The impact of nonmethane hydrocarbon compounds on tropospheric photochemistry

Journal of Geophysical Research: Atmospheres

Volumn 103, Issue 3339, 1998, Pages 10673-10696

  Houweling, Sander ^a   Dentener, Frank ^a   Lelieveld, Jos ^a  

^a UTRECHT UNIVERSITY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL TRANSPORT; NONMETHANE HYDROCARBON; PHOTOCHEMISTRY; TROPOSPHERE;

EID: 0004862558     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/97jd03582     Document Type: Article

References (97)

1. Atkinson, R., Gas-phase tropospheric chemistry of organic compounds, J. Phys. Chem. Ref. Data Monogr. 2, 1994.
2. Atkinson, R., D. L. Baulch, R. A. Cox, R. F. Hampson, J. A. Kerr, and J. Troe, Evaluated kinetic and photochemical data for atmospheric chemistry: supplement IV, Atmos. Environ., 26, 1187-1230, 1992.
3. Atlas, E., W. Pollock, J. Greenberg, and L. Heidt, Alkyl nitrates, nonmethane hydrocarbons, and halocarbon gases over the equatorial Pacific Ocean during Saga 3, J. Geophys. Res., 98, 16,933-16,947, 1993.
4. Bates, T. S., K. C. Kelly, J. E. Johnson, and R. H. Gammon, Regional and seasonal variations in the flux of oceanic carbon monoxide to the atmosphere, J. Geophys. Res., 100, 23,093-23,101, 1995.
5. Bauer, K., R. Conrad, and W. Seiler, CO production höherer pflanzen an natürlichen Standorten, Z. P flanzenphysiol., 94, 219-230, 1979.
6. Benkovitz, C. M., M. T. Scholtz, J. Pacyna, L. Tarrason, J. Dignon, E. C. Voldener, P. A. Spiro, J. A. Logan, and T. E. Graedel, Global gridded inventories of anthropogenic emissions of sulfur and nitrogen, J. Geophys. Res., 101, 29,239-29,253, 1996.
7. Bottenheim, J. W., A. Sirios, K. A. Brice, and A. J. Gallant, Five years of continuous PAN and ozone at a rural location in eastern Canada, J. Geophys. Res., 99, 5333-5352, 1994.
8. Brewer, D. A., T. R. Augustsson, and J. S. Levine, The photochemistry of anthropogenic nonmethane hydrocarbons in the troposphere, J. Geophys. Res., 88, 6683-6695, 1983.
9. Brühl, C., and P. J. Crutzen, Scenarios of possible change in tropospheric temperatures and ozone concentrations due to man's activities, estimated with a one dimensional coupled photochemical climate model, Clim. Dyn., 2, 173-202, 1988.
10. Brühl, C., and P. J. Crutzen, MPIC two dimensional model NASA Ref. Publ., 1292, 103-104, 1993.
11. 3: Implications for tropospheric OH, J. Geophys. Res., 96, 22,347-22,355, 1991.
12. Chameides, W. L., and R. J. Cicerone, Effects of nonmethane hydrocarbons in the troposphere, J. Geophys. Res., 83, 947-952, 1978.
13. Crutzen, P. J., The role of methane in atmospheric chemistry and climate, in Ruminant Physiology: Digestion, Metabolism, Growth and Reproduction: Proceedings of the Eighth International Symposium on Ruminant Physiology, edited by W. V. Engelhardt, S. Leonhardt-Marek, G. Breves, and D. Giesecke, pp. 291-315, Ferdinant Enke Verlag, Stuttgart, Germany, 1995.
14. DeMore, W. B., S. P. Sander, D. M. Golde, R. F. Hampson, M. J. Kurylo, C. J. Howard, A. R. Ravishankara, C. E. Kolb, and M. J. Molina, Chemical kinetics and photochemical data for use in stratospheric modelling, NASA/JPL publ. 94-26, Eval. 11, Jet Propul. Lab., Pasadena, Calif., 1994.
15. Dentener, F. J., Heterogeneous chemistry in the troposphere, Ph.D. thesis, Utrecht Univ., Utrecht, The Netherlands, 1993.
16. 3, and OH, J. Geophys. Res., 98, 7149-7163, 1993.
17. Derwent, R. G., Evaluation of a number of chemical mechanisms for their application in models describing the formation of photochemical ozone in Europe, Atmos. Environ., 24, 2615-2624, 1990.
18. Derwent, R. G., M. E. Jenkin, and S. M. Saunders, Photochemical ozone creation potentials for a large number of reactive hydrocarbons under European conditions, Atmos. Environ., 30, 181-199, 1996.
19. Erickson, D. J., Ocean to atmosphere carbon monoxide flux: Global inventory and climate applications, Global Biogeochem. Cycles, 3, 305-314, 1989.
20. Galliardo-Klenner, L. G., Oxidized nitrogen in the troposphere: The role of lightning, Ph.D. thesis, Stockholm Univ., Stockholm, 1996.
21. x, Tellus, 48B, 641-651, 1996.
22. Gery, M. W., G. Z. Whitten, J. P. Killus, and M. C. Dodge, Developement and testing of the CBM-4 for urban and regional modelling, Rep. EPA-600/3-88-012, U.S. Environ. Prot. Agency, Research Triangle Park, N. C., 1988.
23. Gery, M. W., G. Z. Whitten, J. P. Killus, and M. C. Dodge, A photochemical kinetics mechanism for urban and regional scale computer modeling, J. Geophys. Res., 94, 925-956, 1989.
24. Goldan, P. D., W. C. Kuster, F. C. Fehsenfeld, and S. A. Montzka, Hydrocarbon measurements in the southeastern United States: The rural oxidants in the southern environment (ROSE) program 1990, J. Geophys. Res., 100, 25,945-25,963, 1995.
25. Goldstein, A. H., S. C. Wofsy, and C. M. Spivakovski, Seasonal variations of nonmethane hydrocarbons in rural New England: Constraints on OH concentrations in the northern midlatitudes, J. Geophys. Res., 100, 21,023-21,033, 1995.
26. Guenther, A., et al., A global model of natural volatile organic compound emissions, J. Geophys. Res., 100, 8873-8892, 1995.
27. 2 and other trace gases to the atmosphere from fires in the tropics based on the FAO statistics for the period 1975-1980. in Fire in the Tropical Biota, edited by J. Goldhammer, pp. 440-462, Springer, Berlin, 1991.
28. Heimann, M., The Global Atmospheric Tracer Model TM2, Technical Report 10, ISSN 0940-9327, Deutches Klimarechenzentrum, Hamburg, Germany, 1993.
29. Hein, R., P. J. Crutzen, and M. Heimann, An inverse modeling approach to investigate the global atmospheric methane cycle, Global Biogeochem. Cycles, 11, 43-76, 1997.
30. Hertel, O., R. Berkowicz, J. Christensen, and Ø. Hov, Test of two numerical schemes for use in atmospheric transport-chemistry models, Atmos. Environ.,27A, 2591-2611, 1993.
31. Hough, A. M., Development of a two-dimensional global tropospheric model: Model Chemistry, J. Geophys. Res., 96, 7325-7362, 1991.
32. 5 hydrocarbons in rural southern Norway, Atmos. Environ., 25A, 1981-1999, 1991.
33. Isaksen, I. S. A., Ø. Hov, S. A. Penkett, and A. Semb, Model analysis of the measured concentrations of organic gases in the Norwegian arctic, J. Atmos. Chem., 3, 271-285, 1985.
34. Jacob, J. J., and S. C. Wofsy, Budgets of reactive nitrogen, hydrocarbons, and ozone over the Amazon forest during the wet season, J. Geophys. Res., 95, 16,737-16,754, 1990.
35. 5 alkanes, and acetylene at a remote boreal site in Canada, J. Geophys. Res., 99. 1589-1599, 1994.
36. Junge, C. E, and P. J. Gustafson, On the distribution of seasalt over the United States and its removal by precipitation, Tellus, 9, 164-173, 1957.
37. Kames, J., and U. Schurath, Alkyl nitrates and atmospheric nitrates of atmospheric interest: Henry's law constants and their temperature dependencies, J. Atmos. Chem., 15, 79-95, 1992.
38. Kanakidou, M., H. B. Singh, K. M. Valentin, and P. J. Crutzen, A two-dimensional study of ethane and propane oxidation in the troposphere, J. Geophys. Res., 96, 15,395-15,413, 1991.
39. Kanakidou, M., F. J. Dentener, and P. J. Crutzen, A global three-dimensional study of the fate of HCFCs and HFC-134a in the troposphere, J. Geophys. Res., 100, 18,781-18,802, 1995.
40. Kastings, J. F., and H. B. Singh, Nonmethane hydrocarbons in the troposphere: Impact on odd hydrogen and odd nitrogen chemistry, J. Geophys. Res., 91, 13,239-13,256, 1986.
41. Komhyr, W. D., S. J. Oltmans, P. R. Franchois, W. F. J. Evans, and W. A. Matthews, The latitudinal distribution of ozone to 35 km altitude from ECC ozonesonde observations, 1985-1987, in Ozone in the Atmosphere, edited by R. D. Bojkov and P. Fabian, A. Deepak, Hampton, Va., 1989.
42. Kreileman, G. J. J., Documentation of a geographically explicit dynamic carbon cycle model, RIVM report, Natl. Inst. for Public Health and the Environ., Bilthoven, The Netherlands, Jan. 1996
43. Ledbury, W., and E. W. Blair, The partial formaldehyde vapor pressure of aqueous solutions of formaldehyde, II, J. Chem. Soc., 127, 2823-2839, 1925.
44. Leone, J. A., and J. H. Seinfeld, Comparative analysis of chemical reaction mechanisms for photochemical smog, Atmos. Environ., 19, 437-464, 1985.
45. x, J. Geophys. Res., 101, 22,911-22,922, 1996.
46. Lin, X., O. T. Melo, D. R. Hastie, P. B. Shepson, H. Niki, and J. W. Bottenheim, A case study of ozone production in a rural area of central Ontario, Atmos. Environ., 26, 311-324, 1992.
47. Lind, J. A., and G. L. Kok, Henry's law determinations for aqueous of hydrogen peroxide, methylperoxide, and peroxyacetic acid, J. Geophys. Res., 91, 7889-7895, 1986.
48. Liu, S., M. Trainer, F. C. Fehsenfeld, D. D. Parrish, E. J. Williams, D. W. Fahey, G. Hübler, and P. C. Murphey, Ozone production in the rural troposphere and implications for regional and global ozone distributions, J. Geophys. Res., 92, 4191-4207, 1987.
49. Louis, J. F., A parametric model of vertical eddy fluxes in the atmosphere, Boundary Layer Meteorol., 17, 187-202, 1979.
50. Maier-Reimer, E., Geochemical cycles in an ocean general circulation model: Preindustrial tracer distributions, Global Biogeochem. Cycles, 7, 645-677, 1993.
51. Martin, R. S., H. Westberg, E. Allwine, L. Ashman, E. C. Farmer, and B. Lamb, Measurements of isoprene and its atmospheric oxidation products in a central Pennsylvania deciduous forest, J. Atmos. Chem., 13, 1-32, 1991.
52. Midgley, P. M., The production and release to the atmosphere of 1,1,1-trichloroethane (methyl chloroform), Atmos. Environ., 23, 2663-2665, 1989.
53. Midgley, P. M., and A. McCulloch, The production and global distribution of emissions to the atmosphere of 1,1,1 -Trichloroethane (Methyl Chloroform), Atmos. Environ., 29, 1601-1608, 1995.
54. Moortgat, G. K., W. Kuppel, K. H. Mobius, W. Seiler, and P. Wameck, Laboratory measurements of photolytic parameters for formaldehyde, Rep. FAA-EE-80-47, U.S. Dep. of Transp., Washington, D. C., 1980.
55. x J. Geophys. Res., 101, 12,621-12,638, 1996.
56. Müller, J. F., IMAGES: A three-dimensional chemical transport model of the global troposphere, J. Geophys. Res., 100, 16,445-16,490, 1995.
57. Novelli, P. C., L. P. Steele, and P. P. Tans, Mixing ratios of carbon monoxide in the troposphere, J. Geophys. Res., 97, 20,731-20,750, 1992.
58. O'Brien, J. M., P. B. Shepson, K. Muthuramu, C. Hao, H. Niki, and D. R. Hastie, Measurements of alkyl nitrates and multifunctional nitrates at a rural site in Ontario, J. Geophys. Res., 100, 22,795-22,804, 1995.
59. Olivier, J. G. J., et al., Description of EDGAR version 2.0: A set of global emission inventories of greenhouse gases and ozone depleting substances for all anthropogenic and most natural sources on a per country basis on 1° × 1° grid, RTVM rep. 771060 002/TNO MEP rep. R96/119, Natl. Inst. for Public Health and the Environ., Bilthoven, The Netherlands, 1996.
60. Olsen, J., et al., Results from the Intergovernmental Panel of Climatic Change photochemical model intercomparison (Photo-Comp), J. Geophys. Res., 102,5979-5991, 1997.
61. Oltmans, S. J., and H. Levy II, Ozone measurements from a global network of surface sites, ozone in the troposphere and stratosphere, part 2, Proceedings of the quadrennial ozone symposium, NASA Conf. publ. 3266, 19-24, 1992.
62. Oltmans, S. J., and H. Levy II, Surface ozone measurements from a global network, Atmos. Environ., 28, 9-24, 1994.
63. Oltmans, S. J., W. D. Komhyr, P. R. Franchois, and W. A. Matthews, Tropospheric ozone: Variations from surface and ECC ozonesonde observations, in Ozone in the Atmosphere, edited by R. D. Bojkov and P. Fabian, A. Deepak, Hampton, Va., 1989.
64. Paulson, S. E., and J. H. Seinfeld, Development and evaluation of a photooxidation mechanism for isoprene, J. Geophys. Res., 97, 20,703-20,715, 1992.
65. Penkett, S. A., The seasonal variation of nonmethane hydrocarbons in the free troposphere over the North Atlantic Ocean: Possible evidence for extensive reaction of hydrocarbons with the nitrate radical, J. Geophys. Res., 98, 2865-2886, 1993.
66. Poppe, D., et al., Gas-phase reactions in atmospheric chemistry and transport models: A model intercomparison, EUROTRAC, Garmisch-Partenkirchen, Germany, 1996.
67. Prinn, R. G., et al., Global average concentration and trend for hydroxyl radical deduction from ALE/GAGE trichloroethane (methyl chloroform) data for 1978-1990, J. Geophys. Res., 97, 2445-2461, 1992.
68. 3 data, paper presented at Joint Meeting on Global Atmospheric Chemistry, Int. Assoc. of Meteorol. and Atmos. Phys., Fuji-Yoshida, Japan, Sept. 5-9, 1994.
69. Prinn, R. G., R. F. Weiss, B. R. Miller, J. Huang, F. N. Alyea, D. M. Cunnold, P. B. Fraser, D. E, Hartley, and P. G. Simmonds, Atmospheric trends and lifetime of trichloro-ethane and global average hydroxyl radical concentrations based on 1978-1994 ALE/GAGE measurements, Science, 269, 187-192, 1995.
70. Reichte, H. G., V. S. Conners, J. A. Holland, R. T. Sherrill, H. A. Wallio, J. C. Casas, E. P. Condon, B. B. Gormsen, and W. Seiler, The distribution of middle tropospheric carbon monoxide during early October 1984, J. Geophys. Res.; 95, 9845-9856, 1990.
71. Roberts, J. M., Review article: Atmospheric chemistry of organic nitrates, Atmos. Environ., 24, 243-287, 1990.
72. Roberts, J. M., and R. W. Fayer, UV absorption cross section of organic nitrates of potential atmospheric importance and estimation of atmospheric lifetimes, Environ. Sci. Technol., 23, 945-951, 1989.
73. 3 in the troposphere calculated with a chemistry general circulation model, J. Geophys. Res., 100, 20,983-20,998, 1995.
74. Roemer, M., Trends of tropospheric ozone over Europe, Ph.d. thesis, Utrecht Univ., Utrecht, The Netherlands, 1996.
75. Roselle, S. J., The sensitivity of regional ozone modeling to biogenic hydrocarbons, J. Geophys. Res., 96, 7371-7394, 1991.
76. Russell, G., and J. Lerner, A new finite-differencing scheme for the tracer transport equation, J. Appl. Meteorol., 20, 1483-1498, 1981.
77. Schwanz, S. E., and W. H. White, Solubility equilibria of the nitrogen oxides and oxiacids in dilute aqueous solution, Adv. Environ. Sci. Eng., 4, 1-45, 1981.
78. Senum, G. I., Y. N. Lee, and J. S. Gaffney, Ultraviolet absorption spectrum of peroxy acetyl nitrate and peroxy propionyl nitrate, J. Phys. Chem., 88, 1269-1270, 1984.
79. 3 at urban and rural sites in Ontario, Atmos. Environ., 26A, 1259-1270, 1992.
80. Shepson, P. B., K. G. Anlauf, J. W. Bottenheim, H. A. Wiebe, N. Gao, K. Muthuramu, and G. I. Mackay, Alkyl nitrates and their contribution to reactive nitrogen at a rural site in Ontario, Atmos. Environ., 27A, 749-757, 1993.
81. x concentrations, Atmos. Environ., 31, 27-43, 1997.
82. Singh, H. B., L. J. Salas, and W. Viezee, Global distribution of peroxyacetyl nitrate, Nature, 321, 588-591, 1986.
83. Singh, H. B., D. O. Kara, D. Herlth, J. D. Bradshaw, S. T. Sandholm, G. G. L. Gregory, G. W. Sachse, D. R. Blake, P. J. Crutzen, and M. A. Kanakidou, Atmospheric measurements of peroxyacetyl nitrate and other organic nitrates at high latitudes: possible sources and sinks, J. Geophys. Res., 97, 16,511-16,522, 1992.
84. Singh, H. B., et al., Summertime distribution of PAN and other reactive nitrogen species in the northern high-latitude atmosphere of eastern Canada, J. Geophys. Res., 99, 1821-1853, 1994.
85. Stockwell, W. R., R. P. Middleton, J. S. Chang, and X. Tang, The second generation regional acid deposition model chemical mechanism for regional air quality modeling, J. Geophys. Res., 95, 16,343-16,367, 1990.
86. Strand, A., and Ø. Hov, A two-dimensional giobal study of tropospheric ozone production, J. Geophys. Res., 99, 22,877-22,895, 1994.
87. Tiedke, M., A comprehensive mass flux scheme for cumulus parameterization in large-scale models, Mont. Weather Rev., 117, 1779-1800, 1989.
88. Tonnesen, S., and H. E. Jeffries, Inhibition of the odd oxygen production in the carbon bond four and generic reaction set mechanisms, Atmos. Environ., 28, 1339-1349, 1994.
89. Trainer, M., E. Y. Hsie, S. A. McKeen, R. Tallamraju, D. D. Parrish, F. G. Fehsenfeld, and S. C. Liu, Impact of natural hydrocarbons on hydroxyl and peroxy radicals at a remote site, J. Geophys. Res., 92, 11,879-11,894, 1987.
90. van Minnen, J. G., K. Klein Goldewijk, and R. Leemans, The importance of feedback processes and vegetation transition in the terrestrial carbon cycle, J. Biogeogr., 22, 805-814, 1996.
91. Wesely, M. L., Parameterization of surface resistance to gaseous dry deposition in regional-scale numerical models, Atmos. Environ., 23, 1293-1304, 1989.
92. 3 radical and isoprene, J. Atmos. Chem., 13, 183-193, 1991.
93. World Meteorological Organization, Scientific assessment of ozone depletion 1994: Global ozone research and monitoring project, Rep. 37, Geneva, Switzerland, 1995.
94. X emissions, J. Geophys. Res., 100, 11,447-11,464, 1995.
95. Yokouchi, Y., Seasonal and diurnal variation of isoprene and its oxidation products in a semi-rural area, Atmos. Environ., 28, 2651-2658, 1994.
96. Zimmerman, J., and D. Poppe, A supplement for the RADM2 chemical mechanism: the photooxidation of isoprene, Atmos. Environ., 30, 1255-1269, 1996.
97. Zimmerman, P. R., et al., Measurements of atmospheric hydrocarbons and biogenic emission fluxes in the Amazon boundary layer, J. Geophys. Res., 93, 1407-1416, 1988.