Synthesis and structure of [Cp2PbCpthfNa]·0.5thf; implications to the control of dimensionality in p block metallocene anion systems (Cp = C5H5, Cpthf= {C5H4}CH2C4H7O)

Journal of the Chemical Society, Dalton Transactions

Volumn , Issue 14, 2000, Pages 2247-2248

  Feeder, Neil ^a   Hopkins, Alexander D ^a   Layfield, Richard A ^a   Wright, Dominic S ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002659863     PISSN: 1470479X     EISSN: None     Source Type: Journal    
DOI: 10.1039/b004608f     Document Type: Article

References (20)

1. M. A. Beswick, J. S. Palmer and D. S. Wright, Chem. Soc. Rev., 1998, 27, 225 and references therein.
2. For a more extensive overview of these and related π-complexes, see P. Jutzi, Anorg. Cliem, 1999,33, 342;
3. P. Jutzi and N. Burford, Chem. Rev., 1999,99,969.
4. M. A. Beswick, H. Gornitzka, H. Marcher, M. E. G. Mosquera, 1 S. Palmer, P. R. Raithby, C. A. Russell, D. Stalke, A. Steiner and D. S. Wright, OrganometaUics, 1999,18, 1148.
5. (a) D. R. Armstrong, D. Moncrieff, C. A. Russell, D. Stalke and D. S. Wright, OrganometaUics., 1997, 16, 3340;
6. (b) M. J. Duer, N. G. Page, M. A. Paver, P. R. Raithby, M.-A. Rennie, C. A. Russell, C. Stourton, A. Steiner and D. S. Wright, J. Chem. Soc, Client. Commun., 1995, 1141.
7. (a) S. Harder and H. Prosenc, Angeu: Chem., Int. Ed. Engl, 1994, 33, 1744;
8. (b) S. Harder and M. H. Prosenc, Angew. Chem., Int. Ed. Engl., 1996, 35, 97;
9. see also, S. Harder, Coord. Chem. Rev., 1998, 176, 17.
10. Q. Huang and Y. Qian, Synthesis, 1987,910;
11. H. Qichen, Q. Yahlong and T. Yougi, Transition Met. Chem., 1988,14,315.
12. C-Na bond lengths are normally ca. 2.6-2.9 A. Values of Cpcentroid ⋯ Na distances of 2.40-2.65 A are typical, e.g., G. Rabe, H. W. Roesky, D. Stalke, H. Ponier and G. M. Sheldrick, J. Organomel. Chem., 1991, 403, 11;
13. T. Aoyagi, H. M. M. Shearer, K. Wade and M. Whitehead, J. Organomet. Chem., 1979, 175, 21.
14. M. A. Beswick, M. A. Paver, P. R. Raithby, C. A. Russell, A. Steiner and D. S. Wright, Chem. Commun., 1997, 109.
15. S. Harvey, C. L. Raston, B. W. Skelton, A. H. White, M. F. Läppert and G. Srivastava, J. Organomet. Chem., 1987,328, Cl.
16. G. K. Anderson and N. P. Rath, J. Organomet. Chem., 1991, 414, 129.
17. G. Lin and W. T. Wong, Polyhedron, 1994,13,3027.
18. centroid ⋯ Na 2.58.
19. +, with a range of coordination numbers (Cambridge Crystallography Data Base).
20. SHELXTL PC version 5.03, Siemens Analytical Instruments, Madison, WI, 1994.