Gas-phase reactivity of ethyl cations: Protonation and alkylation of N-methylpyrrole and thiophene

Journal of Physical Chemistry A

Volumn 102, Issue 32, 1998, Pages 6464-6469

  Angelini, G ^a   Bucci, R ^a   Laguzzi, G ^a   Siciliano, C ^a   Segre, A L ^a  

^a CNR   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0005226151     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp980899v     Document Type: Article

References (34)

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33. β atios were respectively 0.41 for ref le and 0.52 for the present work. Since in ref le and in the present work two different gaseous bases have been used, the comparison between the isomeric distribution of the ethylated products, in these works, is only possible in experimental conditions related to the absence of base.
34. Since the PA value of the ethylated adduct of thiophene is unknown, the PA value of thiophene has been taken into account.