Relative binding energies of tertiary phosphine ligands to the Cp*RuOCH2CF3 (Cp* = η5-C5Me5) moiety

Organometallics

Volumn 15, Issue 15, 1996, Pages 3456-3462

  Li, Chunbang ^a   Luo, Lubin ^a   Nolan, Steven P ^a   Marshall, William ^b   Fagan, Paul J ^b  

^a UNIVERSITY OF NEW ORLEANS   (United States)

^b DUPONT COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002605018     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9601514     Document Type: Article

References (57)

1. Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry, 2nd ed.; University Science: Mill Valley, CA, 1987.
2. Kubas, G. J. Acc. Chem. Res. 1988, 21, 120-128 and references therein.
3. Gonzalez, A. A.; Mukerjee, S. L.; Chou, S.-J.; Zhang, K.; Hoff, C. D. J. Am. Chem. Soc. 1988, 110, 4419-4421.
4. Campion, B. K.; Heyn, R. H.; Tilley, T. D. J. Chem. Soc., Chem. Commun. 1988, 278-280.
5. Campion, B. K.; Heyn, R. H.; Tilley, T. D.; Rheingold, A. L. J. Am. Chem. Soc. 1993, 115, 5527-5537.
6. (a) Fagan, P. J.; Ward, M. D.; Caspar, J. V.; Calabrese, J. C.; Krusic, P. J. J. Am. Chem. Soc. 1988, 110, 2981-2983.
7. (b) Fagan, P. J.; Ward, M. D.; Calabrese, J. C. J. Am. Chem. Soc. 1989, 111, 1698-1719 and references therein.
8. (c) Fagan, P. J.; Mahoney, W. S.; Calabrese, J. C.; Williams, I. D. Organometallics 1990, 9, 1843-1852.
9. For solution calorimetry on organoruthenium systems see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993, 12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297.
10. For solution calorimetry on organoruthenium systems see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993, 12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297.
11. For solution calorimetry on organoruthenium systems see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993, 12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297.
12. For solution calorimetry on organoruthenium systems see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993, 12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297.
13. For solution calorimetry on organoruthenium systems see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993, 12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297.
14. For solution calorimetry on organoruthenium systems see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993, 12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297.
15. For solution calorimetry on organoruthenium systems see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993, 12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297.
16. For solution calorimetry on organoruthenium systems see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993, 12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297.
17. For solution calorimetry on organoruthenium systems see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993, 12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297.
18. See for example: (a) Kölle, U.; Kossakowski, J. Inorg. Synth. 1990, 29, 225-228. (b) Kölle, U.; Kossakowski, J.; Raabe, G. Angew. Chem., Int. Ed. Engl. 1990, 29, 773-774. (c) Smith, M. E.; Hollander, F. J.; Andersen, R. A. Angew. Chem., Int. Ed. Engl. 1993, 32, 1294. (d) Christ, M. L.; Sabo-Etienne, S.; Chaudret, B. Organometallics 1994, 13, 3800-3804.
19. See for example: (a) Kölle, U.; Kossakowski, J. Inorg. Synth. 1990, 29, 225-228. (b) Kölle, U.; Kossakowski, J.; Raabe, G. Angew. Chem., Int. Ed. Engl. 1990, 29, 773-774. (c) Smith, M. E.; Hollander, F. J.; Andersen, R. A. Angew. Chem., Int. Ed. Engl. 1993, 32, 1294. (d) Christ, M. L.; Sabo-Etienne, S.; Chaudret, B. Organometallics 1994, 13, 3800-3804.
20. See for example: (a) Kölle, U.; Kossakowski, J. Inorg. Synth. 1990, 29, 225-228. (b) Kölle, U.; Kossakowski, J.; Raabe, G. Angew. Chem., Int. Ed. Engl. 1990, 29, 773-774. (c) Smith, M. E.; Hollander, F. J.; Andersen, R. A. Angew. Chem., Int. Ed. Engl. 1993, 32, 1294. (d) Christ, M. L.; Sabo-Etienne, S.; Chaudret, B. Organometallics 1994, 13, 3800-3804.
21. See for example: (a) Kölle, U.; Kossakowski, J. Inorg. Synth. 1990, 29, 225-228. (b) Kölle, U.; Kossakowski, J.; Raabe, G. Angew. Chem., Int. Ed. Engl. 1990, 29, 773-774. (c) Smith, M. E.; Hollander, F. J.; Andersen, R. A. Angew. Chem., Int. Ed. Engl. 1993, 32, 1294. (d) Christ, M. L.; Sabo-Etienne, S.; Chaudret, B. Organometallics 1994, 13, 3800-3804.
22. (a) Johnson, T. J.; Folting, K.; Strieb, W. E.; Martin, J. D.; Huffman, J. C.; Jackson, S. A.; Eisenstein, O.; Caulton, K. G. Inorg. Chem. 1995, 34, 488-499.
23. (b) Johnson, T. J.; Huffman, J. C.; Caulton, K. G. J. Am. Chem. Soc. 1992, 114, 2725-2726.
24. For leading references in this area see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; Wiley: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds; ACS Symposium Series 428; American Chemical Society: Washington, DC, 1990. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics. In Organotransition Metal Compounds; Polyhedron Symposium-in-Print, 7; Elsevier: Amsterdam, 1988. (f) Skinner, H. A.; Connor J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79-88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41-59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204-238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417-426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1982; pp 43-90. (l) Connor, J. A. Top. Curr, Chem. 1977, 71, 71-110.
25. For leading references in this area see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; Wiley: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds; ACS Symposium Series 428; American Chemical Society: Washington, DC, 1990. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics. In Organotransition Metal Compounds; Polyhedron Symposium-in-Print, 7; Elsevier: Amsterdam, 1988. (f) Skinner, H. A.; Connor J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79-88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41-59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204-238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417-426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1982; pp 43-90. (l) Connor, J. A. Top. Curr, Chem. 1977, 71, 71-110.
26. For leading references in this area see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; Wiley: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds; ACS Symposium Series 428; American Chemical Society: Washington, DC, 1990. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics. In Organotransition Metal Compounds; Polyhedron Symposium-in-Print, 7; Elsevier: Amsterdam, 1988. (f) Skinner, H. A.; Connor J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79-88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41-59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204-238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417-426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1982; pp 43-90. (l) Connor, J. A. Top. Curr, Chem. 1977, 71, 71-110.
27. For leading references in this area see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; Wiley: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds; ACS Symposium Series 428; American Chemical Society: Washington, DC, 1990. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics. In Organotransition Metal Compounds; Polyhedron Symposium-in-Print, 7; Elsevier: Amsterdam, 1988. (f) Skinner, H. A.; Connor J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79-88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41-59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204-238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417-426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1982; pp 43-90. (l) Connor, J. A. Top. Curr, Chem. 1977, 71, 71-110.
28. For leading references in this area see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; Wiley: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds; ACS Symposium Series 428; American Chemical Society: Washington, DC, 1990. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics. In Organotransition Metal Compounds; Polyhedron Symposium-in-Print, 7; Elsevier: Amsterdam, 1988. (f) Skinner, H. A.; Connor J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79-88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41-59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204-238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417-426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1982; pp 43-90. (l) Connor, J. A. Top. Curr, Chem. 1977, 71, 71-110.
29. For leading references in this area see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; Wiley: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds; ACS Symposium Series 428; American Chemical Society: Washington, DC, 1990. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics. In Organotransition Metal Compounds; Polyhedron Symposium-in-Print, 7; Elsevier: Amsterdam, 1988. (f) Skinner, H. A.; Connor J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79-88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41-59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204-238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417-426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1982; pp 43-90. (l) Connor, J. A. Top. Curr, Chem. 1977, 71, 71-110.
30. For leading references in this area see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; Wiley: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds; ACS Symposium Series 428; American Chemical Society: Washington, DC, 1990. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics. In Organotransition Metal Compounds; Polyhedron Symposium-in-Print, 7; Elsevier: Amsterdam, 1988. (f) Skinner, H. A.; Connor J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79-88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41-59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204-238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417-426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1982; pp 43-90. (l) Connor, J. A. Top. Curr, Chem. 1977, 71, 71-110.
31. For leading references in this area see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; Wiley: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds; ACS Symposium Series 428; American Chemical Society: Washington, DC, 1990. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics. In Organotransition Metal Compounds; Polyhedron Symposium-in-Print, 7; Elsevier: Amsterdam, 1988. (f) Skinner, H. A.; Connor J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79-88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41-59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204-238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417-426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1982; pp 43-90. (l) Connor, J. A. Top. Curr, Chem. 1977, 71, 71-110.
32. For leading references in this area see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; Wiley: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds; ACS Symposium Series 428; American Chemical Society: Washington, DC, 1990. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics. In Organotransition Metal Compounds; Polyhedron Symposium-in-Print, 7; Elsevier: Amsterdam, 1988. (f) Skinner, H. A.; Connor J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79-88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41-59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204-238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417-426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1982; pp 43-90. (l) Connor, J. A. Top. Curr, Chem. 1977, 71, 71-110.
33. For leading references in this area see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; Wiley: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds; ACS Symposium Series 428; American Chemical Society: Washington, DC, 1990. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics. In Organotransition Metal Compounds; Polyhedron Symposium-in-Print, 7; Elsevier: Amsterdam, 1988. (f) Skinner, H. A.; Connor J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79-88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41-59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204-238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417-426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1982; pp 43-90. (l) Connor, J. A. Top. Curr, Chem. 1977, 71, 71-110.
34. For leading references in this area see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; Wiley: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds; ACS Symposium Series 428; American Chemical Society: Washington, DC, 1990. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics. In Organotransition Metal Compounds; Polyhedron Symposium-in-Print, 7; Elsevier: Amsterdam, 1988. (f) Skinner, H. A.; Connor J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79-88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41-59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204-238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417-426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1982; pp 43-90. (l) Connor, J. A. Top. Curr, Chem. 1977, 71, 71-110.
35. For leading references in this area see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; Wiley: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds; ACS Symposium Series 428; American Chemical Society: Washington, DC, 1990. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics. In Organotransition Metal Compounds; Polyhedron Symposium-in-Print, 7; Elsevier: Amsterdam, 1988. (f) Skinner, H. A.; Connor J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79-88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41-59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204-238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417-426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1982; pp 43-90. (l) Connor, J. A. Top. Curr, Chem. 1977, 71, 71-110.
36. See for example: (a) Nolan, S. P.; Hoff, C. D.; Stoutland, P. O.; Newman, L. J.; Buchanan, J. M.; Bergman, R. G.; Yang, G. K.; Peters, K. G. J. Am. Chem. Soc. 1987, 109, 3143-3145 and references therein. (b) Nolan, S. P.; Lopez de la Vega, R.; Hoff, C. D. Organometallics 1986, 5, 2529-2537.
37. See for example: (a) Nolan, S. P.; Hoff, C. D.; Stoutland, P. O.; Newman, L. J.; Buchanan, J. M.; Bergman, R. G.; Yang, G. K.; Peters, K. G. J. Am. Chem. Soc. 1987, 109, 3143-3145 and references therein. (b) Nolan, S. P.; Lopez de la Vega, R.; Hoff, C. D. Organometallics 1986, 5, 2529-2537.
38. (a) Nolan, S. P.; Porchia, M.; Marks, T. J. Organometallics 1991, 10, 1450-1457.
39. (b) Nolan, S. P.; Stern, D.; Marks, T. J. J. Am. Chem. Soc. 1989, 111, 7844-7854.
40. (a) Nolan, S. P.; Stern, D.; Hedden, D.; Marks, T. J. In ref 10d, pp 159-174. (b) Nolan, S. P.; Lopez de la Vega, R.; Mukerjee, S. L.; Gonzalez, A. A.; Hoff, C. D. In ref 10e, pp 1491-1498.
41. (c) Marks, T. J.; Gagné, M. R.; Nolan, S. P.; Schock, L. E.; Seyam, A. M.; Stern, D. L. Pure Appl. Chem. 1989, 61, 1665-1672.
42. (d) Schock, L. E.; Marks, T. J. J. Am. Chem. Soc. 1988, 110, 7701-7715.
43. Perrin, D. D.; Armarego, W. L. F. Purification of Laboratory Chemicals, 3rd ed.; Pergamon Press: New York, NY, 1988.
44. Ojelund, G.; Wadsö, I. Acta Chem. Scand. 1968, 22, 1691-1699.
45. Kilday, M. V. J. Res. Natl. Bur. Stand. (U.S.) 1980, 85, 467-481.
46. Nolan, S. P.; Hoff, C. D. J. Organomet. Chem. 1985, 282, 357-362.
47. Halcrow, M. A.; Urbanos, F.; Chaudret, B. Organometallics 1993, 12, 955-957.
48. 2, reported by Kölle; see: (a) Kölle, U.; Kossakowski, J. J. Chem. Soc., Chem. Commun. 1988, 549-551. (b) Kölle, U.; Kossakowski, J.; Boese, R. J. Organomet. Chem. 1989, 378, 449-455.
49. 2, reported by Kölle; see: (a) Kölle, U.; Kossakowski, J. J. Chem. Soc., Chem. Commun. 1988, 549-551. (b) Kölle, U.; Kossakowski, J.; Boese, R. J. Organomet. Chem. 1989, 378, 449-455.
50. (a) Meyer, J. M.; Curtis, C. J.; Bercaw, J. E. J. Am. Chem. Soc. 1983, 105, 2651-2660.
51. (b) Bazan, G. C.; Rodriguez, G.; Cleary, B. P. J. Am. Chem. Soc. 1994, 116, 2177-2178.
52. (c) Rodriguez, G.; Bazan, G. C. J. Am. Chem. Soc. 1995, 117, 10155-10156.
53. Fan, L.; Wei, C.; Aigbirhio, F. I.; Turner, M. L.; Gusev, O. V.; Morozova, L. N.; Knowles, D. R. T.; Maitlis, P. T. Organometallics 1996, 15, 98-104.
54. For other examples of transition-metal-tetramethylfulvene complexes see: (a) Kölle, U.; Kang, B.-S. J. Organomet. Chem. 1990, 386, 267-273. (b) Schock, L. E.; Marks, T. J. Organometallics 1987, 6, 232-241.
55. For other examples of transition-metal-tetramethylfulvene complexes see: (a) Kölle, U.; Kang, B.-S. J. Organomet. Chem. 1990, 386, 267-273. (b) Schock, L. E.; Marks, T. J. Organometallics 1987, 6, 232-241.
56. Nolan, S. P.; Lopez de la Vega, R.; Hoff, C. D. Organometallics 1986, 5, 2529-2537.
57. 10b