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-1, crystal dimension 0.23 × 0.20 × 0.10 mm, R = 0.031, R = 0.031. The data were collecled (+h.+k.+l) at 293 K on a Rigaku AFC7R four-circle diffractometer equipped with a RU300 18KW rotating anode, in the range of 20 < 40° using a -2 scan at a scan rate of 8 deg/min. A total of 1973 reflections were measured, of which 1637 reflections with 1 > 3(1) were considered as observed. An empirical absorption correction using the program DIFABS was applied (transmission 1.000-0.811). The structure was solved by direct methods and refined by the teXsan crystallographic software package of Molecular Structure Corp. All atoms were refined anisotropically except H atoms were fixed. Oneof nitrogen atoms in ethylenediamine was refined with a disordered model.
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note
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-1, crystal dimension 0.20 × 0.04 ×0.02 mm R = 0.062. R, = 0.065. The data were collected (+h,+k,-l) at 293 K on a Rigaku AFC7R four-circle diffractometer equipped with a RU300 18KW rotating anode, in the range of 20 < 40° using a scan at a scan rate of 4 deg/min. A total of 1388 reflections were measured, of which 676 reflections with 1 > >3(1) were considered as observed. An empirical absorption correction was applied (transmission 1.0000.559). The structure was solved by direct methods and refined by the teXsan crystallographic software package of Molecular Structure Corp. In. Te, and P atoms were refined anisotropically, and carbon atoms were refined isotropically and mostly fixed. One phenyl ring was refined with a disordered model.
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