Reaction of ethynediyl, butadiynediyl and ethynyl iron complexes, (η5-C5R5)(CO)2Fe-(C≢C)n-X [X=Fe(η5-C5R5)(CO)2, H; R5=Me5, Me4Et; N=1, 2], with Fe2(CO)9 leading to polynuclear C2 and C4 complexes

Journal of Organometallic Chemistry

Volumn 565, Issue 1-2, 1998, Pages 49-62

  Akita, Munetaka ^a   Chung, Min Chul ^a   Terada, Masako ^a   Miyauti, Masanori ^a   Tanaka, Masako ^a   Moro oka, Yoshihiko ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Cluster compounds; Dicarbide; Polyynediyl complexes

Indexed keywords

EID: 0003044906     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(98)00442-2     Document Type: Article

References (71)

1. (a) W. Beck, B. Niemer, M. Wieser, Angew. Chem. Int. Ed. Engl. 32 (1993) 923.
2. (b) H. Lang, Angew. Chem. Int. Ed. Engl. 33 (1994) 547.
3. (c) U. Bunz, Angew. Chem. Int. Ed. Engl. 35 (1996) 969.
4. C2 complexes: (a) G. Frapper, J.-F. Halet, Organometallics 14 (1995) 5044.
5. (b) G. Frapper, J.-F. Halet, M.I. Bruce, Organometallics 16 (1997) 2590.
6. (c) J. Silvetre, R. Hoffmann, Helv. Chim. Acta 68 (1985) 1461.
7. (d) See also ref. ([6]a) and references cited therein.
8. C4 and higher complexes: Ru: (a) M.I. Bruce, P. Hinterding, E.R.T. Tiekink, B.W. Skelton, A.H. White, J. Organomet. Chem. 450 (1993) 209.
9. (b) Y. Sun, N.J. Taylor, A.J. Carty, J. Organomet. Chem. 423 (1992) C43.
10. (c) Y. Sun, N.J. Taylor, A.J. Carty, Organometallics 11 (1992) 4293. W:
11. (d) M.I. Bruce, M. Ke, P.J. Low, J. Chem. Soc. Chem. Commun. (1996) 2405.
12. (e) M.I. Bruce, B.W. Skelton, A.H. White, N.N. Zaitseva, J. Chem. Soc. Dalton Trans. (1996) 3151.
13. (f) B.E. Woodworth, P.S. White, J.L. Templeton, J. Am. Chem. Soc. 119 (1997) 828. Fe:
14. (g) P.J.Kim, M. Masai, K. Sonogashira, N. Hagihara, Inorg. Nucl. Chem. Lett. 6 (1970) 181.
15. (h) A. Wong, P.C.W. Kang, C.D. Tagge, D.R. Leon, Organometallics 9 (1990) 1992.
16. (i) R. Crescenzi, C. Lo Sterzo, Organometallics 11 (1992) 4301.
17. (j) N. Le Narvor, C. Lapinte, J. Chem. Soc. Chem. Commun. (1993) 357.
18. (k) N. Le Narvor, L. Toupet, C. Lapinte, J. Am. Chem. Soc. 117 (1995) 7129.
19. (l) F. Coat, C. Lapinte, Organometallics 15 (1996) 477. Re:
20. (m) J.A. Ramsden, A. Arif, J.A. Gladysz, J. Am. Chem. Soc. 114 (1992) 6809.
21. (n) J.A. Ramsden, W. Weng, J.A. Gladysz, Organometallics 11 (1992) 3635.
22. (o) Y. Zhou, J.W. Seyler, W. Weng, A.M. Arif, J.A. Gladysz, J. Am. Chem. Soc. 115 (1993) 8509.
23. (p) J.W. Seyler, W. Weng, Y. Zhou, J.A. Gladysz, Organometallics 12 (1993) 3802.
24. (q) W. Weng, T. Bartik, J.A. Gladysz, Angew. Chem. Int. Ed. Engl. 33 (1994) 2199.
25. (r) M. Brady, W. Weng, J.A. Gladysz, J. Chem. Soc. Chem. Commun. (1994) 2655.
26. (s) W. Weng, T. Bartik, M. Brady, B. Bartik, J.A. Ramsden, A.M. Arif, J.A. Gladysz, J. Am. Chem. Soc. 117 (1995) 11922.
27. (t) T. Bartik, B. Bartik, M. Brady, R. Dembinski, J.A. Gladysz, Angew. Chem. Int. Ed. Engl. 35 (1996) 414.
28. (u) M. Brady, W. Weng, Y. Zhou, et al., J. Am. Chem. Soc. 119 (1997) 775.
29. (v) S.B. Falloon, W. Weng, A.M. Arif, J.A. Gladysz, Organometallics 16 (1997) 2008.
30. (w) V.W.-W. Yam, V.C.-Y. Lau, K.-K. Cheung, Organometallics 15 (1996) 1740. Rh, Ir:
31. (x) T. Rappert, O. Nürnberg, H. Werner, Organometallics 12 (1993) 1359.
32. (y) O. Gevert, J. Wolf, H. Werner, Organometallics 15 (1996) 2806.
33. (z) H.B. Fyfe, M. Mlekuz, D. Zargarian, N.J. Taylor, T.B. Marder, J. Chem. Soc. Chem. Commun. (1991) 188.
34. (aa) B.J. Stang, R. Tykwinski, J. Am. Chem. Soc. 114 (1992) 4411.
35. See ref. ([3]j-v). See also, D. Astruc, Acc. Chem. Res. 30 (1997) 383.
36. Somorjai G.A. Introduction to Surface Chemistry and Catalytsis. 1994;Wiley, New York.
37. (a) M. Akita, Y. Moro-oka, Bull. Chem. Soc. Jpn. 68 (1995) 420.
38. (b) M. Akita, M. Terada, S. Oyama, Y. Moro-oka, Organometallics 9 (1990) 816.
39. (c) M. Akita, M. Terada, S. Oyama, S. Sugimoto, Y. Moro-oka, Organometallics 10 (1991) 1561.
40. (d) M. Akita, M. Terada, M., Y. Moro-oka, Organometallics 10 (1991) 2961. The reaction mechanism has been corrected in ref. ([6]k).
41. (e) M. Akita, M. Terada, Y. Moro-oka, Organometallics 11 (1992) 1825.
42. (f) M. Akita, M. Terada, Y. Moro-oka, Organometallics 11 (1992) 3469.
43. (g) M. Akita, S. Sugimoto, M. Tanaka, Y. Moro-oka, J. Am. Chem. Soc. 114 (1992) 7581.
44. (h) M. Akita, S. Sugimoto, A. Takabuchi, M. Tanaka, Y. Moro-oka, Organometallics 12 (1993) 2925.
45. (i) M. Akita, N. Ishii, A. Takabuchi, M. Tanaka, Y. Moro-oka, Organometallics 13 (1994) 258.
46. (j) M. Akita, M. Terada, N. Ishii, H. Hirakawa, Y. Moro-oka, J. Organomet. Chem. 473 (1994) 175.
47. (k) M. Akita, A. Takabuchi, M. Terada, N. Ishii, M. Tanaka, Y. Moro-oka, Organometallics 13 (1994) 2516.
48. (l) M. Akita, H. Hirakawa, M. Tanaka, Y. Moro-oka, J. Organomet. Chem. 485 (1995) C14.
49. (m) M. Akita, H. Hirakawa, K. Sakaki, Y. Moro-oka, Organometallics, 14 (1995) 2775.
50. (n) M. Terada, Y. Masaki, M. Tanaka, M. Akita, Y. Moro-oka, J. Chem. Soc. Chem. Commun. (1995) 1611.
51. (o) M. Akita, S. Kato, M. Terada, Y. Masaki, M. Tanaka, Y. Moro-oka, Organometallics 16 (1997) 2392. C4 complexes:
52. (p) M. Akita, M.-C. Chung, A. Sakurai, S. Sugimoto, M. Terada, M. Tanaka, Y. Moro-oka, Organometallics 16 (1997) 4882. C1 complex:
53. (q) Y. Takahashi, M. Akita, Y. Moro-oka, J. Chem. Soc. Chem. Commun. (1997) 1557.
54. (a) J.L. Davidson, Comprehensive Organometallic Chemistry, vol. 4, E.W. Abel, F.G.A. Stone, G. Wilkinson (Eds.), Pergamon, Oxford, UK, 1982, ch. 31-5.
55. (b) M. Akita, Comprehensive Organometallic Chemistry II, vol. 7, E.W. Abel, F.G.A. Stone, G. Wilkinson (Eds.), Pergamon, Oxford, UK, 1995, ch. 4.
56. (a) E. Sappa, A. Tiripicchio, P. Braunstein, Chem. Rev. 83 (1983) 203.
57. (b) P.R. Raithby, M.J. Rosales, Adv. inorg. Chem. Radiochem. 29 (1985) 170.
58. (c) R. Nast, Coord. Chem. Rev. 47 (1982) 89.
59. Shriver D.F., Kaesz H.D., Adams R.D. The Chemistry of Metal Cluster Complexes. 1990;VCH, New York.
60. Halet et al. ([2]a) pointed out a possibility of interconversion between the 66e species 5 and the 68e permetallated ethene-type structure by addition and removal of a 2e-donor. But we could not get any evidence for formation of 68e species because of the failure in isolation of characterisable products.
61. Yasufuku K., Aoki K., Yamazaki H. Bull. Chem. Soc. Jpn. 48:1975;1616.
62. Kousantonis G.A, Selegue J.P., Wang J.-G. Organometallics. 11:1992;2704.
63. Weidmann T., Weinrich V., Wagner B., Robl C., Beck W. Chem. Ber. 124:1991;1363.
64. 4-system can be raised as a typical example. (a) R.J. Klinger, W. Butler, M.D. Curtis, J. Am. Chem. Soc. 98 (1975) 4645.
65. (b) M.D. Curtis, Polyhedron 6 (1987) 759.
66. (c) M.J. Winter, Adv. Organomet. Chem. 29 (1989) 101.
67. Farrugia L.S., Rae S.E. Organometallics. 11:1992;196.
68. Geoffroy G.L., Bassner S.L. Adv. Organomet. Chem. 28:1988;1.
69. Parshall G.W., Ittel S.D. Homogeneous Catalysis. 1992;206 Wiley, New York.
70. King R.B. Organometallic Syntheses. 1:1965;93 Academic, New York.
71. International Tables for X-ray Crystallography, vol. 4, Kynoch Press, Birmingham, 1975.