N,N-dimethylformamide dimethylacetal (DMF-DMA) catalyzed formation of 1,3,5-trisubstituted benzene derivatives from α,β-unsaturated nitro compounds [2]

Bulletin of the Korean Chemical Society

Volumn 20, Issue 11, 1999, Pages 1255-1256

  Kim, Tae Yi ^a   Kim, Hyoung Shik ^a   Lee, Ka Young ^a   Kim, Jae Nyoung ^a  

^a Chonnam National University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE DERIVATIVE; FORMAMIDE DERIVATIVE;

CATALYSIS; CYCLIZATION; LETTER; REACTION ANALYSIS; SYNTHESIS;

EID: 0004956338     PISSN: 02532964     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Letter

References (17)

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12. For transition metal catalyzed [2+2+2] cycloaddition reaction of phenyl acetylene derivatives, see (a) Meriwether, L. S.; Colthup, E. C.; Kennerly, G. W.; Reusch, R. N. J. Org. Chem. 1961, 26, 5155.
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14. For acid catalyzed cyclic trimerization of acetophenones, see Iranpoor, N.: Zeynizaded, B. Synlett 1998, 1079, and further references cited therein.
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16. +, 100).
17. 2) from the reaction of acetophenone and DMFDMA in DMF. From the reaction of phenylacetylene and DMF-DMA, to our surprise, phenylpropargyl aldehyde was isolated in 52% yield.