Regioselective 1,2-insertion of Ru into the C-S bond in 3-substituted thiophenes

Chemical Communications

Volumn , Issue 18, 1999, Pages 1793-1794

  Planas, Jose Giner ^a   Hirano, Masafumi ^a   Komiya, Sanshiro ^a  

^a TOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKADIENE; CARBON; RUTHENIUM DERIVATIVE; SULFUR; THIOPHENE;

ARTICLE; CHEMICAL REACTION; COVALENT BOND; DESULFURIZATION; STEREOCHEMISTRY;

EID: 0003055406     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a905748j     Document Type: Article

References (19)

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2. W. D. Jones, D. A. Vicic, R. M. Chin, J. H. Roache and A. W. Myers, Polyhedron, 1997, 16, 3115; R. J. Angelici, Polyhedron, 1997, 16, 3073; C. Bianchini and A. Meli, Acc. Chem. Res., 1998, 31, 109; C. Bianchini, D. Masi, A. Meli, M. Peruzzini, F. Vizza and F. Zanobini, Organometallics, 1998, 17, 2495.
3. W. D. Jones, D. A. Vicic, R. M. Chin, J. H. Roache and A. W. Myers, Polyhedron, 1997, 16, 3115; R. J. Angelici, Polyhedron, 1997, 16, 3073; C. Bianchini and A. Meli, Acc. Chem. Res., 1998, 31, 109; C. Bianchini, D. Masi, A. Meli, M. Peruzzini, F. Vizza and F. Zanobini, Organometallics, 1998, 17, 2495.
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11. C=O).
12. W) = 0.068(0.081)for 6755 reflections. Single crystals of both 2b and 5a were recrystallised from acetone and mounted in a glass capillary. Both structures were solved using heavy atom Patterson methods and refined by full-matrix least squares on F. CCDC 182/1364. See http://www.rsc.org/suppdata/cc/ 1999/1793/ for crystallographic data in .cif format.
13. C=O).
14. T. Morikita, M. Hirano, A. Sasaki and S. Komiya, Inorg. Chim. Acta, 1999, 291, 341.
15. Thiophenes investigated: 2-methyl-, 3-methyl-and 2,5-dimethyl-thiophene.
16. -1.
17. (a) S. Harris and R. R. Chianelli, J. Catal., 1984, 86, 400;
18. (b) L. Dong, S. B. Duckett, K. F. Ohman and W. D. Jones, J. Am. Chem. Soc., 1992, 114, 151.
19. 5 were -0.62 and -0.40 for 3-acetyl thiophene and -0.63 and -0.41 for 3-formyl thiophene, respectively.