Structure, Stability, and Reactivity of Cationic Hydrogen Trioxides and Thermochemistry of their Neutral Analogs. A Fourier-Transform Ion Cyclotron Resonance Study

Inorganic Chemistry

Volumn 35, Issue 21, 1996, Pages 6140-6151

  Speranza, Maurizio ^a  

^a SAPIENZA UNIVERSITY OF ROME   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0004592749     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960549s     Document Type: Article

References (75)

1. Steinfeld, J. I.; Alder-Golden, S. M.; Gallagher, J. W. J. Phys. Chem. Ref. Data 1987, 16, 911.
2. Horvath, M.; Bilitzky, L.; Huttner, J. In Topics in Inorganic Chemistry; Clark, R. J. H., Ed.; 1985; Vol 20.
3. Salem, L. Electrons in Chemical Reactions: First Principles; Wiley: New York, 1982.
4. Plesnicar, B. Organic Peroxides; Ando, W., Ed.; Wiley: New York, 1992.
5. Arnold, D. W.; Xu, C.; Kim, E. H.; Neumark, D. M. J. Chem. Phys. 1994, 101, 912.
6. Goddard, W. A., III; Dunning, T. H., Jr.; Hunt, W. J.; Hay, P. J. Acc. Chem. Res. 1973, 6, 368.
7. Benson, S. W. Thermochemical Kinetics; Wiley; New York, 1968.
8. Blint, R. J.; Newton, M. D. J. Chem. Phys. 1973, 59, 6220.
9. Nangia, P. S.; Benson, S. W. J. Phys. Chem. 1979, 83, 1138.
10. Nangia, P. S.; Benson, S. W. J. Am. Chem. Soc. 1980, 102, 3105.
11. Brich Mathisen, K; Gropen, O; Skancke, P. N.; Wahlgren, U. Acta Chem. Scand. A 1983, 37, 817.
12. Brich Mathisen, K.; Sieghban, P. E. M. Chem. Phys. 1984, 90, 225.
13. Dupuis, M.; Fitzgerald, G.; Hammond, B.; Lester, W. A., Jr.; Schaefer, H.F., III J. Chem. Phys. 1986, 84, 2691.
14. Vincent, M. A.; Hillier, I. H.; Burton, N. A. Chem. Phys. Lett. 1995, 233, 111.
15. Benson, S. W. J. Chem. Phys. 1960, 33, 306.
16. Radom, L.; Hehre, W. J.; Pople, J. A. J. Am. Chem. Soc. 1971, 93, 289.
17. Jackels, C. F.; Phillips, D. H. J. Chem. Phys. 1986, 84, 5013.
18. Gonzales, C.; Theisen, J.; Zhu, L.; Schlegel, H. B.; Hase, W. L.; Kaiser, E. W. J. Phys. Chem. 1991, 95, 6784.
19. Zhao, M.; Gimarc, B. J. Phys. Chem. 1993, 97, 4023.
20. Vincent, M. A.; Millier, I. H. J. Phys. Chem. 1995, 99, 3109.
21. Koller, J.; Plesnicar, B. J. Am. Chem. Soc. 1996, 118, 2470.
22. Kausch, M.; Schleyer, P.v.R. J. Comput. Chem. 1980, 1, 94.
23. Meredith, C.; Quelch, G. E.; Schaefer, H. F., III J. Am. Chem. Soc. 1991, 113, 1186.
24. Zakharov, I. I; Kolbasina, O. I.; Semenyuk, T. N.; Tyupalo, N.; Zhidomirov, G. M. Zh. Strukt. Khim. 1993, 34, 28.
25. Cacace, F.; Speranza, M. Science 1994, 265, 208.
26. Smith, G. P.; Lee, L. C. J. Chem. Phys. 1978, 69, 5393 and references therein.
27. Gromov, A. R.; Antipenko, E. E.; Strakhov, B. V. Zh. Fiz. Khim. 1990, 64, 77.
28. Cerkovnik, J.; Plesnicar, B. J. Am. Chem. Soc. 1993, 115, 12169.
29. Czapski, G.; Bielski, B. H. J. J. Phys. Chem. 1963, 67, 2180.
30. Bielski, B. H. J.; Schwarz, H. A. J. Phys. Chem. 1968, 72, 3836.
31. Giguère, P. A.; Herman, K. Can. J. Chem. 1970, 48, 3473.
32. Deglise, X.; Giguère, P. A. Can. J. Chem. 1971, 49, 2242.
33. Arnau, J. L.; Giguère, P. A. J. Chem. Phys. 1974, 60, 270.
34. Yagodovskaya, T. V.; Zhogin, D. Y.; Nekrasov, L. I. Zh. Fiz. Khim. 1976, 50, 2736.
35. Blahous, C. P., III; Schaefer, H. F., III J. Phys. Chem. 1988, 92, 959.
36. Fehsenfeld, F. C.; Moseman, M.; Ferguson, E. E. J. Chem. Phys. 1971, 55, 2115.
37. Olah, G. A.; Yoneda, N.; Parker, D. G. J. Am. Chem. Soc. 1976, 98, 5261.
38. Yoneda, N.; Olah, G. A. J. Am. Chem. Soc. 1977, 99, 3113.
39. Fehsenfeld, F. C.; Ferguson, E. E. J. Geophys. Res. 1969, 74, 2217.
40. Ferguson, E. E.; Fehsenfeld, F. C. J. Geophys. Res. 1969, 74, 5743.
41. Adams, N. G.; Bohme, D. K.; Dunkin, D. B.; Fehsenfeld, F. C.; Ferguson, E. E. J. Chem. Phys. 1970, 52, 3133.
42. Howard, C. J.; Bierbaum, V. M.; Rundle, H. W.; Kaufman, F. J. Chem. Phys. 1972, 57, 3491.
43. Good, A.; Durden, D. A.; Kebarle, P. Proceedings of the Symposium of the Physics and Chemistry of the Upper Atmosphere; Stanford Research Inst.: Palo Alto, CA, 24-25 June 1969.
44. Mehandjiev, D.; Naidenov, A. Ozone Sci. Eng. 1983, 14, 277.
45. Johnstone, W. M.; Mason, N. J.; Newell, W. R.; Biggs, P.; Martson, G.; Wayne, R.P. J. Phys. B 1992, 25, 3873.
46. Olmstead, W. N.; Brauman, J. I. J. Am. Chem. Soc. 1977, 99, 4219.
47. Ikezoe, Y.; Matsuoka, S.; Takebe, M.; Viggiano, A. A. Gas Phase Ion-Molecule Reaction Rate Constants Through 1986; Maruzen Company, Ltd.: Tokyo, 1987.
48. Bartmess, J. E.; Georgiadis, R. M. Vacuum 1983, 33, 149.
49. De Koning, L. J.; Fokkens, R. H.; Pinkse, F. A.; Nibbering, N. M. M. Int. J. Mass Spectrom. Ion Processes 1987, 77, 95.
50. Su, T.; Chesnavich, W. J. J. Chem. Phys. 1982, 76, 5183.
51. Weiss, M. J.; Berkowitz, J.; Appleman, E. H. J. Chem. Phys. 1977, 66, 2049.
52. 18O.
53. Susic, R.; Kralj, B.; Zigon, D. Rapid Commun. Mass Spectrom. 1995, 9, 64.
54. Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data 1988, 17, Suppl. No. 1.
55. Szulejko, J. E.; McMahon, T. B. J. Am. Chem. Soc. 1993, 115, 7839.
56. Chen, M. M. L.; Wetmore, R. W.; Schaefer, H. F., III J. Chem. Phys. 1981, 74, 2938.
57. Ferguson, E. E. In Ion-Molecule Reactions; Franklin, J. L. Ed.; Butterworths: London, 1972; Vol. 2, Chapter 8.
58. Ferguson, E. E.; Fehsenfeld, F. C.; Albritton, D. L. In Gas-Phase Ion Chemistry; Bowers, M. T. Ed.; Academic Press: New York, 1979; Vol. 1, Chapter 2.
59. The FT efficiency can be depressed if the FT process is nearly thermoneutral or if hindered bases are involved; cf.: Bucker, H.; Grutzmacher, H. F. Int. J. Mass Spectrom. Ion Processes 1991, 109, 95.
60. 3OH ((s) in Table 5) do not apparently fit the interpolating curve of Figure 5. This derives from the fact that, in these systems, the PT reaction undergoes competion from an efficient ET process and, therefore, the comparatively low PT efficiencies do not reflect a slow PT reaction, but just the branching ratio between two fast, competing processes.
61. Zappey, H. W.; Ingemann, S.; Nibbering, N. M. M. J. Am. Soc. Mass Spectrom. 1992, 3, 515.
62. Bouma, W. J.; Nobes, R. H.; Radom, L. Org. Mass Spectrom. 1982, 17, 315.
63. (a) Huntress, W. T., Jr.; Sen Sharma, D. K.; Jennings, K.; Bowers, M. T. Int. J. Mass Spectrom. Ion Physics 1977, 24, 25.
64. (b) Nobes, R. H.; Radom, L. Org. Mass Spectrom. 1982, 17, 340.
65. Uggerud, E. J. Am. Chem. Soc. 1994, 116, 6873.
66. Nhuyen, M. T.; Bouchoux, G. J. Phys. Chem. 1996, 100, 2089.
67. Rowe, B. R.; Fahey, D. W.; Ferguson, E. E.; Feshenfeld, F. C. J. Chem. Phys. 1981, 75, 3325.
68. (a) Eller, K.; Schwarz, H. Chem. Rev. 1991, 91, 1121, and references therein.
69. (b) Schroder, D.; Schwarz, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 1973 and references therein.
70. Kappes, M. M.; Staley, R. H. J. Phys. Chem. 1981, 85, 942.
71. Kappes, M. M.; Staley, R. H. J. Am. Chem. Soc. 1981, 103, 1286.
72. Baranov, V.; Javahery, G.; Hopkinson, A. C.; Bohme, D. K. J. Am. Chem. Soc. 1995, 117, 12801.
73. Gill, P. M. W.; Radom, L. J. Am. Chem. Soc. 1988, 110, 4931.
74. Barnett, R. N.; Landman, U. J. Phys. Chem. 1995, 99, 17305.
75. de Visser, S. P.; de Koning, L. J.; Nibbering, N. M. M. J. Phys. Chem. 1995, 99, 15444.