Mono- and dinuclear d10 metal complexes of hexakis(3,5-dimethylpyrazolyl)cyclotriphosphazene. Synthesis, structures, and unusual solution dynamic behavior

Inorganic Chemistry

Volumn 35, Issue 13, 1996, Pages 3981-3989

  Byun, Younghun ^a   Min, Dongwon ^a   Do, Junghwan ^b   Yun, Hoseop ^b   Do, Youngkyu ^a  

^a Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

^b Ajou University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0004529347     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic950907b     Document Type: Article

References (40)

1. (a) Alkock, H. R.; Desorcie, J. L.; Riding, G. H. Polyhedron 1987, 6, 119
2. (b) Allcock, H. R. In Rings, Clusters, and Polymers of the Main Group Elements, Cowley, A H., Ed.; ACS Symposium Series; American Chemical Society: Washington, DC, 1983; Chapter 3.
3. (c) Allcock, H. R. Phosphorus-Nitrogen Compounds: Cyclic, Linear and High Polymeric Systems; Academic Press: New York and London. 1972.
4. (a) Chandrasekhar, V.; Thomas, K. R. J Struct. Bonding (Berlin) 1993, 81, 41
5. (b) Allen, C. W. Chem. Rev. 1991, 91, 133.
6. (a) Mark, J. E.; Allcock, H. R.; West, R. Inorganic Polymers; Prentice-Hall Inc.: New York, 1992; Chapter 3.
7. (b) Chandrasekhar, V.; Thomas, K. R J Appl. Organomet. Chem. 1993, 7, 1.
8. (a) Allcock, H. R.; Turner, M. L. Macromolecules 1993, 26, 3,
9. (b) Allcock, H. R.; Dodge, J. A.; Manners, I.; Parvez, M.; Riding, G. H.; Visscher, K. B. Organometallics 1991, 10, 3098.
10. (c) Allcock, H. R.; Dodge, J. A.; Manners, I.; Riding, G. H. J. Am. Chem. Soc. 1991, 113, 9596.
11. (d) Manners, I.; Riding, G. H.; Dodge, J. A.; Allcock, H. R. J. Am. Chem. Soc. 1989, 111, 3067.
12. (e) Manners, I.; Coggio, W. D.; Mang, M. N.; Parvez, M.; Allcock, H. R. J. Am. Chem. Soc. 1989, 111, 3481.
13. (a) Thomas, K. R. J., Tharmaraj, P.; Chandrasekhar, V.; Bryan, C. D.; Cordes, A. W. Inorg. Chem. 1994, 33, 5382.
14. (b) Thomas, K. R. J.; Tharmaraj, P.; Chandrasekhar, V.; Tiekink, E. R. T. J. Chem. Soc., Dalton Trans. 1994, 1301.
15. (a) Chandrasekaran, A.; Krishnamurthy, S. S., Nethaji, M. J. Chem. Soc., Dalton Trans. 1994, 63.
16. (b) Chandrasekaran, A.; Krishnamurthy, S. S.; Nethaji, M. Inorg. Chem. 1994, 33, 3085.
17. (c) Chandrasekaran, A.; Krishnamurthy, S. S.; Nethaji, M. Inorg. Chem. 1993, 32, 6102.
18. (a) Allcock, H. R.; Nissan, R. A.; Harris, P. J., Whittle, R. R. Organometallics 1984, 3, 432.
19. (b) Allcock, H. R.; Lavin, K. D.; Tollefson, N. M.; Evans, T. L. Organumetallics 1983, 2, 432.
20. (c) Allcock, H. R.; Manners, I.; Mang, M. N.; Parvez, M Inorg. Chem. 1990, 29, 522.
21. (d) Allcock, H. R., Scopelianos, A. G.; Whittle, R. R.; Tollefson, N M. J. Am Chem. Soc. 1983, 105, 1316.
22. (a) Gallicano, K. D.; Paddock, N. L., Rettig, S. J.; Trotter, J. Inorg. Nucl. Chem Lett. 1979, 15, 417.
23. (b) Gallicano, K. D.; Paddock, N. L. Can. J. Chem. 1982, 60, 521.
24. Thomas, K. R. J.; Chandrasekhar, V.; Pal, P.; Scott, S. R.; Hallford, R.; Cordes, A. W. Inorg. Chem. 1993, 32, 606.
25. Thomas, K. R. J.; Chandrasekhar, V.; Scott, S. R.; Hallford, R.; Cordes, A. W. J. Chem. Suc., Dalton Trans. 1993, 2589.
26. Min, D.; Do, Y. Chem. Lett. 1994, 1989.
27. (a) Schriver, D. F.; Drezdzon, M. A. The Manipulation of Air-Sensitive Compounds, 2nd ed.; John Wiley & Sons, Ine: New York, 1986.
28. (b) Wayda, A. L., Darensbourg, M.-Y., Eds. Experimental Organometallic Chemistry; ACS Symposium Series 357; American Chemical Society Washington, DC, 1987.
29. Perrin, D. D.; Armarego, W. L. F. Purification of Laboratory Chemicals, 3rd ed.; Pergamon Press; London, 1988.
30. Sheldrick, G. M. SHELXS 86. Program for Crystal Structure Determination; University of Göttingen: Göttingen, Germany, 1986.
31. Sheldrick, G. M. SHELXL 93. Program for Crystal Structural Determination; University of Göttingen: Gottingen, Germany, 1993.
32. 1H-NMR, δ 5.79, 2.16, and 2.09.
33. All compounds were well characterized, and a manuscript is in preparation for submission to Inorg Chem.
34. Krishnamurthy, S. S.; Sau, A. C.; Woods, M. Adv. Inorg. Chem. Radiochem. 1978, 21, 41.
35. (a) Craig, D. P.; Paddock, N. L. Nature 1958, 181, 1052.
36. (b) Craig, D. P.; Mitchell, K. A. R. J. Chem. Soc. 1965, 4682.
37. Shannon, R D. Acta Crystallogr. 1976, A32, 751.
38. Related figures and illustrations are deposited as Supporting Information
39. (a) Summers, M. F.; Marzill, L G. Inorg. Chem. 1984, 23, 523.
40. (b) Munakata, M.; Kitagawa, S.; Yagi, F. Inorg. Chem. 1986, 25, 964.