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This result depends, of course, on the choice of the nickel cluster size, the vdW radius of carbon, and the Ni-C distance. None of these quantities are known exactly for any of the species considered here. The general agreement of the observed saturation levels at the FK→SK transition with predictions based on nonoverlapping vdW molecules is in some sense a validation of the commonly used 1.7 Å value for the vdW radius of carbon in the CO molecule.
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24
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85037497435
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note
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In our experiments, the exposure (CO pressure X time) is 12 mTorr X 0.8 ms or 9.6 mTorr ms. In the Vajda et al. experiments, the reaction time is given as 10 ms, and the CO plus He pressure was 0.38 mTorr (0.5 mbar), giving a product of 3.8 mTorr ms.
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A staggered configuration cannot be produced simply by rotating one ring of five CO molecules by 36° (which would reduce overlap), since the 1.9 Å distance between the carbon atom and both nickel atoms in the bridging site must be maintained. The net result is increased overlap compared to the eclipsed configuration.
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