Phosphorus-carbon bond activation of PMe3 at a dimolybdenum center: Synthesis and structure of [Cp*Mo(μ-O2CMe)]2(μ-PMe2)(μ-Me)

Chemical Communications

Volumn , Issue 12, 1998, Pages 1273-1274

  Shin, Jun Ho ^a   Parkin, Gerard ^a  

^a Och Spine at New York Presbyterian Hospitals   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0004603361     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a801835i     Document Type: Article

References (8)

1. Multiple Bonds Between Metal Atoms, ed. F. A. Cotton and R. A. Walton, Clarendon Press, Oxford, 2nd edn., 1993.
2. See, for example: J. H. Shin and G. Parkin, Polyhedron, 1994, 13, 1489.
3. 3c (a) J. C. Smart and C. J. Curtis, Inorg. Chem., 1978, 17, 3290;
4. (b) J. Bashkin, M. L. H. Green, M. L. Poveda and K. Prout, J. Chem. Soc., Dalton Trans., 1982, 2485;
5. (c) M. C. Kuchta, F. G. N. Cloke and P. B. Hitchcock, Organometallics, 1998, 17, 934.
6. 1, = 0.0404 [I > 2σ(I)]. The hydrogen atoms of the bridging methyl group were located and refined isotropically, giving the following bond lengths (Å): Cl-Hla 0.86, Cl-Hlb 0.97, Cl-Hlc 0.84 Å. CCDC 182/868.
7. P. E. Garrou, Chem. Rev., 1985, 85, 171;
8. M. Michman, Isr. J. Chem., 1986, 27, 241.