Chain-length dependence of the dissociation dynamics of oriented molecular adsorbates: n-Alkyl bromides on GaAs(110)

Journal of Physical Chemistry B

Volumn 103, Issue 26, 1999, Pages 5530-5542

  Khan, Khalid A ^a   Camillone III, Nicholas ^a   Osgood Jr , Richard M ^a  

^a Och Spine at New York Presbyterian Hospitals   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0004411273     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp990782m     Document Type: Article

References (55)

1. Marsh, E. P.; Tabares, F. L.; Schneider, M. R.; Gilton, T. L.; Meir, W.; Cowin, J. P. Phys. Rev. Lett. 1988, 60, 2551.
2. Zhou, X. L.; Zhu, X. Y.; White, J. M. Surf. Sci. Rep. 1991, 13, 76.
3. Ukrainstev, V. A.; Long, T. J.; Harrison, I. J. Chem. Phys. 1992, 96, 3957.
4. Lu, P. H.; Lasky, P. J.; Yang, Q. Y.; Osgood, R. M., Jr. Chem. Phys. 1996, 205, 143.
5. Khan, K. A.; Moryl, J. E.; Slater, D. A.; Lasky P. J.; Osgood, R. M., Jr. J. Phys. Chem. B 1997, 101, 9077.
6. Khan, K. A.; Camillone, N., III; Osgood, R. M., Jr. J. Chem. Phys. 1999, 110, 10526.
7. Rowntree, P.; Sanche, L.; Parenteau, L.; Meinke, M.; Weik, F.; Illenberger, E. J. Chem. Phys. 1994, 101, 4248.
8. Ayotte, P.; Gamache, J.; Bass, A. D.; Fabrikant, I. I.; Sanche, L. J. Chem. Phys. 1997, 106, 749.
9. Sanche, L.; Bass, A. D.; Ayotte, P.; Fabrikant, I. I. Phys. Rev. Lett. 1995, 75, 3568.
10. Camillone, N., III; Khan, K. A.; Lasky, P. J.; Wu, L.; Moryl, J. E.; Osgood, R. M., Jr. J. Chem. Phys. 1998, 109, 8045.
11. Avouris, P.; Persson, B. N. J. J. Phys. Chem. 1984, 88, 837.
12. Dixon-Warren, St. J.; Jensen, E. T.; Polanyi, J. C. J. Chem. Phys. 1993, 98, 5938.
13. Yang, Q. Y.; Schwarz, W. N.; Osgood, R. M., Jr. J. Chem. Phys. 1993, 98, 10085.
14. Yang, Q. Y.; Osgood, R. M., Jr. J. Phys. Chem. 1993, 97, 8855.
15. Yang, Q. Y.; Schwarz, W. N.; Lasky, P. J.; Hood, S. C.; Loo, N. L.; Osgood, R. M., Jr. Phys. Rev. Lett. 1994, 72, 3068.
16. Black, S.; Friesner, R.; Lu, P. H.; Osgood, R. M., Jr. Surf. Sci. 1997, 382, 154.
17. Lasky, P. J.; Lu, P. H.; Yang, M. X.; Osgood, Jr., R. M.; Bent, B. E.; Stevens, P. A. Surf. Sci. 1995, 336, 140.
18. Fairbrother, D. H.; Briggman, K. A.; Stair, P. C.; Weitz, E. J. Chem. Phys. 1995, 102, 7267.
19. Holbert, V. P.; Garrett, S. J.; Bruns, J. C.; Stair, P. C.; Weitz, E. Surf. Sci. 1994, 314, 107.
20. Dixon-Warren, St. J.; Heyd, D. V.; Jensen, E. T.; Polanyi, J. C. J. Chem. Phys. 1993, 98, 5954.
21. Lu, P. H.; Lasky, P. J.; Yang, Q. Y.; Wang, Y.; Osgood, R. M., Jr. J. Chem. Phys. 1994, 101, 10145.
22. Meyer, R. J.; Duke, C. B.; Paton, A.; Kahn, A.; So, E.; Yeh, J. L.; Mark, P. Phys. Rev. B 1979, 19, 10.
23. Pedrotti, F. L.; Pedrotti, L. S. Introduction to Optics, 2nd ed.; Prentice Hall: Englewood Cliffs, NJ, 1993; Chapter 20.
24. Properties of Gallium Arsenide, 3rd ed.; Brozel, M. R., Stillman, G. E., Eds.; INSPEC: London, 1996.
25. Redhead, P. A. Vacuum 1962, 12, 203.
26. Due to a recalibration of our TOF apparatus, the average energies for the ethyl fragments are different from those reported earlier in ref 5.
27. Yang, Q. Y.; Schwarz, W. N.; Hood, S. C.; Loo, N. L.; Osgood, R. M., Jr. Surf. Sci. 1993, 298, 195.
28. Zhu, X.-Y. Annu. Rev. Phys. Chem. 1994, 45, 113.
29. Gadzuk, J. W.; Richter, L. J.; Buntin, S. A.; King, D. S.; Cavanagh, R. R. Surf. Sci. 1990, 235, 317.
30. 3Br on GaAs(110).
31. Huang, Z.-H.; Guo, H. J. Chem. Phys. 1993, 98, 3395.
32. French, C.; Harrison, I. Surf. Sci. 1997, 387, 11.
33. Garrett, S. J.; Heyd, D. V.; Polanyi, J. C. J. Chem. Phys. 1997, 106, 7834.
34. Stinnett, J. A.; Madix, R. J.; Tully, J. C. J. Chem. Phys. 1996, 104, 3134.
35. Stinnett, J. A.; Weaver, J. F.; Madix, R. J. Surf. Sci. 1998, 395, 148.
36. McMaster, M. C.; Schroeder, S. L. M.; Madix, R. J. Surf. Sci. 1993, 297, 253.
37. McMaster, M. C.; Arumainayagam, C. R.; Madix, R. J. Chem. Phys. 1993, 177, 461.
38. Pianetta, P.; Lindau, I.; Garner, C. M.; Spicer, W. E. Phys. Rev. B 1978, 18, 2792.
39. Northrup, J. E.; Foyen, S. Mater. Sci. Eng. B 1995, 30, 81.
40. Mokwa, W.; Kohl, D.; Heiland, G. Surf. Sci. 1984, 139, 98.
41. Büchel, M.; Lüth, H. Surf. Sci. 1979, 87, 285.
42. Sasaki, M.; Yoshida, S. Surf. Sci. 1996, 356, 233-246.
43. Sugawara, S.; Sasaki, M.; Yamamoto, S. Appl. Surf. Sci. 1998, 130-132, 387.
44. Zhu, X.-Y. J. Chem. Phys. 1993, 98, 3410.
45. Wentworth, W. E.; George, R.; Keith, H. J. Chem. Phys. 1969, 51, 1791.
46. Modelli, A.; Scagnolari, F.; Destefano, G.; Jones, D.; Guerra, M. J. Chem. Phys. 1992, 96, 2061.
47. Zhu, Q.; Cao, J. R.; Wen, Y.; Zhang, J.; Zhong, X.; Huang, Y.; Fang, W.; Wu, X. Chem. Phys. Lett. 1988, 144, 486.
48. Kawasaki, M.; Kasatani, K.; Sato, H.; Shinohara, H.; Nishi, N. Chem. Phys. 1984, 88, 135.
49. This similarity between these two dissociative events has been noted previously, viz., in harpooning reactions of alkyl halides with alkali metal atoms in crossed molecular beams: Herschbach, D. R. Adv. Chem. Phys. 1966, 10, 319.
50. Miskovic, Z.; Vukanic, J.; Madey, T. E. Surf. Sci. 1984, 141, 285.
51. Guest, R. J.; Goldby, I. M.; Palmer, R. E.; Bly, D. N.; Hartley, D. M.; Rous, P. J. Faraday Discuss. 1993, 96, 117.
52. Clinton, W. L. Surf. Sci. 1981, 112, L791.
53. Francisco, T. W.; Camillone, N., III; Miller, R. E. Phys. Rev. Lett. 1996, 77, 1402.
54. Watson, J. M.; NoorBatcha, I.; Lucchese, R. R. J. Chem. Phys. 1992, 96, 7771.
55. Guo, H.; Liu, L. Surf. Sci. 1997, 372, 337.