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3 chemistry in organic syntheses, see: (a) L. S. Hegedus, Transition Metals in the Synthesis of Complex Organic Molecules, University Science Books, Mill Valley, CA, 1994, chapter 10; (b) M. F. Semmelhack, in Comprehensive Organometallic Chemistry II, Vol. 12 (Eds.: E.W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, 1995, p. 979; (c) M. F. Semmelhack, ibid., S. 1017; (d) S. G. Davies, T. D. McCarthy, ibid. p. 1039; (e) M. Uemura, in Advances in Metal-Organic Chemistry, Vol. 2 (Ed.: L. S. Liebeskind), JAI Press, 1991, p. 195.
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3 chemistry in organic syntheses, see: (a) L. S. Hegedus, Transition Metals in the Synthesis of Complex Organic Molecules, University Science Books, Mill Valley, CA, 1994, chapter 10; (b) M. F. Semmelhack, in Comprehensive Organometallic Chemistry II, Vol. 12 (Eds.: E.W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, 1995, p. 979; (c) M. F. Semmelhack, ibid., S. 1017; (d) S. G. Davies, T. D. McCarthy, ibid. p. 1039; (e) M. Uemura, in Advances in Metal-Organic Chemistry, Vol. 2 (Ed.: L. S. Liebeskind), JAI Press, 1991, p. 195.
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3 chemistry in organic syntheses, see: (a) L. S. Hegedus, Transition Metals in the Synthesis of Complex Organic Molecules, University Science Books, Mill Valley, CA, 1994, chapter 10; (b) M. F. Semmelhack, in Comprehensive Organometallic Chemistry II, Vol. 12 (Eds.: E.W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, 1995, p. 979; (c) M. F. Semmelhack, ibid., S. 1017; (d) S. G. Davies, T. D. McCarthy, ibid. p. 1039; (e) M. Uemura, in Advances in Metal-Organic Chemistry, Vol. 2 (Ed.: L. S. Liebeskind), JAI Press, 1991, p. 195.
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3 chemistry in organic syntheses, see: (a) L. S. Hegedus, Transition Metals in the Synthesis of Complex Organic Molecules, University Science Books, Mill Valley, CA, 1994, chapter 10; (b) M. F. Semmelhack, in Comprehensive Organometallic Chemistry II, Vol. 12 (Eds.: E.W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, 1995, p. 979; (c) M. F. Semmelhack, ibid., S. 1017; (d) S. G. Davies, T. D. McCarthy, ibid. p. 1039; (e) M. Uemura, in Advances in Metal-Organic Chemistry, Vol. 2 (Ed.: L. S. Liebeskind), JAI Press, 1991, p. 195.
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3 chemistry in organic syntheses, see: (a) L. S. Hegedus, Transition Metals in the Synthesis of Complex Organic Molecules, University Science Books, Mill Valley, CA, 1994, chapter 10; (b) M. F. Semmelhack, in Comprehensive Organometallic Chemistry II, Vol. 12 (Eds.: E.W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford, 1995, p. 979; (c) M. F. Semmelhack, ibid., S. 1017; (d) S. G. Davies, T. D. McCarthy, ibid. p. 1039; (e) M. Uemura, in Advances in Metal-Organic Chemistry, Vol. 2 (Ed.: L. S. Liebeskind), JAI Press, 1991, p. 195.
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For our first approach which, however, did so far lead only to pseudopterosin analogs, see: (a) H.-G. Schmalz, A. Schwarz, G. Dürner, Tetrahedron Lett. 1994, 35, 6861; b) H.-G. Schmalz, S. Siegel, A. Schwarz, Tetrahedron Lett. 1996, 37, 2947.
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For our first approach which, however, did so far lead only to pseudopterosin analogs, see: (a) H.-G. Schmalz, A. Schwarz, G. Dürner, Tetrahedron Lett. 1994, 35, 6861; b) H.-G. Schmalz, S. Siegel, A. Schwarz, Tetrahedron Lett. 1996, 37, 2947.
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2342484208
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3, with DEPT):
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30
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2342589177
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Dissertation, TU-Berlin
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5,6-Dimethoxytetralone 3 was prepared from veratrole in 50 % yield. For details, see: A. Majdalani, Dissertation, TU-Berlin, 1997.
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Majdalani, A.1
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3 stabilized benzylic anions, see: (a) S. G. Davies, S. J. Coote, C. L. Goodfellow in Advances in Metal-Organic Chemistry, Vol. 2 (Ed.: L. S. Liebeskind), JAI Press, 1991, p. 1.
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2342569451
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note
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4i for a related transformation we observed no conversion of 10.
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41
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0010617447
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Dissertation, TU-Berlin
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LiSEt was prepared from HSEt and nBuLi in hexane followed by solvent evaporation; for details of this methodology, see: T. Geller, Dissertation, TU-Berlin, 1997. For the use of LiSMe for the cleavage of mono-methoxyarenes, see: T. Ross Kelly, H. M. Dali, W.-G. Tsang, Tetrahedron Lett. 1977, 3859.
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Geller, T.1
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0010617447
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LiSEt was prepared from HSEt and nBuLi in hexane followed by solvent evaporation; for details of this methodology, see: T. Geller, Dissertation, TU-Berlin, 1997. For the use of LiSMe for the cleavage of mono-methoxyarenes, see: T. Ross Kelly, H. M. Dali, W.-G. Tsang, Tetrahedron Lett. 1977, 3859.
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2342523801
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1,2,4b,4d.
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44
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33845282886
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a) E. J. Corey, R. K. Bakshi, S. Shibata, J. Am. Chem. Soc. 1987, 109, 5551;
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