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note
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Initial precipitation of a precursor salt is not necessary. A concentration gradient of solubilized precursor can be established by direct swelling of an initially unswelled polymer and subsequent reduction. Using variations of this infiltration processes, we have formed silver particles with average sizes as small as 7 nm in Kapton.
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We used a 13.7 wt % PBZT/PPA solution that was homogenized in a Haake Rheomixer (model Rheocord 90) at 120 °C for 6 h, filtered, deaerated at 80 °C through a 74 μm stainless steel mesh, and extruded at 80 °C through a 0.010 in. spinneret into a single filament fiber by a dry-jet, wet-spinning process. The fiber was highly stretched during processing and a draw ratio of take-up speed to extrusion rate of about 60 was obtained.
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49
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85033916965
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note
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Wide-angle X-ray diffraction (Cu Kα radiation from a RU-200BVH Rigaku rotation anode operating at 40 kV and 200 mA monochromatized with graphite crystals). The scattering patterns were recorded on photographic films using an evacuated Statton camera with a camera length of 3 cm.
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85033937354
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4 S/cm
-
4 S/cm.
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53
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85033909384
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note
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The fiber tensile modulus and strength were determined using an Instron Universal Testing Machine (model 1122) and fibers mounted on 1 in. paper tabs with fast setting epoxy. The fiber diameters were determined by using the Nikon Metaphot optical microscope. A series of tests was repeated in order to find out the consistent tensile stress required to rupture the fiber.
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Organic/Inorganic Hybrid Materials; Laine, R. M., Sanchez, C., Brinker, C. J., Giannelis, E. P., Eds.; Pittsburgh, PA
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