A one-pot synthesis of alkyl ferrocenyl ketones

Synlett

Volumn , Issue 12, 1998, Pages 1329-1330

  Vukicevic R D ^a   Vukicevic M ^a   Ratkovic Z ^a   Konstantinovic S ^a  

^a UNIVERSITY OF KRAGUJEVAC   (Serbia)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0003072694     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1998-1941     Document Type: Article

References (10)

1. Woodward, R. B.; Rosenblum, M; Whiting, M. J. Org. Chem., 1952, 74, 3458.
2. Togni, A.; Hayashi, T. Ferrocenes, VCH: Weinheim, Germany 1995, and citations therein.
3. Schlögel, K.; Falk, H. Methodicum Chimicum, 1976, Vol 8, Chap. 30, and citations therein.
4. Graham, P.J.; Lindsey, R. V.; Parshall, G. W.; Peterson, M. L.; Whitman, G. M. J. Org. Chem., 1957, 79, 3416.
5. As a recent report see also Taudien, S.; Riant, O.; Kagan, H. B. Tetrahedron Lett., 1995, 36, 3513, and citations therein.
6. Satchell, D. P. N.; Satchell R. S. in The Chemistry of Acid Derivatives; Patai, S., Ed.; Wiley: New York, 1992.
7. Vukićević. R. D.; Ratković, Z.; Vukićević, M; Konstantinović, S. Tetrahedron Lett., 1998, 39, 5837.
8. The reaction was also carried out at low temperature (water/ice/ salt bath) but the yields of the products were the same as those obtained at room temperature.
9. 2 were used and that the reaction mixture was stirred for two hours after addition of the catalyst. It should also be noted that a mixture of toluene and ethyl acetate (9:1) can be used for the more rapid separation of mono-and diacylferrocenes
10. 3, 200 MHz)- δ 207.3, 78.9, 73.2, 70.3, 37.1, 19.0.