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0007063953
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Butterworths: London
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Pentafulvalene was first reported by Doering and DeMore, see: (a) Doering, W. v. E. Theoretical Organic Chemistry (The Kekulé Symposium); Butterworths: London, 1959; pp 35-48. (b) DeMore, W. B.; Pritchard, H. O.; Davidson, M. J. Am. Chem. Soc. 1959, 81, 5874-5879.
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Pentafulvalene was first reported by Doering and DeMore, see: (a) Doering, W. v. E. Theoretical Organic Chemistry (The Kekulé Symposium); Butterworths: London, 1959; pp 35-48. (b) DeMore, W. B.; Pritchard, H. O.; Davidson, M. J. Am. Chem. Soc. 1959, 81, 5874-5879.
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5344232360
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Siemens Analytical Instrument, Inc., Madison, WI, 1990
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Siemens Analytical Instrument, Inc., Madison, WI, 1990.
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27
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5344252623
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note
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The cis assignment is made relative to the least-squares plane of the fused cyclic portion of the molecule.
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-
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28
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0001308394
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Baron, P. A.; Brown, R. D.; Burden, F. R.; Domaillee, P. J.; Kent, J. E. J. Mol. Spectrosc. 1972, 43, 401-410.
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Domaillee, P.J.4
Kent, J.E.5
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29
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33750351462
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Kuchitsu, K.S.4
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30
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0343508391
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-
The central C=C in perchloroheptafulvalene was 1.332 Å. See: Ishimori, M.; West, R.; Teo, B. K; Dahl, L. F. J. Am. Chem. Soc. 1971, 93, 7101-7102.
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32
-
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5344270126
-
-
note
-
Bailey et al. reported a C=C twist with an average value of 40° and length of 1.39 Å for 1,1′-bis(isopropoxycarbonyl)-9,9′-bis-(fluorenylidene) and ascribed a diradical character to the bond (see ref 5d).
-
-
-
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33
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0000827871
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Beachley, O. T., Jr.; Blom, R.; Churchill, M. R.; Faegri, K., Jr.; Fettinger, J. C.; Pazik, J. C.; Victoriano, L. Organometallics 1989, 8, 346-356.
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Pazik, J.C.6
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35
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36
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33748240602
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(a) Sitzmann, H.; Boese, R. Angew. Chem., Int. Ed. Engl. 1991, 30, 971-973.
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Sitzmann, H.1
Boese, R.2
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37
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0001304002
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(b) Sitzmann, H.; Bock, H.; Boese, R.; Dezember, T.; Havlas, Z.; Kaim, W.; Moescherosch, M.; Zanathy, L. J. Am. Chem. Soc. 1993, 115, 12003-12009.
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Dezember, T.4
Havlas, Z.5
Kaim, W.6
Moescherosch, M.7
Zanathy, L.8
-
38
-
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5344267713
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note
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The trimethylsilyl groups were not included in the determination of the best least-squares plane of each of the substituted-fulvalene fragments.
-
-
-
-
39
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12044250714
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Bradshaw, J. D.; Solooki, D.; Tessier, C. A.; Youngs, W. J. J. Am. Chem. Soc. 1994, 116, 3177-3179.
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Youngs, W.J.4
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