Synthesis and structure of mono-THF solvates of bis(cyclopentadienyl)samarium(II) complexes: (C5Me5)2 Sm(THF) and [C5H2(SiMe 3)3][C5H3(SiMe3)2]Sm(THF)

Journal of Organometallic Chemistry

Volumn 444, Issue 1-2, 1993, Pages 61-66

  Evans, William J ^a   Kociok Köhn, Gabriele ^a   Foster, Samuel E ^a   Ziller, Joseph W ^a   Doedens, Robert J ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002994006     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(93)83055-Z     Document Type: Article

References (29)

1. Bis(η5-Pentamethylcyclopentadienyl)-Bis(Tetrahydrofuran)Samarium (II)
2. Use of the bis(trimethylsilyl)cyclopentadienyl ligand for stabilising early (f0?f3) lanthanocene chlorides; X-ray structure of [(Pr{?-[C5H3(SiMe3)2]}2Cl)2] and of isoleptic scandium and ytterbium complexes
3. Organometallic complexes of the Group 3A and lanthanoid metals containing M(�-Cl)2Li bridging units; the X-ray structure of [Nd{?-[C5H3(SiMe3)2]}2(�-Cl)2Li(thf)2](thf = tetrahydrofuran)
4. Synthesis and characterisation of stable anionic group 3a dichlorometallocene(III) complexes and the X-ray structure of [AsPh4][Nd{?-C5H3(SiMe3)2}2Cl2]
5. Metallocene(III) tetrahydridoborates of the Group 3A elements and the X-ray structure of [Sc{?-C5H3(SiMe3)2}2(�-H)2BH2]
6. Hydrocarbon-soluble, crystalline, four-co-ordinate chloro(aryl oxide)s, dialkylamido(aryl oxide)s and di[bis(trimethylsilyl)cyclopentadienyl]s of Th IV and U IV ; X-ray crystal structure of diethylamidotris(2,6-di-t-butylphenoxo)uranium(IV)
7. The synthesis and characterisation, including X-ray diffraction study, of [Th{?-C5H3(SiMe3)2}3]; the first thorium(III) crystal structure