Intramolecular C-H Insertion Reactions of Acetoxy Fischer Carbene Complexes

Synlett

Volumn 1997, Issue 10, 1997, Pages 1181-1183

  Takeda, Kei ^a   Okamoto, Yasushi ^a   Nakajima, Akemi ^a   Yoshii, Eiichi ^a   Koizumi, Toru ^a  

^a UNIVERSITY OF TOYAMA   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0003019231     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1997-992     Document Type: Article

References (14)

1. Taber, D. F. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon: Oxford, 1991; Vol. 3, pp 1045-1062.
2. Dötz, K. H. Angew. Chem. Int. Ed. Engl. 1984, 23, 587-608.
3. (a) Fischer, H.; Schmid, J.; Märkl, R. J. Chem. Soc., Chem. Commun. 1985, 572-573.
4. (b) Fischer, H.; Schmid, J. J. Mol. Catal. 1988, 46, 277-285.
5. Wang, S. L. B.; Su, J.; Wulff, W. D. J Am. Chem. Soc. 1992, 114, 10665-10666.
6. Barluenga, J.; Rodoríguez, F.; Vadecard, J.; Bendix, M.; Fañanás, F. J.; López-Ortiz, F. J. Am. Chem. Soc. 1996, 118, 6090-6091.
7. Takeda, K.; Takeda, M.; Nakajima, A.; Yoshii, E. J. Am. Chem. Soc. 1995, 117, 6400-6401.
8. Mechanistic studies of the [3 + 4] annulation using 4 and the related compounds will be reported elsewhere.
9. Murray, C. K.; Yang, D. C. Wulff, W. D. J. Am. Chem. Soc. 1990, 112, 5660-5662.
10. Takeda, K.; Sakurama, K.; Yoshii, E. Tetrahedron Lett. 1997, 38, 3257-3260.
11. 3, R = 4.4 for 3743 reflections. Diffraction data were collected on a Rigaku AFC7R diffractometer with graphite monochromated Mo-Ka radiation and 12 kW rotating generator. The structure was solved by the direct methods and expanded using Fourier techniques.
12. Wulff, W. D.; Bauta, W. E.; Kaesler, R. W.; Lankford, P. J.; Miller, R. A.; Murray, C. K.; Yang, D. C. J. Am. Chem. Soc. 1990, 112, 3642-3659.
13. Wulff, W. D. In Advances in Metal-Organic Chemistry; Vol. 1; Liebeskind, L. S., Ed.; JAI Press Inc.: Greenwich, CT, 1989.
14. 2O) to give (Z)-4 (21 mg, 12%), 6,7-trans-5 (16 mg, 9%), and 3 (36 mg, 21%).