Linear vs. bent MOR bonds in d0 metal alkoxides: X-ray crystal structure of (C5Me5)Ta(StBu)3(OnBu) and EHMO analysis

Journal of Organometallic Chemistry

Volumn 471, Issue 1-2, 1994, Pages 111-115

  Tatsumi, Kazuyuki ^a   Tahara, Akitoshi ^a   Nakamura, Akira ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

Alkoxide; Molecular orbital calculations; Tantalum; Thiolate; X ray diffraction

Indexed keywords

EID: 0005328645     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(94)88114-6     Document Type: Article

References (28)

1. The synthesis and structure of Group 5 metal alkyl and alkylidene complexes containing 2,6-dialkylphenoxide ligands: X-ray crystal structures of [Ta(OC6H3Me2-2,6)2(CH2Ph)3], [Ta(OC6H3Me2-2,6)4Me], and [Ta(OC6H3But 2-2,6)2(?CHSiMe3)(CH2SiMe3)]
2. Facile synthesis of group 4-6 transition metal phenoxides and X-ray structures of TiCl2(O-2,6-(CH3)2C6H3)2(THF)2 and NbCl3(O-2,6-(CH3)2C6H3)2(THF).
3. A New Class of Tantalum(V) Dithiolate Complexes: Synthesis and Characterization of [Ta(?5-C5Me4R)(SCH?CHS)2] (R = Me, Et) and [Ta(?5-C5Me5)(SCH2CH2S)2]
4. Transition metal thiolates: synthetic, catalytic, and biomimetic aspects
5. First examples of six-coordinate niobium and tantalum homoleptic complexes with monodentate arenethiolate ligands. Synthesis and structural characterization of [Ph4P]2[Nb(SPh)6], Na(THF)3Nb(SPh-pMe)6. [(15-crown-5)Na][Ta(SPh)6], and Nb2(.mu.2-SPh)4(SPh)4(SPh)2Cl2(C2H5CN)2