Trans., (1991) 137.
26. See for example: J.J. Bonnet and R. Mathieu, Inorg. Chem., 17 (1978) 1973; D.H. Bradley, M.A. Khan and K.M. Nicholas, Organometallics, 8 (1989) 554; Organometallics, 11 (1992) 2598; R.H. Cragg, J.C. Jeffery and M.J. Went, J. Chem. Soc., Dalton Trans., (1991) 137.
27. See for example: J.J. Bonnet and R. Mathieu, Inorg. Chem., 17 (1978) 1973; D.H. Bradley, M.A. Khan and K.M. Nicholas, Organometallics, 8 (1989) 554; Organometallics, 11 (1992) 2598; R.H. Cragg, J.C. Jeffery and M.J. Went, J. Chem. Soc., Dalton Trans., (1991) 137.
28. A.J.M. Caffyn, M.J. Mays and P.R. Raithby, J. Chem. Soc., Dalton Trans., (1991) 2349.
29. G.M. Sheldrick, SHELXS 86, program for crystal structure solution, Acta Crystallogr., Sect. A, 46 (1990) 467.
30. G.M. Sheldrick, SHELXL 93, program for crystal structure refinement, University of Göttingen, Göttingen, Germany, 1993.