Synthesis and Crystal Structure of [Cd10Se4(SePh)12(PPh3)4] and [Cd16(SePh)32(PPh3)2]

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 24, 1997, Pages 2797-2799

  Behrens, Silke ^a   Bettenhausen, Marco ^a   Eichhöfer, Andreas ^a   Fenske, Dieter ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

Cadmium; Clusters; Nanostructures; Selenium; Structure elucidation

Indexed keywords

EID: 0003633927     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199727971     Document Type: Article

References (17)

1. C. J. Murphy, J. Cluster Science 1996, 7, 341.
2. C. B. Murray, D. J. Norris, M. G. Bawendi, J. Am. Chem. Soc. 1993, 115, 8706.
3. H. Weller, Angew. Chem. 1993, 105, 43; Angew. Chem. Int. Ed. Engl. 1993, 32, 41.
4. H. Weller, Angew. Chem. 1993, 105, 43; Angew. Chem. Int. Ed. Engl. 1993, 32, 41.
5. I. G. Dance, K. Fisher in Progress in Inorganic Chemistry, vol. 41, (Ed.: K. D. Karlin), 1994.
6. S. Behrens, M. Bettenhausen, A. C. Deveson, A. Eichhöfer, D. Fenske, A. Lohde, U. Woggon, Angew. Chem. 1996, 108, 2361; Angew. Chem. Int. Ed. Engl. 1996, 35, 2215.
7. S. Behrens, M. Bettenhausen, A. C. Deveson, A. Eichhöfer, D. Fenske, A. Lohde, U. Woggon, Angew. Chem. 1996, 108, 2361; Angew. Chem. Int. Ed. Engl. 1996, 35, 2215.
8. N. Herron, J. C. Calabrese, W. E. Farneth, Y. Wang, Science 1993, 259, 1426.
9. T. Vossmeier, G. Reck, B. Schulz, L. Katsikas, H. Weller, J. Am. Chem. Soc. 1995, 117, 12881.
10. -3. Se4, Se14, Se15, and some of the phenyl groups are disordered over two sites. Refinement in Ia and I2 did not lead to any improvement in terms of this disorder. Other crystals also showed this disorder. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Center as supplementary publication no. CCDC-100535. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: int. code + (1223)336-033; e-mail: deposit@chemcrys.cam.ac.uk).
11. V. M. Goldschmidt in Geochemische Verteilungsgesetze der Elemente, Bd. 8, Untersuchungen über Bau und Eigenschaften von Krystallen (Ed.: J. Dybwad), Oslo, 1927.
12. D. Craig, I. G. Dance, R. Garbutt, Angew. Chem. 1986, 98, 178; Angew. Chem. Int. Ed. Engl. 1986, 25, 165; I. G. Dance, R. G. Garbutt, D. C. Craig, M. L. Scudder, Inorg. Chem. 1887, 26, 4057.
13. D. Craig, I. G. Dance, R. Garbutt, Angew. Chem. 1986, 98, 178; Angew. Chem. Int. Ed. Engl. 1986, 25, 165; I. G. Dance, R. G. Garbutt, D. C. Craig, M. L. Scudder, Inorg. Chem. 1887, 26, 4057.
14. D. Craig, I. G. Dance, R. Garbutt, Angew. Chem. 1986, 98, 178; Angew. Chem. Int. Ed. Engl. 1986, 25, 165; I. G. Dance, R. G. Garbutt, D. C. Craig, M. L. Scudder, Inorg. Chem. 1887, 26, 4057.
15. I. G. Dance, R. G. Garbutt, T. D. Bailey, Inorg. Chem. 1990, 29, 603.
16. Se4, Se14, Se14′, and Se15 are disordered over two sites. For reasons of clarity only the coordinates of the center of gravity are shown.
17. E. Keller, SCHAKAL-A FORTRAN Program for Graphical Representation of Molecular and Crystallographic Models, Universität Freiburg, 1992.