The reaction of triphenylmethylhalophosphines with tetrachloro-orthobenzoquinone: oxidation - Isomerization - Dehydrohalogenation

Heteroatom Chemistry

Volumn 10, Issue 4, 1999, Pages 277-280

  Plack, Volker ^a   Goerlich, Jens R ^a   Thönnessen, Holger ^a   Jones, Peter G ^a   Schmutzler, Reinhard ^a  

^a TECHNICAL UNIVERSITY OF BRAUNSCHWEIG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0004826363     PISSN: 10427163     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1098-1071(1999)10:4<277::AID-HC3>3.0.CO;2-5     Document Type: Article

References (17)

1. 2 are known, but to the best of our knowledge, none of these exists in the acid form.
2. The limited attention that was paid to this class of compounds is illustrated by the fact that no chapter in the latest relevant edition of Houben-Weyl [Vol. E1, Thieme Verlag, Stuttgart (1982)] deals with hypophosphonous acids/primary phosphine oxides or their derivatives.
3. Examples of organohalophosphines: (a) tert. BuP(H)F: Niecke, E.; Rüger, R.; Güth, W. Z Naturforsch 1985, 40b, 1049. (b) Mes*P(H)Cl: Yoshifuji, M.; Sasaki, S.; Inamoto, N. Tetrahedron Lett 1989, 30, 839.
4. Examples of organohalophosphines: (a) tert. BuP(H)F: Niecke, E.; Rüger, R.; Güth, W. Z Naturforsch 1985, 40b, 1049. (b) Mes*P(H)Cl: Yoshifuji, M.; Sasaki, S.; Inamoto, N. Tetrahedron Lett 1989, 30, 839.
5. 3: Kischkel, H.; Röschenthaler, G.-V., Chem Ber 1985, 118, 4842.
6. Annan, T. A.; Tian, Z.; Tuck, D. G. J Chem Soc Dalton Trans, 1991, 19.
7. Well, M.; Schmutzler, R. Phosphorus Sulfur Silicon 1992, 72, 171.
8. Goerlich, J. R.; Fischer, A.; Jones, P. G.; Schmutzler, R. Z Naturforsch 1994, 49b, 801.
9. Berger, S.; Braun, S.; Kalinowski, H.-O. NMR-Spektroskopie von Nichtmetallen; Georg Thieme Verlag: Stuttgart, 1993; Vol. 3, pp 48, 49, 77, 127, 147.
10. Clark, T. E.; Day, R. O.; Holmes, R. R. Inorg Chem 1979, 18, 1668.
11. Krill, J.; Shevchenko, I.; Fischer, A.; Jones, P. G.; Schmutzler, R. Chem Ber 1997, 130, 1479.
12. Shevchenko, I. V.; Fischer, A.; Jones, P. G.; Schmutzler, R. Chem Ber 1992, 125, 1325.
13. Dennis, L. W.; Bartuska, V. J.; Maciel, G. E. J Am Chem Soc 1982, 104, 230.
14. The structure of the phenyl analogue of 5 was found to be square-pyramidal; cf. Ref. [10].
15. Goerlich, J. R.; Fischer, A.; Jones, P. G.; Plack, V.; Schmutzler, R. Z Naturforsch 1993, 48b, 341.
16. Plack, V.; Goerlich, J. R.; Thönnessen, H.; Jones, P. G.; Schmutzler, R. submitted for publication.
17. Plack, V.; Goerlich, J. R.; Fischer, A.; Thönnessen, H.; Jones, P. G.; Schmutzler, R. Z Anorg Allg Chem 1995, 621, 1080.