A metal-assisted conversion of CO2 and imidazole to carboxylate: Synthesis and structural characterisation of the zinc carboxylate {bis(1-methyl-2-imidazolecarboxylato)(1-methylimidazole)}zinc(II), [Zn(1-Me-2-Imc)2(1-MeIm)]

Inorganic Chemistry Communications

Volumn 1, Issue 1, 1998, Pages 30-33

  Zevaco, Thomas A ^a   Trotzki, Ronald ^a   Görls, Helmar ^b   Dinjus, Eckhard ^c  

^a Projektgruppe 'CO2 C   (Germany)

^b 07743   (Germany)

^c KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

Carbon dioxide; Carboxylate complexes; Crystal structures; Imidazole complexes; Zinc complexes

Indexed keywords

EID: 0002607982     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1387-7003(98)00003-3     Document Type: Article

References (31)

1. (a) S. Dev, E. Ramli, T.B. Rauchfuss, C.L. Stern, J. Am. Chem. Soc. 112 (1990) 6385;
2. (b) A.K. Verma, T.B. Rauchfuss, S.R. Wilson, Inorg. Chem. 34 (1995) 3072.
3. A. Belforte, F. Calderazzo, U. Englert, J. Strähle, Inorg. Chem. 30 (1991) 3778.
4. (a) W.S. Wade, M. Mrksich, P.B. Dervan, J. Am. Chem. Soc. 114 (1992) 8783;
5. (b) E.M. Sabo, R.E. Sheperd, M.S. Rau, M.G. Elliott, Inorg. Chem. 26 (1987) 2897;
6. (c) R. Carballo, A. Castiñeiras, W. Hiller, J. Strähle, J. Coord. Chem. 40 (1996) 253;
7. (d) G.A. Ardizzoia, G. La Monica, M.A. Angaroni, F. Cariati, Inorg. Chim. Acta, 158 (1989) 159.
8. A. Fürstner, Active Metals, VCH, Weinheim, 1996.
9. M.R. Grimmett, in: P.G. Sammes (Ed.), Comprehensive Organic Chemistry, vol. 4, Pergamon, Oxford, 1979, p. 357.
10. K. Nakamoto, in Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed., Wiley Interscience, New York, 1986, p. 231.
11. (a) M.C. Favas, D.L. Kepert, in Progress in Inorganic Chemistry, vol. 27, Wiley, New York, 1984, p. 325;
12. (b) R.R. Holmes, Progress in Inorganic Chemistry, vol. 36, Wiley, New York, 1984, p. 224.
13. (a) T.P.E. Auf Der Heyde, L.R. Nassimbeni, Acta Crystallogr. Sect. B 40 (1984) 582;
14. (b) H. Sigel, R.B. Martin, Chem. Soc. Rev., (1994) 83.
15. R.J. Gillespie, J. Chem. Soc. (1963) 4679.
16. 2]: A. Takenaka, H. Utsumi, N. Ishihara, A. Furusaki, I. Nitta, J. Chem. Soc. Jpn., Pure Chem. 91 (1970) 921;
17. 2]: R. Faure, H. Loiseleur, Acta Crystallogr., Sect. B 28 (1972) 811;
18. 2]: H. Ptasiewicz-Bak, J. Leciejewicz, J. Zachara, J. Coord. Chem. 36 (1995) 317;
19. 2]: T.A. Zevaco, H. Görls, E. Dinjus, Inorg. Chim. Acta, in press.
20. M.A.S. Goher, M.A.M. Abuu-Youssef, F.A. Mautner, Polyhedron 15 (1996) 453.
21. A.W. Addison, T.N. Rao, J. Reedijk, J. Rijn, G.C. Verschoor, J. Chem. Soc., Dalton Trans. (1984) 1349.
22. C.-H. Ng, H.-K. Fun, S.-B. Teo, S.-G. Teoh, K. Chinnakali, Acta Crystallogr. Sect. C 51 (1995) 244.
23. D. Van der Helm, A.F. Nicholas, C.G. Fischer, Acta Crystallogr., Sect. B 28 (1970) 1172.
24. D.P. Craig, A. Macoll, R.S. Nyolm, L.E. Orgel, L.E. Sutton, J. Chem. Soc. (1954) 332.
25. J. Skorsepa, K. Györyovà, M. Melnik, K. Smolander, M. Ahlgrèn, Acta Crystallogr. Sect. C 51 (1995) 1069.
26. X.-M. Chen, Z.-T. Xu, X.-L. Yu, T.C.W. Mak, Polyhedron 13 (1994) 2079.
27. E.E. Castellano, G. Oliva, J. Zukerman-Schpector, Acta Crystallogr. Sect. C 42 (1986) 21.
28. M. Ahlgrén, U. Turpeinen, R. Hämäläinen, Acta Chem. Scand. Ser. A 36 (1982) 841.
29. MOLEN, an interactive structure solution procedure, Enraf-Nonius, Delft, Netherlands, 1990.
30. G.M. Sheldrick, Acta Crystallogr. Sect. A 46 (1990) 467.
31. G.M. Sheldrick, SHELXL-93, program for the refinement of crystal structures, University of Göttingen, Germany, 1993.