Electrochemical and IR Spectroelectrochemical Studies of the Electrocatalytic Reduction of Carbon Dioxide by [Ir2(dimen)4]2+ (dimen = 1,8-Diisocyanomenthane)

Inorganic Chemistry

Volumn 35, Issue 26, 1996, Pages 7704-7708

  Cheng, Stephen C ^a   Blaine, Christine A ^a,b   Hill, Michael G ^a,c   Mann, Kent R ^a  

^a University of Minnesota   (United States)

^b CARTHAGE COLLEGE   (United States)

^c OCCIDENTAL COLLEGE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0003356228     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9512385     Document Type: Article

References (50)

1. Zhang, J. J.; Pietro, W. J.; Lever, A. B. P. J. Electroanal. Chem. 1996, 403, 93.
2. Xu, X. D.; Moulijn, J. A. Energy Fuel 1996, 10, 305.
3. Bhugun, I.; Lexa, D.; Saveant, J. M. J. Am. Chem. Soc. 1996, 118, 1769.
4. Lee, Y. F.; Kirchhoff, J. R.; Berger, R. M.; Gosztola, D. J. Chem. Soc., Dalton Trans. 1995, 22, 3677.
5. (a) Toyohara, K.; Nagao, H.; Mizukawa, T.; Tanaka, K. Inorg. Chem. 1995, 34, 5399.
6. (b) Kushi, Y.; Nagao, H.; Nishioka, T.; Isobe, K.; Tanaka, K. J. Chem. Soc. Ch. 1995, 12, 1223.
7. (c) Kushi, Y.; Nagao, H.; Nishioka, T.; Isobe, K.; Tanaka, K. Chem. Lett. 1994, 11, 2175.
8. (d) Ishida, H.; Fujiki, K.; Ohba, T.; Ohkubo, K.; Tanaka, K.; Terada, T.; Tanaka, T. J. Chem. Soc., Dalton Trans. 1990, 2155.
9. (a) Christensen, P. A.; Hamnett, A.; Higgins, S. J.; Timney, J. A. J. Electroanal. Chem. 1995, 395, 195.
10. (b) Christensen, P. A.; Higgins, S. J. J. Electroanal. Chem. 1995, 387, 127.
11. (c) Christensen, P.; Hamnett, A.; Muir, A. V. G.; Timney, J. A. J. Chem. Soc., Dalton Trans. 1992, 1455.
12. (d) Christensen, P. A.; Hamnett, A.; Muir, A. V. G.; Freeman, N. A. J. Electroanal. Chem. 1990, 288, 197.
13. Steffey, B. D.; Curtis, C. J.; Dubois, D. L. Organometallics 1995, 14, 4937.
14. Ortiz, R.; Marquez, O. P.; Marquez, J.; Gutierrez, C. J. Electroanal. Chem. 1995, 390, 99.
15. Ogata, T.; Yanagida, S.; Brunschwig, B. S.; Fujita, E. J. Am. Chem. Soc. 1995, 117, 6708.
16. (a) Arana, C.; Keshavarz, M.; Potts, K. T.; Abruna, H. D. Inorg. Chim. Acta 1994, 225, 285.
17. (b) Arana, C.; Tan, S.; Keshavarz-K. M.; Potts, K. T.; Abruna, H. D. Inorg. Chem. 1992, 31, 3680.
18. (a) Haines, R. J.; Wittrig, R. E.; Kubiak, C. P. Inorg. Chem. 1994, 33, 4723.
19. (b) Morgenstern, D. A.; Wittrigm, R. E.; Fanwick, P. E.; Kubiak, C. P. J. Am. Chem. Soc. 1993, 115, 6470.
20. (c) Ratliff, K. S.; Lentz, R. E.; Kubiak, C. P. Organometallics 1992, 11, 1986.
21. (d) Reinking, M. K.; Ni, J.; Fanwick, P. E.; Kubiak, C. P. J. Am. Chem. Soc. 1989, 111, 6459.
22. (a) Keene, F. R.; Sullivan, B. P. In Electrochemical and Electrocatalytic Reactions of Carbon Dioxide; Sullivan, B. P., Krist, K., Guard, H. E., Eds.; Elsevier: Amsterdam, 1993.
23. (b) Brace, M. R. M.; Megehee, E.; Sullivan, B. P.; Thorp, H. H.; O'Toole, T. R.; Downard, A.; Pugh, J. R.; Meyer, T. J. Inorg. Chem. 1992, 31, 4864.
24. (c) Pugh, J. R.; Bruce, M. R. M.; Sullivan, B. P.; Meyer, T. J. Inorg. Chem. 1991, 30, 86.
25. (d) Bolinger, C. M.; Story, N.; Sullivan, B. P.; Meyer, T. J. Inorg. Chem. 1988, 27, 4582.
26. (e) Bruce, M. R. M.; Megehee, E.; Sullivan, B. P.; Thorp, H.; O'Toole, T. R.; Downard, A.; Meyer, T. J. Organometallics 1988, 7, 238.
27. Rasmussen, S. C.; Richter, M. M.; Yi, E.; Place, H.; Brewer, K. J. Inorg. Chem. 1990, 29, 3926.
28. Eggins, B. R.; Brown, E. M.; McNeill, E. A.; Grimshaw, J. Tetrahedron Lett. 1988, 29, 945.
29. Slater, S.; Wagenknecht, J. H. J. Am. Chem. Soc. 1984, 106, 5367.
30. Tezuka, M.; Yajima, T.; Tsuchiya, A.; Matsumoto, Y.; Uchida, Y.; Hidai, M. J. Am. Chem. Soc. 1982, 104, 6834.
31. (a) Fisher, B.; Eisenberg, R. J. Am. Chem. Soc. 1980, 102, 7363.
32. (b) O'Connell, C.; Hommeltoft, S. I.; Eisenberg, R. In Carbon Dioxide as a Source of Carbon; Aresta, M., Forti, G., Eds.; D. Reidel Publishing Co.: Dordrecht, The Netherlands, 1987.
33. Desilvestro, J.; Pons, S. J. Electroanal. Chem. 1989, 267, 207.
34. Silavwe, N. D.; Goldman, A. S.; Ritter, R.; Tyler, D. R. Inorg. Chem. 1989, 28, 1231.
35. Smith, T. P. Ph.D. Dissertation, California Institute of Technology, 1982.
36. Sykes, A. G. Ph.D. Dissertation, University of Minnesota, 1990.
37. Herde, J. L.; Lambert, J. C.; Senoff, C. V. Inorg. Synth. 1974, 15, 18.
38. Bullock, J. P.; Mann, K. R. Inorg. Chem. 1989, 28, 4006.
39. Hill, M. G.; Sykes, A. G.; Mann, K. R. Inorg. Chem. 1993, 32, 783.
40. Boyd, D. C.; Rodman, G. S.; Mann, K. R. J. Am. Chem. Soc. 1986, 108, 1779.
41. Hill, M. G.; Mann, K. R. Inorg. Chem. 1991, 30, 1431.
42. Hill, M. G.; Lamanna, W. M.; Mann, K. R. Inorg. Chem. 1991, 30, 4690.
43. Strauss, S. H. Chem. Rev. 1993, 93, 927.
44. 2 reduction products.
45. Hill, M. G. Ph.D. Dissertation, University of Minnesota, 1992.
46. Blaine, C. A.; Ellis, J. E.; Mann, K. R. Inorg. Chem. 1995, 34, 1552.
47. -1.
48. See supplementary Figure 1 in the Supporting Information.
49. Amatore, C.; Saveant, J.-M. J. Am. Chem. Soc. 1981, 103, 5021.
50. Becker, B. F.; Fritz, H. P. Liebigs Ann. Chem. 1976, 1015.