Solid acid catalysts

Current Opinion in Solid State and Materials Science

Volumn 2, Issue 1, 1997, Pages 63-75

  Corma, Avelino ^a  

^a UNIVERSITAT POLITÈCNICA DE VALÈNCIA   (Spain)

Author keywords

EGS energy gradient selectivity; HPA heteropolyacids; HPW 12 tungstophosphoric acid; HSAB hard soft acid base; MELS molecularly engineered layered structures; MTBE methyl tert butyl ether; NNN next nearest neighbours

Indexed keywords

EID: 0002625882     PISSN: 13590286     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1359-0286(97)80107-6     Document Type: Article

References (75)

1. Gadja GJ, Rabo JA. The acid function in zeolites. Fraissard J, Petrakis L. Acidity and Basicity of Solids, Theory, Assessment and Utility. 444:1994;127-179. NATO ASI Series.
2. Van Santen RA, Kramer GJ. Reactivity theory of zeolitic Brönsted acidic sites. Chem Rev. 95:1995;637-660. The background on Brönsted acid hydroxyls is discussed on the bases of quantum-chemical cluster calculations, and vibrational spectroscopy. Transition states of carbocations on zeolites and their reactivity is rationalized. of special interest.
3. Teunissen EH, Roetti C, Pisani C, Deman AJM, Jansen APJ, Orlando R, Van Santen RA, Dovesi R. Proton-transfer in zeolites - a comparison between cluster and cristal calculations. Modelling Simul Mater Sci Eng. 2:1994;921-932.
4. + in zeolites corrected for the long-range electrostatic potential of the crystal. J Chem Phys. 101:1994;5865-5874.
5. Shah R, Gale JD, Payne MC. Methanol adsorption in zeolites - a first principles study. J Phys Chem. 100:1996;11688-11697.
6. Pisani C, Bierkenheuer U. Embedded-cluster approach to the study of catalytic reactions in zeolite cavities. Int J Quantum Chem. 29:1995;221-234.
7. Nicholas JB, Hess AC. Ab Initio periodic Hartree - Fock investigation of a zeolite acid site. J Am Chem Soc. 116:1994;5428-5436.
8. Schroder KP, Sauer J. Potential functions for silica and zeolite catalysts based on ab initio calculations 3. A shell-model ion-pair potential for silica and aluminosilicates. J Phys Chem. 100:1996;11043-11049.
9. Haase F, Sauer J. Interaction of methanol with Brönsted acid sites and zeolite catalysts an ab initio study. J Am Chem Soc. 117:1995;3780-3789.
10. Zicovich Wilson CM, Viruela P, Corma A. Formation of surface methoxy groups on H-zeolites from methanol. A quantum chemical study. J Phys Chem. 99:1995;13224-13231.
11. Barthomeuf D. Compared formation of light products in n-alkane cracking in SAPO-37 and Si-Al faujasites energy gradient selectivity. Appl Catal. 126:1995;187-194.
12. Barthomeuf D. Zeolites as adsorbents and catalysts. The interactive system encaged molecule/zeolite framework. Chon H, Ihm SK, Uuh YS. 11th International Zeolite Conference: 1996 August 12-17; Seoul Korea. 1996;PL2-1 Elsevier, Amsterdam.
13. Sastre G, Viruela PM, Corma A. Quantum-chemistry calculations on the effect of the electronic confinement upon the frontier molecular orbitals of ethylene and benzene in sodalite Implications on reactivity. Chem Phys Lett. 1997;. A new concept (electronic confinement) which involves the activation of molecules in confined spaces, when the size of the pore matches the size of the molecule introduced. It is shown that the effect is specially notorious in systems with π electrons. of special interest.
14. Corma A. Covalent interactions in zeolites: the influence of zeolite composition and structure on acid softness and hardness. Stud Surf Sci Catal. 94:1995;736-747.
15. Zicovich Wilson CM, Corma A, Viruela P. Electronic confinement of molecules in microscopic pores. A new concept which contributes to explain the catalytic activity of zeolites. J Phys Chem. 98:1994;10863-10870.
16. Corma A, Llopis F, Viruela P, Zicovich Wilson CM. Acid softness and hardness in large pore zeolites as a determinant parameter to control selectivity in orbital controlled reactions. J Am Chem Soc. 116:1994;134-142.
17. Genciu A, Farcasiu D. The mechanism of conversion of hydrocarbons on sulfated metal oxides. Part II. Reaction of benzene on sulfated Zirconia [1]. J Mol Catal A - Chem. 109:1996;273-283. It is demonstrated that sulfated zirconia does not act as a superacid, protonating paraffins, but activates the alkanes and other hydrocarbons via a radical cation type, of outstanding interest.
18. Farneth WE, Gorte RJ. Methods for characterizing zeolite acidity. Chem Rev. 95:1995;615-635. The different characterization techniques for acid sites using basic probe molecules are critically reviewed. of special interest.
19. Haw JF, Nicholas JB, Xu T, Beck LW, Ferguson DB. Physical organic chemistry of solid acids. Lessons from in situ NMR and theoretical chemistry. Acc Chem Res. 29:1996;259-267.
20. Corma A. Inorganic solid acids and their use in acid-catalyzed hydrocarbon reactions. Chem Rev. 95:1995;559-614. The nature and reactivity of acid sites on different solid acid catalysts is extensively reviewed. of special interest.
21. Zones SI, Davis ME. Zeolite materials: recent discoveries and future prospects. Curr Opin Solid State Mater Sci. 1:1996;107-117.
22. Freyhardt CC, Tsapatsis M, Lobo RF, Balkus KJ, Davis ME. A high-silica zeolite with a 14-tetrahedral atom pore opening. Nature. 381:1996;295-298.
23. Beck JS, Vartuli JC. Recent advances in the synthesis, characterization and applications of mesoporous molecular sieves. Curr Opin Solid State Mater Sci. 1:1996;76-87. The advances on synthesis, characterization, predicting adsorption properties, and possible applications of long-range ordered mesoporous materials are presented. of outstanding interest.
24. Garces JM. On void fraction and the nature of porous solids. Adv Mater. 8:1996;434-437.
25. Corma A, Grande MS, Gonzalez Alvaro V, Orchillés AV. Cracking activity and hydrothermal of MCM-41 and its comparison with amorphous silica-alumina and a USY zeolite. J Catal. 159:1996;375-382.
26. Corma A, Martínez A, Martínez Soria V, Montón JB. Hydrocracking of vacuum gasoil on the novel mesoporous MCM-41 aluminosilicate catalyst. J Catal. 53:1995;25-31.
27. Corma A, Fornés V, Navarro MT, Pérez Pariente J. Acidity and stability of MCM-41 crystalline aluminosilicates. J Catal. 148:1994;569-574.
28. Chen CY, Xiao SQ, Dahmen U. Determination of the pore size and wall thickness of MCM-41 using the Fresnel method. Chon H, Ihm SK, Uuh YS. 11th International Zeolite Conference: 1996 Aug 12-17; Seoul, Korea. 1996;RP63 Elsevier, Amsterdam.
29. Climent MJ, Corma A, Iborra S, Navarro MC, Primo J. Use of mesoporous MCM-4 aluminosilicates as catalysts in the production of the fine chemicals: preparation of dimethylacetals. J Catal. 161:1996;783-789.
30. Kozhevnikov IV, Sinnema A, van Bekkum H. Proton sites in Keggin heteropolyacis from 0-17 NMR. Catal Lett. 34:1995;213-221.
31. Okuhara T, Mizuno N, Mison M. Catalytic chemistry of heteropoly compounds. Adv Catal. 41:1996;113-252. An extensive and complete review on heteropolyacids from synthesis, characterization, adsorption and reactivity is presented in this article. of outstanding interest.
32. Izumi Y, Ogawa M, Urabe K. Alakali-metals salts and ammonium-salts of Keggin-type heteropolyacids as solid acid catalysts for liquid phase Friedel-Crafts reactions. Appl Catal A - Gen. 132:1995;127-140.
33. + salts of 12-tungstophosphoric acid as solid catalysts for isobutane/2-butene alkylation. J Catal. 1997;. in press.
34. 40 heteropolyacid compounds. Catal Lett. 34:1995;223.
35. Kozhevnikov IV. Heteropolyacids and related compounds as catalysts for fine chemical synthesis. Catal Rev-Sci Eng. 37:1995;311-352.
36. Yadav GD, Kirthivasan N. Single-pot synthesis is methyl tert-butyl ether from tert-butyl alcohol and methanol: dodecatungstophosphoric acid support on clay as an efficient catalysts. J Chem Soc Chem Commun. 1995;203-204.
37. Dupont P, Vedrine JC, Paumard E, Hecquet G, Lefebvre F. Heteropolyacids supported on activated carbon as catalysts for the esterification of acrylic acid by butanol. Appl Catal A Gen. 129:1995;217-227.
38. Hasik M, Kulszewiczbajer I, Pozniczek J, Piwowarska Z, Pron A, Bielanski A, Dziembaj R. Preparation of conjugated polymer supported heteropoly anions. New efficient catalysts for ethyl-alcohol conversion. Stud Surf Sci Catal. 9:1995;571-578.
39. Song X, Sayari A. Sulfated zirconia-based strong solid-acid catalysts: recent progress. Catal Rev-Sci Eng. 38:1996;329-412.
40. Srinivasan R, Keogh RA, Davis BH. Sulfated zirconia catalysts are Brönsted acid sites the source of the activity. Catal Lett. 36:1996;51-57.
41. White RL, Sikabwe EC, Coelho MA, Resasco De. Potential role of pentacoordinated sulfur in the acid site structure of sulfated zirconia. J Catal. 157:1995;755-758.
42. Ward DA, Ko El. Sol-gel synthesis of zirconia supports Important properties for generating n-butane isomerization activity upon sulfate promotion. J Catal. 157:1995;321-333.
43. Pinna F, Signoretto M, Strukul G, Cerrato G, Morterra C. Isomerization of n-butane on sulfated zirconia. Evidence for the dominant role of Lewis acidity on the catalytic activity. Catal Lett. 26:1994;339-344.
44. Lunsford JH, Sang H, Campbell SM, Liang CH, Anthony RG. An NMR study of acid sites on sulfated zirconia catalysts using trimethylphosphine as a probe. Catal Lett. 27:1994;305-314.
45. Babou F, Bigot B, Coudurier G, Sautet P, Vedrine JC. Sulfated zirconia for n-butane isomerization. Experimental and theoretical approaches. Stud Surf Sci Catal. 90:1994;519-529.
46. 4(2-) anions. J Catal. 150:1994;143-149.
47. 2 is due to the stabilization of the transition state complex at the surface, of special interest.
48. Srinivasan R, Keogh RA, Ghenciu A, Farcasiu D, Davis BH. Reaction of benzene and pyridine on metal promoted sulfated zirconia catalysts. J Catal. 158:1996;502-510.
49. 2 promoted with sulfate, iron and manganese. A solid superacid catalyst capable of low temperature n-butane isomerization. Catal Lett. 25:1994;21-28.
50. Yaluris G, Larson RB, Kobe JM, Gonzalez MR, Fogash KB, Dumesic JA. Selective poisoning and deactivation of acid sites on sulfated zirconia catalysts for n-butane isomerization. J Catal. 158:1996;336-342.
51. 2 catalyst. Appl Catal A - Gen. 118:1994;L11-L15.
52. Fogash KB, Yaluris G, Gonzalez MR, Ouraipryvan P, Ward DA, Ko El, Dumesic JA. Characterization and selective poisoning of acid sites on sulfated zirconia. Catal Lett. 32:1995;241-251.
53. Corma A, Martínez A, Martínez C. Influence of process variables on the continuous alkylation of isobutane with 2-butene on superacid sulfated zirconia catalysts. J Catal. 149:1994;52-60.
54. Coelho MA, Resasco DE, Sikabwe EC, White RL. Modification of the catalytic properties of sulfated zirconia by addition of metal promoters. Catal Lett. 32:1995;253-262.
55. 2 superaci d catalysts. Appl Catal A - Gen. 116:1994;151-163.
56. 2 and zeolite Beta as catalysts for the isomerization of n-butane and the alkylation of isobutane with 2-butene. Appl Catal A - Gen. 111:1994;175-189.
57. Tichit D, Coq B, Armendariz H, Figueras F. One-step sol-gel synthesis of sulfated zirconia catalysts. Catal Lett. 38:1996;109-113.
58. Signoretto M, Pinna F, Strukul G, Cerrato G, Morterra C. Platinum promoted zirconia sulfate catalysts one pot. Preparation physical properties and catalytic activity. Catal Lett. 36:1996;129-133.
59. Brewer TD, Matson DW. Solid acid process. Catalysis Consultants. 1995.
60. -2 during n-butane isomerization. Appl Catal A - Gen. 23:1995;L197-L203.
61. Van Mao RLe, Xiao S, Le TS. Thermal stability of the Pt bearing sulfate-promoted zirconia in the presence of hydrogen. Catal Lett. 35:1995;107-118.
62. 2 catalysts during isobutane/2-butene alkylation. Appl Catal A - Gen. 144:1996;249-268.
63. Li C, Stair PC. Ultraviolet raman-spectroscopy characterization of sulfated zirconia catalysts. Fresh, deactivated and regenerated. Catal Lett. 36:1996;119-123.
64. Iglesia E, Barton DG, Soled SL, Miseo S, Baumgartner JE, Gates WE, Fuentes GA, Meitzner GD. Selective isomerization of alkanes on supported tungsten oxide acids. Hightower JW, Delgass WN. Proceedings of the 11th International Congress on Catalysis: 1996 Jun 30-Jul 5; Baltimore, USA. 1996;B2 The North American Catalysis Society.
65. Larsen G, Raghavan S, Marquez M, Lotero E. Tungsta supported on zirconia and alumina catalysts temperature programmed desorption/reaction of methanol and pyridine drifts studies. Catal Lett. 37:1996;57-62.
66. Alberti G, Gasciola M, Constantino U, Vivani R. Layered and pillared metal (IV) phosphates and phosphonates. Adv Mater. 8:1996;291-303.
67. Alberti G, Boccali L, Casciola M, Massinelli L, Montoneri E. Protonic conductivity of layered zirconium phosphonates containing So3H Groups 3. Preparation and characterization of gamma-zirconium sulfoaryl phosphonates. Solid State Ionics. 84:1996;97-104.
68. Curini M, Rosati O, Pisani E, Constantino U. Heterogeneous catalysis in carbonyl regeneration from oximes semicarbazones and tosylhydrazones by zirconium sulfophenyl phosphonate. Synlett. 4:1996;333-334.
69. Harmer MA, Farneth WE, Sun Q. High surface area nafion resin/silica nanocomposite: a new class of solid acid catalyst. J Am Chem Soc. 118:1996;7708-7715. A novel nanocomposite of nafion resin in porous silica is described, showing the benefits in reactant accessibility, and therefore, in catalytic activity. of outstanding interest.
70. Soled SL, McVicker GB, Miseo S, Gates WE. US Patent 5 420 092; 1995.
71. Soled SL, McVicker GB, Miseo S, Gates WE. US Patent 5 391 532; 1995.
72. Angstadt HP, Hollstein EJ, Hsu CY: US Patent 5 491 278; 1996.
73. Del Rossi KJ, Jablonski GA, Kuehl GA, Marler DO, Rav GS, Rose BH: US Patent 5 475 178; 1996.
74. Kresge CT, Marler DO, Rav GS, Rose BH: US Patent 5 324 881; 1994.
75. Kresge CT, Marler DO, Rav GS, Rose BH: US Patent 5 336 945; 1994.