Stereocontrolled synthesis of (E)-olefin dipeptide isosteres using a [3,3] allylic trichloracetimidate rearrangement

Synlett

Volumn , Issue 5, 1997, Pages 615-617

  Imogaï, Hassan ^a   Petit, Yves ^a   Larchevêque, Marc ^a  

^a CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002871696     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1997-3221     Document Type: Article

References (38)

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32. 2 (5 mL) cooled to -60 °C. After stirring for 3 h, the solvent was evaporated and the residue quickly chromatographed on carbonated silicagel. The trichloracetimidate was then diluted in xylene (15 mL), refluxed for 12 h and chromatographed.
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37. 13C NMR δ: 21.8 (q), 22.1 (q), 22.5 (q), 22.6 (q), 24.7 (d), 25.3 (d), 40.6 (t), 43.4 (d), 46.7 (t), 50.2 (d), 92.6 (s), 129.7 (d), 131.6 (d), 160.9 (s), 180.9 (s).
38. 15b