Covalent linking of β-slabs of EDT-TTF moieties: Bis(ethylenedithiotetrathiafulvalenyl)-ethane and its 1:1 radical cation salt with Au(CN)2-

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Volumn 11, Issue 9, 1999, Pages 766-769

  Fourmigué, Marc ^a   Mézière, Cécile ^a   Canadell, Enric ^b   Zitoun, David ^a   Bechgaard, Klaus ^c   Auban Senzier, Pascale ^d  

^a UNIVERSITÉ DE NANTES   (France)

^b UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^c TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

^d CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0004990623     PISSN: 09359648     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-4095(199906)11:9<766::aid-adma766>3.3.co;2-l     Document Type: Article

References (27)

1. TMTTF: tetramethyltetrathiafulvalene; TMTSF: tetramethyltetraselenafulvalene; BEDT-TTF: bis(ethylenedithio)tetrathiafulvalene; EDT-TTF: ethylenedithiotetrathiafulvalene.
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20. min = 0.621) reflections. H atoms were introduced at calculated positions (riding model). Crystallographic data (excluding structure factors) have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-102945. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
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23. μv matrix elements were calculated according to the modified Wolfsberg-Helmholz formula (J. H. Ammeter, H.-B. Bürgi, J. Thibeault, R. Hoffman, J. Am. Chem. Soc. 1978, 100, 3686).
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25. This situation is very similar to that leading to the metal-to-insulator transition in the blue bronzes: E. Canadell, M.-H. Whangbo, Chem. Rev. 1991, 91, 965; J.-P. Pouget, C. Noguera, A. H. Moudden, R. Moret, J. Phys. Fr. 1985, 46, 1731.
26. This situation is very similar to that leading to the metal-to-insulator transition in the blue bronzes: E. Canadell, M.-H. Whangbo, Chem. Rev. 1991, 91, 965; J.-P. Pouget, C. Noguera, A. H. Moudden, R. Moret, J. Phys. Fr. 1985, 46, 1731.
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